Abstract: Provided are: acrylic fibers having 2-7% boiling water shrinkage and formed by the side-by-side conjugation of a copolymer A, which contains 5-10 mass % of an unsaturated monomer that can form a copolymer with acrylonitrile units, and a copolymer B, which contains 2-5 mass % of unsaturated monomer units that can form a copolymer with acrylonitrile units and 0.2-1.5 mass % of sulfonic acid group-containing monomer units; a method for manufacturing said fibers; a spun yarn containing said fibers; and a knitted fabric obtained from said spun yarn. The single fiber fineness of the heat-treated acrylic fibers is 1.7-6.6 dtex, the bulkiness is at least 380 cm3/g, the percentage of crimp is at least 15%, and the product (DKSDKE) of the knot strength (cN/dtex) and the knot elongation (%) is 10-25. The acrylic fibers have excellent crimp characteristics and anti-pilling properties.
Abstract: Provided are: a resin composition with which it is possible to form a cured film having excellent weather resistance and wear resistance; and a resin molding having said cured film. An active energy beam-curable resin composition containing a radical polymerizable compound and a photopolymerization initiator (d), wherein said radical polymerizable compound contains 57-90 mass % of (a) caprolactone-modified mono- or poly-penta erythritol poly (meth)acrylate represented by formula (1) and 10-43 mass % of (b) urethane (meth)acrylate synthesized from a polycarbonate polyol having a branched alkyl structure and an average molecular weight falling within the range of 500-1000, a diisocyanate having an alicyclic structure, and a mono (meth)acrylate containing a hydroxyl group. In formula (1), each X independently represents a caprolactone-modified (meth)acryloyl group, a (meth)acryloyloxy group, or a —OH group.
Abstract: The present invention relates to a polyester resin with excellent solubility in generic solvents, especially with excellent solubility at a temperature of 0° C. or lower. According to the present invention, by using the polyester resin with excellent solubility in generic solvents, solubility at a lower temperature, especially the solubility at a temperature of 0° C. or lower, is enhanced, making it easier to prepare paints, coatings and the like. The polyester resin related to the present invention contains 0.05 to 0.5 mol of an isosorbide-derived structural unit and 0.015 to 0.4 mol of a trihydric or higher alcohol-derived structural unit relative to 1 mol of a polycarboxylic acid-derived structural unit.
Abstract: A (meth)acrylic copolymer (A) having a mass average molecular weight of 50,000 to 1,000,000, in which the (meth)acrylic copolymer (A) is obtained by polymerizing a monomer mixture including a macromonomer (a) that has a number average molecular weight of 500 or more and less than 6000 and a vinyl monomer (b), and preferably includes 7 to 40% by mass of a repeat unit derived from the macromonomer (a), has sufficient coating workability, adhesive holding power and adhesive property as an adhesive composition.
Type:
Application
Filed:
November 28, 2014
Publication date:
February 2, 2017
Applicant:
Mitsubishi Rayon Co., Ltd.
Inventors:
Eri KAWAI, Junichi NAKAMURA, Hiroko SHINADA
Abstract: Provided are a long structural member and a structural member complex that comprise a fiber-reinforced resin having a simple reinforced structure, suppressing increase in molded article weight, and exhibiting high mechanical properties. The long structural member has a perpendicular cross-section formed in a U shape, has two of the corners on the inside of the U-shaped section reinforced by the fiber-reinforced resin, and has a triangular cross-section for each of the cross-sections of the two corners inside the reinforced U-shaped section, that fulfills the following formulas. 0.05?W/W0?0.15 and 0.15?H/H0?0.
Abstract: Provided is a method for producing a methacrylic acid ester using a biocatalyst, said method comprising a step of reacting an alcohol or a phenol with methacrylyl-CoA in the presence of an alcohol acyltransferase originated from a plant selected from the group consisting of a plant belonging to the genus Osmanthus, a plant belonging to the genus Vitis, a plant belonging to the genus Citrus, a plant belonging to the genus Durio, a plant belonging to the genus Magnolia and a plant belonging to the genus Chamaemelum to thereby synthesize the methacrylic acid ester.
