Patents Assigned to L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
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Patent number: 8016271Abstract: The invention relates to an apparatus for the treatment of gaseous effluents, such as those originating from the production of semi-conductors involving contact with a liquid. The inventive apparatus consists of: a gas/liquid contact chamber which can receive a liquid in the lower part thereof and which is topped with a gas cover, said chamber comprising means for introducing a gas to be treated and means for releasing residual gases following treatment involving contact with the liquid; turbine-type gas/liquid contacting means comprising one or more stages which ensure improved contact between the gas and the liquid, the upper part of said means being equipped with an opening for drawing the gas situated in the gas cover above the liquid; and, preferably, means for measuring the pH of the liquid.Type: GrantFiled: March 31, 2005Date of Patent: September 13, 2011Assignee: L'Air Liquide, Societe Anonyme a Directoire et conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Hervé Dulphy, Pascal Moine, Thierry Laederich
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Patent number: 7955526Abstract: A composite material (M) comprising: at least 75% by volume of a mixed electronic conductor compound oxygen anions O<2->(C1) selected from doped ceramic compounds which, at the temperature of use, are present in the form of a crystalline network having ion oxide lattice vacancies and, more particularly, in the form of a cubic phase, a fluorite phase, a perovskite phase, of the aurivillius variety, a Brown-Millerite phase or a pyrochlore phase; and 0.01%-25% by volume of a compound (C2) which is different from compound (C1), selected from oxide-type ceramic materials, non-oxide type ceramic materials, metals, metal alloys or mixtures of said different types of material; and 0%-2.5% by volume of a compound (C3) produced from at least one chemical reaction represented by the equation: xFC1+yFC2 - - - >zFC3, wherein FC1, FC2 and FC3 represent the raw formulae of compounds (C1), (C2) and (C3) and x, y and z represent rational numbers above or equal to 0.Type: GrantFiled: November 5, 2004Date of Patent: June 7, 2011Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l 'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pascal Del Gallo, Thierry Chartier, Gregory Etchegoyen
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Patent number: 7933724Abstract: Method of tracking the performance of an industrial appliance (E), in which an estimate (We) of the quantity representing the electrical power consumed is calculated, in real-time, using the model (M), based on the values of the set (F) of operating parameters of the industrial appliance (E), the difference between the measured value (W) of the electrical power consumed (W) and the estimated value (We) provided by the model (M) is calculated, to obtain the overconsumption value, based on a statistical test on the overconsumption variable, using the distribution of this variable, an overconsumption score is deduced from this corresponding to a probability of overconsumption (p1) and an alarm is triggered if the probability of overconsumption (p1) exceeds a given overconsumption probability threshold (sp1), so constituting an overconsumption indicator.Type: GrantFiled: December 8, 2005Date of Patent: April 26, 2011Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Caroline Drouart, Thierry Roba, Alain Donzel
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Patent number: 7891197Abstract: A method and an apparatus for the uninterrupted supply of liquid subcooled carbon dioxide. The liquid is supplied at a nearly constant pressure greater than about 40 bar. Liquid carbon dioxide is supplied at a low pressure and is sent into a low pressure tank where it is stored temporarily. The carbon dioxide is then pumped, with a pump, from the low pressure tank to a high pressure tank. During the pumping, the pressure of the carbon dioxide is increased. The carbon dioxide is stored in the high pressure tank until its removal. When the carbon dioxide is removed, it is in a thermodynamic disequilibrium between the liquid and gas phases.Type: GrantFiled: February 5, 2003Date of Patent: February 22, 2011Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Harald Winter
