Patents Assigned to L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
  • Patent number: 11959702
    Abstract: An air separation device can include: a first compressor and a second compressor for compressing feed air; a first refrigerator and a second refrigerator for cooling the feed air; a pre-purification unit for pre-purifying the feed air; a flow rate measuring unit for measuring the flow rate of the feed air; a main heat exchanger for subjecting the feed air to heat exchange; a purification portion into which the feed air led out from the main heat exchanger is fed, and which separates and purifies product nitrogen and/or product oxygen from the feed air; and a compressor control unit for controlling the feed quantity of the feed air in accordance with an increase or decrease in the production quantity of product nitrogen and/or product oxygen.
    Type: Grant
    Filed: March 4, 2021
    Date of Patent: April 16, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Takuya Kaneda, Tsuyoshi Sugitani
  • Publication number: 20240116009
    Abstract: Composite hollow fiber gas separation membranes with improved permeance and separation layer adhesion are manufactured by providing dipping a hollow fiber membrane substrate in a pre-coat layer coating composition followed by drying to thereby provide a pre-coated substrate and dipping the pre-coated substrate in a separation layer coating composition followed by drying to thereby provide the composite hollow fiber gas separation membranes. The pre-coating composition includes a first polymer dissolved in a first solvent and the separation layer composition includes a second polymer dissolved in a second solvent. The first and second polymers are the same or different, each of the first and second polymers is at least 1 wt % soluble in a same third solvent, the first and second solvents are the same or different, the first and third solvents are the same or different, and the second and third solvent are the same or different.
    Type: Application
    Filed: October 10, 2022
    Publication date: April 11, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Junyi LIU, Sudhir KULKARNI, Raja SWAIDAN, Megha SHARMA
  • Publication number: 20240117911
    Abstract: Self-closing emergency release and coupling device for the transport of cryogenic fluid comprising two pipes extending in a longitudinal direction and each comprising, at a connection end, a valve mechanism configured to automatically close the pipe when the connection ends are separated and to open the pipe when the connection ends are coupled, the device further comprising a tube arranged around each pipe and defining a vacuum space for thermally insulating the pipeline, the device is characterized in that it further comprises a chamber disposed around the valve mechanism and delimited by a wall assembly located between the outer tube and the transport pipe, the volume of the insulation chamber being independent of the vacuum space between the outer tube and the transport pipe.
    Type: Application
    Filed: January 17, 2022
    Publication date: April 11, 2024
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Gaetan COLEIRO, Yan PENNEC
  • Publication number: 20240117285
    Abstract: Raw biogas from an anaerobic digester is fed to a membrane separation unit that produces methane rich biomethane and a CO2 rich permeate that is recycled to the anaerobic digester where it is mixed with the digestate.
    Type: Application
    Filed: October 6, 2022
    Publication date: April 11, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Sudhir KULKARNI, Min Ho MAENG, Shu FANG
  • Patent number: 11953158
    Abstract: A device and process for refuelling containers comprising a pressurized gas source, a transfer circuit intended to be removably connected to a container, the device comprising a refrigeration system comprising a refrigerant cooling loop circuit comprising, arranged in series, a compressor, a condenser section, an expansion valve and an evaporator section, the refrigeration system comprising a cold source in heat exchange with the condenser section and a heat exchanger located in the transfer circuit, the refrigerant cooling loop circuit comprising a bypass conduit comprising an upstream end connected to the outlet of the compressor and a downstream end connected to the refrigerant cooling loop circuit upstream the compressor inlet, the device further comprising a bypass regulating valve for controlling the flow of refrigerant flowing into the by-pass conduit, the device comprising a pressure sensor for sensing the refrigerant pressure in the cooling loop circuit between the compressor inlet and the heat excha
    Type: Grant
    Filed: October 31, 2022
    Date of Patent: April 9, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Etienne Werlen, Marcus Buck
  • Patent number: 11952270
    Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.
    Type: Grant
    Filed: October 5, 2021
    Date of Patent: April 9, 2024
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Pierre-Philippe Guerif, Vincent Follaca, Alain Guillard, Youssef Tazi
  • Publication number: 20240110670
    Abstract: At a liquid cryogen depot, gaseous cryogen from non-completely filled short trailers is used for pressurizing jumbo trailers, from which liquid cryogen is caused to flow into empty trailers through pressure differential.