Abstract: The purpose of the present invention is to provide an acrylic resin composition that is a raw material for an acrylic resin film which has an excellent appearance and in which occurrence of blocking is suppressed. The present invention is an acrylic resin composition that comprising an acrylic polymer (A), an anti-blocking agent (B), and a non-crosslinked acrylic polymer (C). The non-crosslinked acrylic polymer (C) is a polymer of a monomer component including 50% to 100% by mass of methyl methacrylate (c1), the polymer having a reduced viscosity of 0.2 to 2 L/g.
Abstract: Provided is a method that can produce phenyl(meth)acrylate inexpensively and at high yields. The phenyl(meth)acrylate production method of the present invention reacts (meth)acrylic acid with carbonic acid diphenyl. Further, the phenyl(meth)acrylate composition of the present invention contains 90-99.999 wt % phenyl(meth)acrylate and 0.001-10% carbonic acid diphenyl. Or, the phenyl(meth)acrylate composition of the present invention contains 90-99.999 wt % phenyl(meth)acrylate and 0.001-10 wt % of a specified compound.
Type:
Application
Filed:
October 4, 2016
Publication date:
January 26, 2017
Applicant:
MITSUBISHI RAYON CO., LTD.
Inventors:
Ryo Aizawa, Takeshi Matsuo, Naoshi Murata, Hiroyuki Mori
Abstract: A variety of molded bodies having high weatherability, impact resistance, designability, and the like, and a polyorganosiloxane latex and a graft copolymer used as the raw materials therefor are provided, where the polyorganosiloxane latex has a mass average particle diameter (Dw) of a polyorganosiloxane particle of 100 to 200 nm, and a ratio of the mass average particle diameter (Dw) to a number average particle diameter (Dn) (Dw/Dn) of 1.0 to 1.7. A polyorganosiloxane-containing vinyl-based copolymer (g) obtained by polymerizing one or more vinyl-based monomers in the presence of the latex. A graft copolymer (G) is obtained by graft polymerizing one or more vinyl-based monomers in the presence of the copolymer. A thermoplastic resin composition includes the graft copolymer (G) and a thermoplastic resin (Ha) except for the graft copolymer (G). A molded body is obtained by molding the resin composition.
Type:
Grant
Filed:
January 29, 2016
Date of Patent:
January 24, 2017
Assignees:
Mitsubishi Rayon Co., Ltd., UMG ABS, Ltd.
Abstract: Provided is an active energy ray-curable resin composition with which it is possible to form a cured film, having outstanding scratch resistance, hardness, and weather resistance, on the surface of a molded resin article for an automobile headlamp lens. The active energy ray-curable resin composition is used to form a cured film on the surface of a molded resin article for an automobile headlamp lens and comprises (A) 10-70% by mass of a mono- or poly-pentaerythritol poly(meth)acrylate compound having a specific structure, (B) 10-50% by mass of a urethane(meth)acrylate compound having at least two (meth)acryloyloxy groups, at least one amido group, and at least two urethane bonds, and (C) 20-80% by mass of a poly[(meth)acryloyloxyalkyl]isocyanurate compound having a specific structure.
Abstract: Provided is a resist copolymer which has favorable sensitivity, enables a resist pattern to be formed to have a favorable shape, has favorable dry etching resistance when a dry etching is carried out using the resist pattern as a mask, and suppresses the surface roughness of a pattern formed by carrying out a dry etching process to a substrate. A resist copolymer including a constituent unit (1) based on a (meth)acrylic acid ester derivative having a cyclic hydrocarbon group such as an adamantane ring and two or more cyano groups bonded to the cyclic hydrocarbon group, a constituent unit (2) having a lactone backbone and a cross-linking cyclic structure, and a constituent unit (3) having an acid leaving group.
Abstract: A method of manufacturing a porous film includes a decomposition step of introducing a porous film precursor which is formed by coagulating an undiluted film forming solution containing a hydrophilic polymer and a hydrophobic polymer, into a decomposition container; bringing a heated chemical containing an oxidizing agent into contact with the porous film precursor in the decomposition container; warming the porous film precursor in contact with the chemical; and decomposing the hydrophilic polymer remaining inside the porous film precursor using the oxidizing agent. An apparatus for manufacturing a porous film includes a decomposition device provided with the decomposition container.