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Patent number: 7870759Abstract: In a process for supplying a pressurized gas, a pressurized gas at a high production pressure is produced as an end product by separating a gaseous mixture in a separator apparatus (3, 5), a liquid to be pressurized is stored in a store (9), storing liquid is tapped, and it is pressurized with a pump (11) and at least part of the pressurized liquid is sprayed in a sprayer (27) to produce the pressurized backup gas (29) having substantially the same pressure or a pressure higher than the pressurized gas to be produced, liquid is circulated in a substantially vertical duct (13), optionally within the cold box (33) of the separator apparatus, and at least part of the duct length is at a level above the sprayer and before and/or after starting up the pump (11), liquid is sent from the duct to the sprayer where the liquid is sprayed to provide pressurized backup gas having substantially the same purity or a purity higher than the pressurized gas to be produced (31).Type: GrantFiled: May 14, 2004Date of Patent: January 18, 2011Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Jean-Marc Peyron
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Patent number: 7805951Abstract: Methods and apparatus for freezing a product. The product is frozen in a treatment container which contains a vibrating support. The vibrating support is capable of receiving a film of a cryogenic liquid. A heated temperature probe, located just before the outlet of the treatment container, measures the temperature at that location. The supply system for the cryogenic liquid has a proportional valve. A data acquisition and processing unit receives the temperature information and controls the opening of the proportional valve.Type: GrantFiled: March 24, 2004Date of Patent: October 5, 2010Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Beny Bruggeman, Cemal Oztas, Didier Pathier, Robert Taylor
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Patent number: 7806075Abstract: The invention concerns an installation wherein is performed a crosslinking operation for a coating such as an ink or a varnish through ultraviolet radiation or electronic beam, in the presence of a gas mixture with controlled oxygen residual content. The installation comprises a chamber including one or more UV lamps or a source of accelerated electrons, required for performing the crosslinking operation, and is characterized in that it comprises an input device adjacent the chamber comprising at least the following three components, viewed successively by the product moving to be treated: a labyrinth system, means for injecting an inert gas forming a gas knife and a channel.Type: GrantFiled: January 24, 2005Date of Patent: October 5, 2010Assignee: L'Air Liquide, Société Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: François Coeuret, Géraldine Rames-Langlade, Andrea Spizzica
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Patent number: 7776208Abstract: This disclosure discusses integrating syngas streams with refinery hydrotreators, synthetic hydrocarbon gas to liquid (GTL) processes, and power generation units (such as combined cycle units) to efficiently use hydrogen contained in the syngas produced from heavy hydrocarbons (pet coke, residues, oil, etc.). Membrane separation and pressure swing adsorption is used to separate components of syngas and feed them to refineries, GTL units, and power/steam generation units. Hydrogen-rich refinery purge is used to raise the H2/CO ratio of syngas. A hydrogen-enriched syngas is produced with an H2/CO ratio favorable for the production on synthetic hydrocarbons (greater than about 1.5 to about 2.0 or higher). Pure hydrogen is also produced in a PSA unit, to further raise the H2/CO ratio of the syngas and provide hydrogen feed for refinery hydrotreators and synthetic hydrocarbon units (such as methanol units).Type: GrantFiled: October 1, 2004Date of Patent: August 17, 2010Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: C.J. Guo
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Patent number: 7776137Abstract: A polyimide MMC membrane useful for the production of oxygen-enriched air or nitrogen-enriched-air, for the separation of carbon dioxide from hydrocarbons or nitrogen, and the separation of helium or hydrogen from various streams. Membranes of polyimide polymers, such as polyimide polymers sold under the tradename P-84, are mixed with molecular sieve materials, such as SSZ-13, to make MMC membranes. The MMC membranes of the invention provide improved membrane performance compared to polymer only membranes, particularly when used to form asymmetric film membranes or hollow fiber membranes. The MMC films exhibit consistent permeation performance as dense film or asymmetric membranes, and do not interact with components of the process streams, such as organic solvents. The membranes of the invention exhibit particularly surprisingly good selectivity for the fluids of interest.Type: GrantFiled: March 20, 2009Date of Patent: August 17, 2010Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Sudhir S. Kulkarni, David J. Hasse