    Type: Application
    Filed: September 29, 2022
    Publication date: April 4, 2024
    Applicant: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Joshua LIGHT
  • Patent number: 11946594
    Abstract: Mobile cryogenic tank for transporting cryogenic fluid, notably liquefied hydrogen or helium, comprising an internal shell intended to contain the cryogenic fluid, an external shell arranged around the internal shell and delimiting a space between the two shells, said space containing a thermal insulator, the first shell having a cylindrical overall shape extending along a central longitudinal axis (A), when the tank is in the configuration for transport and use, the central longitudinal axis (A) being oriented horizontally, the tank comprising a set of temperature sensors measuring the temperature of the fluid in the internal shell, characterized in that the set of temperature sensors is situated on the external face of the internal shell and measure the temperature of said shell, the set of temperature sensors comprising a lower sensor positioned at the lower end of the internal shell situated below the central longitudinal axis (A), the set of temperature sensors further comprising a plurality of intermedi
    Type: Grant
    Filed: January 14, 2021
    Date of Patent: April 2, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Lucien Varrassi, Philippe Cadeau, Thomas Fayer, Stephane Duval
  • Patent number: 11946692
    Abstract: A method for separating a mixture containing at least nitrogen and methane by cryogenic distillation in a first column operating in a first pressure and a second column operating at a second pressure lower than the first pressure, the mixture being separated in the first column to form a gas enriched in nitrogen and a liquid enriched in methane, at least a portion of the gas enriched in nitrogen being at least partially condensed in a heat exchanger and returned to the first column, the gas enriched in nitrogen is sent into the heat exchanger by the bottom, ascends in a first series of passages of the exchanger and condenses therein at least partially, the liquid formed descending in these passages of the first series and exiting by the bottom of the exchanger.
    Type: Grant
    Filed: April 8, 2022
    Date of Patent: April 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Paul Terrien, Nicolas Chantant, Jean-Marc Peyron
  • Patent number: 11946703
    Abstract: A heat exchanger having a stack of multiple plates which are parallel to one another and to a longitudinal direction, and stacked spaced apart from one another so as to define, between one another, a first series of passages for the flow of at least a first fluid in an overall flow direction parallel to the longitudinal direction, each passage being delimited by closure bars disposed between the plates. A filtering device is arranged in at least one passage of the first series, the filtering device extending for the one part between two adjacent plates defining the passage and for the other part between two of the closure bars delimiting the passage, the filtering device having a metal sheet material chosen from among a metal fabric, a nonwoven of metal fibres, a sintered metal powder or sintered metal fibres, a metal foam, or a microperforated plate.
    Type: Grant
    Filed: May 12, 2022
    Date of Patent: April 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Eric Masliah, Arnaud Gueguen, Gilles Lebain, Ludovic Amant
  • Patent number: 11946693
    Abstract: The invention relates to a system for controlling an argon flow rate of a fluid at the outlet of an assembly of at least one distillation column in order to reach a target dioxygen level (SP).
    Type: Grant
    Filed: May 22, 2019
    Date of Patent: April 2, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Marc Bastid
  • Patent number: 11940149
    Abstract: An elevated flare system in a synthesis gas production plant for thermal disposal of offgases having at least two different contents of carbon monoxide arising in synthesis gas production and/or synthesis gas treatment.
    Type: Grant
    Filed: January 12, 2021
    Date of Patent: March 26, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Antonio Coscia
  • Patent number: 11940228
    Abstract: The present invention discloses a high-temperature fluid transporting pipeline with a heat exchange apparatus installed therein, a suitable heat exchange apparatus and a heat exchange method, wherein heat contained in a high-temperature fluid can be recovered during the transportation thereof. The heat exchange apparatus comprises a heat exchange body inserted into the high-temperature fluid transporting pipeline, and a heat-receiving fluid coil installed therein. The method of heat exchange is that the high-temperature fluid heats an auxiliary fluid in a heat exchange cavity via a heat exchange panel of the heat exchange body in contact therewith, and the heated auxiliary fluid then conducts the heat to a heat-receiving fluid in the heat-receiving fluid coil.
    Type: Grant
    Filed: December 17, 2021
    Date of Patent: March 26, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Yuquan Gu, Peter Van Kampen, KuoHsuan Wang, Aili Zhang, Wenbiao Zhou
  • Patent number: 11933458
    Abstract: Heat is transferred from a first portion of liquid hydrogen to a flow of a heat transfer fluid at a first heat exchanger through heat exchange with a heat transfer fluid to produce a flow of vaporized hydrogen and a warmed flow of heat transfer fluid. The flow of vaporized hydrogen is combined with a second portion of liquid hydrogen in amounts designed to produce a combined flow with a desired temperature, the combined flow being used to fill one or more buffer vessels. Heat is also transferred at a second heat exchanger from a stream of pressurized hydrogen from the at least one buffer vessel to the cooled flow of heat transfer fluid to produce a cooled flow of pressurized hydrogen that is used to fill tanks of fuel cell electric vehicles.