Abstract: Method for producing an iron carboxylate, whereby it becomes possible to prevent the generation of hydrogen during the production of the iron carboxylate by the reaction of a carboxylic acid with metal iron. An embodiment of the present invention is a method for producing an iron carboxylate by reacting metal iron with a carboxylic acid in a reaction solution, wherein the reaction solution contains a non-iron metal having a standard electrode potential of ?2.5 to 0.1 inclusive or a metal compound containing the metal, or the reaction solution contains at least one metal selected from the group consisting of Ag, Bi and Pd or a metal compound containing the metal.
Type:
Grant
Filed:
August 2, 2013
Date of Patent:
January 10, 2017
Assignee:
MITSUBISHI RAYON CO., LTD.
Inventors:
Takeshi Matsuo, Naoshi Murata, Hiroyuki Mori
Abstract: An object of the invention is to provide a molding with suppressed coloring which has good weather resistance and in which the advantageous effect does not decrease with time. The present invention provides a molding material comprising a polymer (A) obtained by polymerizing 0.01 to 35 mol % of monomer (a1) represented by a specified formula (1) and 65 to 99.99 mol % of monomer (a2) whose main component is methylmethacrylate.
Abstract: A graft copolymer capable of providing impact resistance, flame retardance, and color rendering properties to a thermoplastic resin is described. The graft copolymer contains a polyorganosiloxane, and is obtained by graft-polymerizing vinyl monomers including a (meth)acrylate ester (b1) having an alkyl group or an aromatic group and an aromatic vinyl monomer (b2) on a polyorganosiloxane-based rubber. The graft copolymer has a volume average particle diameter of 200-2000 nm, and contains 0.1-69 mass % of polyorganosiloxane. A thermoplastic resin composition is also described, containing a thermoplastic resin (A), the graft copolymer, a fluorine resin (C) and a flame retardant (D). A molded article is also described, which is obtained by molding the thermoplastic resin composition.
Abstract: Provided is a copolymer for lithography containing a monomer containing an acid leaving group and a monomer not containing an acid leaving group, in which N(v1)/Nave is from 1.01 to 1.09 and all of N(v2)/Nave, N(v3)/Nave, and N(v4)/Nave are from 0.95 to 1.05 when, among five fractions obtained by dividing an eluate providing a peak according to the copolymer in an elution curve obtained by GPC in order of elution so as to have an equal volume, ratios of monomer units containing an acid leaving group among the total monomer units constituting a copolymer included in the respective fractions from the first which is eluted earliest to the fourth are denoted as N(v1) mol % to N(v4) mol %, respectively, and the ratio of the monomer unit containing an acid leaving group among the total monomer units constituting a copolymer included in the sum of the five fractions is denoted as Nave mol %.
Abstract: The present invention provides a (meth)acrylic acid-producing method capable of suppressing formation of carbides so that the production yield of (meth)acrylic acid is enhanced. In such a method, (meth)acrylic acid is produced through gas-phase catalytic oxidation reactions of (meth)acrolein by using molecular oxygen in a fixed-bed reactor configured to have a packed layer containing a packing material and a catalyst layer formed with a catalyst containing at least molybdenum and vanadium. The packed layer contains a packing material that has been used at least once for above gas-phase catalytic oxidation reactions, and the catalyst is present in the packed layer at 0.001˜0.15 mass % of the total amount of the packing material.
Abstract: The present invention of a method for producing a porous membrane including a solidification step of forming a porous membrane, and a heating step of drying the porous membrane, wherein the heating step includes at least a water reduction step of the porous membrane, the water reduction step uses a heating medium, and the temperature of the heating medium (Tgh) satisfies a relation of tgh>Td, when Td represents the heat deformation temperature of a membrane material. The present invention of a drying device of a porous membrane including a water reduction unit, and a final drying unit, wherein the drying device includes a membrane-surface-temperature measurement means for measuring the surface temperature of the porous membrane and the final drying unit, and a control means for controlling the temperature and/or the flow speed of the heating medium of the water reduction unit.
Abstract: The present invention provides a defect inspection apparatus and a defect inspection method that allows easy and efficient inspection of a defect of a porous hollow fiber membrane.