Patents Assigned to Mitsui Toatsu Chemicals, Incorporated
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Patent number: 5374708Abstract: Polyimide filaments and polyimide films having great strength, high elastic modulus and high crystallinity and comprising a novel polyimide which can be melt-processed without impairing high crystallinity and which essentially consists of recurring structural units represented by the formula (I): ##STR1## more than 85 mol % the polyimide consists of recurring structural units of the formula (II): ##STR2## and from 0.5 to 15 mol % of the polyimide consists of recurring structural units represented by the formula (III), the formula (II) exclusive, the formula (IV) and/or the formula (V).Type: GrantFiled: August 8, 1991Date of Patent: December 20, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi, Masumi Saruwatari
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Patent number: 5372871Abstract: The invention provides a circuit board for an optical element which is disposed in an optical reading apparatus or an optical writing apparatus and is used to irradiate document reading light upon an document or irradiate image writing light upon a photosensitive material through a lighting window thereof.Type: GrantFiled: March 10, 1993Date of Patent: December 13, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Mitsuo Takase, Nobuhiro Fukuda, Toshihiro Dodo
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Patent number: 5370958Abstract: An object of the present invention is to provide an electrophotographic toner for high-speed copying machines having a high hot-roll speed and capable of fixing a toner at lower temperatures. The toner according to the present invention comprises a vinyl resin which has a wide molecular-weight distribution (Mn:1,000-20,000, Mw: 50,000-2,000,000), a glass transition temperature (Tg) of 40.degree.-75.degree. C. and a low acid value (AV:1-10); and a glycidyl compound in an amount sufficient to provide 0.05-1.0 equivalent of glycidyl groups per equivalent of COOH groups in the vinyl resin. It assures well-balanced fixing property, offset resistance and blocking resistance. In particular, it exhibits a remarkable effect in improving offset resistance and also in grindability during the production of the toner.Type: GrantFiled: January 29, 1993Date of Patent: December 6, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Masaaki Shin, Kenji Uchiyama, Yasuo Okada
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Patent number: 5364958Abstract: The hue of a methylene-crosslinked polyphenylene polyisocyanate continuously produced by the reaction with phosgene in an inert solvent of a polyamine mixture obtained by condensation of aniline and formaldehyde in the presence of an acid catalyst is improved by first removing any residual phosgene followed by heat treatment in the presence of hydrogen chloride gas.Type: GrantFiled: June 22, 1993Date of Patent: November 15, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Noritoshi Ishida, Zunzi Tashima, Naoki Sato, Michiya Takasaki, Masaaki Iijima, Kazuyuki Kuroda, Kazunari Nitta
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Patent number: 5362595Abstract: This invention discloses electrophotographic toners and the methods for their preparation. The electrophotographic toners contain resin and coloring agents as primary components. The resin is a non-crosslinked polymer of vinyl monomers or its mixtures, and has a number average molecular weight (Mn) of 2,000-15,000, a Z average molecular weight (Mz) of not less than 400,000 and Mz/Mn of 50-600. The electrophotographic toners exert an excellent fixing ability at high duplication speed or at lower temperatures.Type: GrantFiled: October 26, 1992Date of Patent: November 8, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Nobuhiro Hirayama, Masaaki Shin, Shoji Kawasaki, Akira Misawa, Akio Fujiwara, Kenji Uchiyama
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Patent number: 5359102Abstract: A transition metal compound represented by the formula ##STR1## (wherein each of A.sup.1, A.sup.2, A.sup.3 and A.sup.4 is a cyclopentadienyl group, an indenyl group, a fluorenyl group or their derivative; A.sup.5 is a hydrocarbondiylidene group having 4 to 30 carbon atoms; a pair of A.sup.1 and A.sup.2 as well as a pair of A.sup.3 and A.sup.4 is respectively bonded to the identical carbon atom in A.sup.5 to form a crosslinking structure; each of R.sup.1 and R.sup.2 is a halogen atom, a hydrogen atom, an alkyl group or a silicon-containing alkyl group having 1 to 10 carbon atoms, an aryl group, an alkylaryl group, an arylalkyl group or a halogenated aryl group having 6 to 20 carbon atoms; R.sup.1 and R.sup.2 may be identical or different; each of M.sup.1 and M.sup.2 is titanium, zirconium or hafnium; and M.sup.1 and M.sup.2 may be mutually identical or different), and a method for polymerizing an olefin in the presence of this compound and a co-catalyst.Type: GrantFiled: October 8, 1992Date of Patent: October 25, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Norihide Inoue, Tetsunosuke Shiomura, Masahiro Kouno, Yoshiho Sonobe, Kazumi Mizutani
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Patent number: 5359075Abstract: A novel quinophthalone compounds and the 2(2')-ene wherein when R.sub.1 is tautomer a hydrogen atom, tautomer thereof an alkyl group having 2 to 8 carbon atoms which may be branched cycloalkyl group having 5 or 6 ring atoms, R.sub.2 is a hydrogen atom, halogen atom, alkoxy group, alkylthio group, arylthio group which may be substituted, by alkyl of 1 to 4 carbon atoms, each of R.sub.3 and R.sub.4 is a hydrogen atom, alkyl group, N-substituted aminocarbonyl group, or a heterocyclic ring substituent having two or more ring atoms of one or more kinds selected from the group consisting of a nitrogen atom, oxygen atom and sulfur atom, R.sub.3 and R.sub.4 collectively with the ring carbon atoms to which they are attached form an N-substituted maleimide ring; provided however, that when R.sub.1 is a hydrogen atom, is a hydrogen atom, and R.sub.Type: GrantFiled: August 5, 1992Date of Patent: October 25, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tsukasa Ohyama, Yasushi Shimokawa, Yoriaki Matsuzaki, Keisuke Takuma, Isamu Ghoda, Hitoshi Koshida