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Patent number: 7758336Abstract: The invention relates to processes for the combustion of liquid fuels, including a means of using an oxygenated gas in a combustion zone, applicable to steam boilers, which produces a longer, more uniform and cooler oxygen flame than a conventional oxygen flame. According to the invention, the liquid fuel is injected into the combustion zone in atomized form, the fuel being atomized by bringing a stream of fuel into contact with a stream of atomizing fluid, and: prior to its atomization, the liquid fuel has a viscosity of at least 30×10?6 m2/s, the stream of fuel is brought into contact with the stream of atomizing fluid only in the combustion zone, and oxygenated gas is injected into the combustion zone in stages.Type: GrantFiled: December 14, 2005Date of Patent: July 20, 2010Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pascal Tromeur, Remi Tsiava, Bertrand Leroux, Patrick Jean-Marie Recourt
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Patent number: 7739878Abstract: A method is provided for cooling a powder in a tunnel with a vibrating support with at least two independently controllable cryogenic liquid inflows into the tunnel. It includes the following steps. A thermal mass of powder entering the tunnel is determined. The arrival of the powder at the tunnel inlet is detected. The thermal mass measurement previously obtained is synchronized with the detection of the arrival of the powder at the tunnel inlet, according to a known or predefined response time of the means for controlling the said cryogenic liquid inflows into the tunnel. The synchronization data is transmitted to a data acquisition and processing unit, which is able to retroact, if necessary, on the basis of this data, on all or part of the parameters governing the operation of the tunnel. The method is especially applicable to the cooling or deep-freezing treatments of food products or chemicals.Type: GrantFiled: June 5, 2006Date of Patent: June 22, 2010Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Beny Bruggeman, Robert Taylor
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Patent number: 7699022Abstract: The invention relates to equipment for area-based surface treatment of an article by electric dielectric barrier discharge in the presence of a non-atmospheric controlled gaseous mixture, comprising a hollow metal electrode enabling the gaseous mixture to circulate therewithin and the mixture to be transported to a discharge area, whereby said electrode is divided into individual elements which can each be pivoted about a central axis to ensure sufficient distance between the element which is considered as being pivoted and the area of the article opposite the element in question so that the discharge cannot develop; the central pivoting axis is used as a channel for the circulation of the gaseous mixture inside the electrode and is provided with openings enabling the gaseous mixture to be evacuated to the discharge area; pivoting one of the elements of the electrodes blocks up the evacuating opening associated therewith and the gaseous mixture can only be evacuated via the evacuating openings of non-pivotedType: GrantFiled: May 7, 2004Date of Patent: April 20, 2010Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alain Villermet, François Coeuret, Jacques Delumeau
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Patent number: 7691318Abstract: The invention provides a spinnerette assembly for forming hollow fibers. The spinnerette assembly contains an extrusion orifice and a fiber-forming material passage in communication with the extrusion orifice. A hollow needle extends through the extrusion orifice in a concentric manner to define an annular passage surrounding the needle. The fiber-forming material passage includes a fiber-forming material inlet port extending from a surface of the spinnerette assembly to an interior of the assembly and a transverse passage extending from the fiber-forming material port to the annular passage surrounding the needle. A bore forming fluid passage communicates with the interior of the needle.Type: GrantFiled: September 14, 2004Date of Patent: April 6, 2010Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Samuel Earl Moore
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Patent number: 7648558Abstract: Methods for treating aluminum in a furnace. An aluminum charge is introduced into a furnace and melted with heat from at least one burner. The burner is supplied with at least one oxidizer and at least one fuel. The oxidizer is made up of at least 10% oxygen by volume. The concentration of a first gas is measured in the furnace atmosphere or in a flue gas exiting the furnace. The oxidation of the molten aluminum is then reduced by holding the flow rate of the oxidizer steady while varying the flow rate of the fuel, according to the concentration of a second gas in the furnace or in the flue gas exiting the furnace. The concentration of the second gas is determined by comparing the measured species concentration and the intrinsic concentration which would be present absent the aluminum charge.Type: GrantFiled: March 30, 2004Date of Patent: January 19, 2010Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Bruno Allemand, Jean-Claude Vuillermoz