    Type: Grant
    Filed: September 15, 2022
    Date of Patent: March 19, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Vincent Fairy, Anh Thao Thieu, Samuel Trompezinski
  • Publication number: 20240084941
    Abstract: Disclosed is a self-closing emergency coupling and release device for the transport of cryogenic fluid, comprising two fluid transport pipes extending in a longitudinal direction and each comprising, at a connection end, a valve mechanism configured to automatically close the pipe when the connection ends are separated and to open the pipe when the connection ends are coupled, the device further comprising an outer tube arranged around each transport pipe and delimiting a vacuum space for thermally insulating the transport pipe, the device further comprising a mechanism for holding the transport pipe in the outer tube, characterized in that the holding mechanism comprises a frustoconical connection tube having a first end connected to the outer tube and a second end connected to the transport pipe.
    Type: Application
    Filed: January 12, 2022
    Publication date: March 14, 2024
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Gaetan COLEIRO, Yan PENNEC
  • Patent number: 11920736
    Abstract: Heat is transferred from a flow of liquid hydrogen to a flow of a heat transfer fluid at a first heat exchanger to produce a warmed flow of pressurized hydrogen and a cooled flow of heat transfer fluid. Heat is also transferred at a second heat exchanger, to the cooled flow of heat transfer fluid, from a flow of pressurized hydrogen that is derived from one or more buffer vessels filled by the warmed flow of pressurized hydrogen and/or the warmed flow of pressurized hydrogen from the first exchanger to produce a cooled flow of pressurized hydrogen that is used to fill tanks of fuel cell electric vehicles.
    Type: Grant
    Filed: September 15, 2022
    Date of Patent: March 5, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Vincent Fairy, Anh Thao Thieu
  • Patent number: 11920732
    Abstract: A quality control method for the preparation of dry compressed gas cylinder including passivating and/or preparing the compressed gas cylinder with the technique to be validated, filling the passivated/prepared compressed gas cylinder with gaseous carbon dioxide to a normal working pressure, wherein the gaseous carbon dioxide has a known ?18O isotope ratio, maintaining the pressurized gas cylinder at ambient temperature for a first predetermined period of time, and gradually emptying the pressurized gas cylinder, while simultaneously measuring the ?18O isotopic ratio, wherein a predetermined variation in the measured isotopic ratio of ?18O indicates a properly prepared cylinder.
    Type: Grant
    Filed: March 2, 2020
    Date of Patent: March 5, 2024
    Assignees: Airgas, Inc., America Air Liquide, Inc., L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Tracey Jacksier, Mani C. Matthew, Richard A. Socki, Jun Sonobe, Megumi Isaji, James McHale
  • Patent number: 11920737
    Abstract: Device for storing and for supplying fluid fuel, comprising a reservoir of liquefied fuel gas in equilibrium with a gas phase, in particular hydrogen, a circuit for filling the reservoir, at least one circuit for tapping fluid from the reservoir, and at least one circuit for regulating the pressure in the reservoir, the filling circuit, tapping circuit and pressure-regulating circuit comprising a set of valves arranged in a housing separate from the reservoir, the housing being removably connected to the reservoir via a demountable mechanical coupling system, the tapping circuit, the pressure-regulating circuit and the filling circuit comprising a set of demountable fluidic connectors situated at the junction between the reservoir and the housing and configured to allow the separation between portions of circuits situated in the reservoir and in the housing during the demounting of the housing with respect to the reservoir.
    Type: Grant
    Filed: March 12, 2020
    Date of Patent: March 5, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Emmanuel Bensadoun, Patrick Bravais, Patrick Sanglan
  • Publication number: 20240066493
    Abstract: A hydrogen production facility having equipment with a nitridation protective layer is provided. The hydrogen production facility can include a reformer configured to catalytically convert a feed stream into a product stream comprising hydrogen, the reformer having a plurality of catalyst tubes and a plurality of burners configured to provide heat to the catalyst tubes; means for providing the feed stream to the reformer from an ammonia source, wherein the feed stream comprises at least 90% of ammonia, wherein the plurality of catalyst tubes comprise a nitridation protective layer on an inner surface of the catalyst tubes.
    Type: Application
    Filed: August 25, 2022
    Publication date: February 29, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Christoph BEYER, Robert BREINING, Dieter ULBER
  • Publication number: 20240068081
    Abstract: A method for converting an existing steam methane reformer (SMR) to produce hydrogen via ammonia cracking is provided. The method can include the steps of: providing the existing SMR, wherein the SMR was formerly used to produce hydrogen from a hydrocarbon feedstock; and improving the nitridation resistance of the inner surface of the equipment by adding a protective layer to an inner surface of equipment to be used in the existing SMR, wherein the equipment is selected from the group consisting of a catalyst tube, feed piping, a feed preheater, process gas heat exchangers, and combination thereof.
    Type: Application
    Filed: August 25, 2022
    Publication date: February 29, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Christoph BEYER, Robert BREINING, Dieter ULBER