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Patent number: 7648569Abstract: A method and an apparatus for injecting two-phase (gas+solid) carbon dioxide into a gas stream. Liquid carbon dioxide is cryogenically expanded into two-phase carbon dioxide, which is then injected into the center of the stream. An inerting gas is also injected into the stream along with the two-phase carbon dioxide.Type: GrantFiled: July 7, 2003Date of Patent: January 19, 2010Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes George ClaudeInventors: Dominique Bras, José Buil
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Patent number: 7645319Abstract: The invention relates to a method for renovating a combined system consisting of a blast furnace supplied with an oxidant fluid received at least partly from an air/gas separation unit (ASU). The method consists in injecting, before renovation, at least 50% of the flow rate of the blower feeding the blast furnace into an ASU to produce oxygen whose purity is greater than 90% by volume of O2 which feeds the blast furnace, in controlling the blower airflow rate and the pressure of the air derived therefrom by a regulator which measures the flow rate and/or pressure at the input and/or output of a cleaning stage which is mounted upstream of the separation unit to control the flow rate and pressure of the air derived from the blower. The fluid feeding the blast furnace consists of pure oxygen or diluted by air produced by the cryogenic separation unit.Type: GrantFiled: February 11, 2005Date of Patent: January 12, 2010Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Richard Dubettier-Grenier, Michel Devaux, Jean-Marc Peyron
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Patent number: 7641719Abstract: The gas separation apparatus comprises a flexible wall which is maintained in a placed position on an upper end of an adsorbant material; the volume between the wall and an upper dome communicates with one of inner and outer chambers on both sides of the adsorbant (4). The invention can be used to separate air components.Type: GrantFiled: June 18, 2004Date of Patent: January 5, 2010Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jérôme Bres, Xavier Vigor, Sylvain Fourage, Anne Barbier
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Patent number: 7638972Abstract: A system for monitoring a group of electrochemical cells (C1, . . . , Ci, . . . , Cn) arranged in series, wherein each cell (Ci) is provided for outputting a DC voltage (Vi) greater than a minimum value (Vmin). According to the invention, said monitoring system includes a corresponding set of n electronic components (D1, . . . , Di, . . . , Dn) arranged in series, wherein each component (Di) is biased by the DC voltage (Vi) of a corresponding cell (Ci) by means of a low-frequency connecting element (Li), and has a conductivity threshold voltage (Vs) no lower than said minimum value (Vmin); and a means (D) for measuring a high-frequency conductivity parameter of all of said components. The system is useful in fuel cells.Type: GrantFiled: May 17, 2005Date of Patent: December 29, 2009Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Pierre Charlat
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Patent number: 7632453Abstract: The invention relates to a gas quenching method of the type that makes use of (i) a quenching cell (V1) which is intended to receive objects to be quenched with a quenching gas and (ii) a buffer capacity (V2) which is designed to contain the quenching gas.Type: GrantFiled: August 10, 2004Date of Patent: December 15, 2009Assignee: L'Air Liquide-Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Florent Chaffotte, Nicolas Blanchard, Olivier Delobel, Linda Lefevre
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Patent number: 7628843Abstract: A feedstock hydrogen-enriched gas (3) is supplied to a PSA purification unit (1) which delivers pure hydrogen at a production output (4) and a hydrogen-deficient gas at a residual output. Said hydrogen-deficient gas is compressed (9) and injected into a line (10) wherein a gaseous combustible mixture circulates whose part (12) is extracted upstream of the PSA unit (1), compressed (13) and reinjected into said feedstock of the PSA unit (1). Said invention is used, in particular for petrochemical sites.Type: GrantFiled: June 28, 2004Date of Patent: December 8, 2009Assignee: L'Air Liquide, Societe Anonyme A Directoire Et Conseil de Surveillance pour l'Etude Et l'Exploitation des Procedes Georges ClaudeInventors: Christian Monereau, François Fuentes, Guillaume De Souza