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Patent number: 5358536Abstract: According to the present invention, there can be provided a black dyestuff for heat-sensitive transfer record comprising at least one orange dyestuff represented by the formulaAr.sub.1 --N=N--Ar.sub.2 --N=N--Ar.sub.3 ( 1)[wherein each of Ar.sub.1, Ar.sub.2 and Ar.sub.3 is independently an aryl group which may have a substituent] and at least one blue dyestuff represented by the formula ##STR1## [wherein each of R.sub.1, R.sub.2 and R.sub.3 is independently a hydrogen atom, halogen atom, nitro group, hydroxyl group, alkyl group which may have a substituent, alkoxy group, alkylsulfonylamino group or alkylcarbonylamino group, and each of R.sub.4 and R.sub.5 is independently an alkyl group which may have a substituent, and a black heat-sensitive transfer sheet in which the above-mentioned dyestuff is used.Type: GrantFiled: July 31, 1992Date of Patent: October 25, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Hitoshi Koshida, Isamu Ghoda, Tsukasa Ohyama, Keisuke Takuma
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Patent number: 5356866Abstract: Furobenzopyran derivatives of the general formula (I): ##STR1## in which R.sup.1 is a lower alkyl group, R.sup.2 is a lower alkyl group, lower alkoxy group, halogen atom or lower alkyl group substituted by a halogen atom, R.sup.3 is a lower alkyl group, lower alkoxy group, halogen atom, lower alkyl group substituted by a halogen atom, phenoxy group or benzyloxy group, R.sup.4 is a hydrogen atom or lower alkyl group and m and n are any integers between 0 and 4, have an excellent herbicidal activity on weeds and are completely selective to crops such as paddy rice, soybeans and cotton.Type: GrantFiled: May 24, 1993Date of Patent: October 18, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Kiyoshi Arai, Masayuki Ooka, Fumiaki Koizumi, Sadafumi Koda, Yasunaga Iwasaki, Yoshiro Kanemoto
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Patent number: 5354839Abstract: A polyimide comprising a requisite structural unit having one or more recurring structural units of the formula: ##STR1## such as the structural units of the formula ##STR2## The polyimide can have an extremely low dielectric constant and is colorless, transparent and excellent in processability and heat resistance, and also provides an aromatic diamine which is useful as a raw material monomer of the polyimide or a raw material of other various engineering plastics.Type: GrantFiled: March 31, 1993Date of Patent: October 11, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Wataru Yamashita, Yoshihiro Sakata, Toshiyuki Kataoka, Yuichi Okawa, Hideaki Oikawa, Tadashi Asanuma, Mitsunori Matsuo, Tsutomu Ishida, Keizaburo Yamaguchi, Akihiro Yamaguchi
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Patent number: 5354513Abstract: Disclosed is a polarizing film comprising a hydrophobic polymer containing a dichroic organic colorant in an oriented state which is characterized in that the dichroic organic colorant is substantially insoluble in water, organic solvents and liquid crystals and the dichroic ratio of the colorant is not less than 7 when it is measured with the film obtained by blending the colorant intimately with polyethylene terephthalate, melting the resulting blend and forming it into a film. This polarizing film has exceptionally excellent moisture resistance and thermal resistance.Type: GrantFiled: October 13, 1993Date of Patent: October 11, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuji Nakamura, Junichi Fujio, Shin Hosonuma, Masakatsu Nakatsuka, Tsutomu Nishizawa
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Patent number: 5352655Abstract: A 3-azabicyclo[3.1.0]hexane-2-one derivative represented by the following formula (I), and a herbicidal composition containing the same as a herbicidally active ingredient: ##STR1## (wherein X is a halogen atom, an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms or a haloalkyl group having 1 to 3 carbon atoms; Y is a halogen atom or an alkyl group having 1 to 3 carbon atoms; R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms; R.sub.2 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms; m is an integer of 0 to 3; n is an integer of 0 to 2; and when m is 2 or 3, the groups represented by X may be identical or different, and when n is 2, the groups represented by Y may be identical or different).Type: GrantFiled: December 6, 1993Date of Patent: October 4, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Koichi Moriyasu, Kanji Tomiya, Hideyuki Akieda, Harumichi Aoki, Makoto Suzuki, Yasunaga Iwasaki, Sadafumi Koda
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Patent number: 5352665Abstract: A medicament for prevention and remedy of diseases caused by the infection of viruses is disclosed, which is characterized by containing as an effective ingredient thereof a nonapeptide having the following amino acid configuration:pGlu-Ala-Lys-Ser-Gln-Gly-Gly-Ser-Asn or an ester and an amide at the carboxyl group of the C-terminal of the asparagine or a pharmacologically acceptable salt thereof.Type: GrantFiled: July 15, 1993Date of Patent: October 4, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Akira Awaya, Hisashi Kobayashi, Yusaku Ishizuka, Hayao Abe
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Patent number: 5352758Abstract: A mercapto compound represented by the following formula (1): ##STR1## is obtained by reacting, in the presence of a mineral acid, thiourea with a compound represented by the following formula (2): ##STR2## wherein X means a hydroxyl group or a chlorine or bromine atom, and then adding a base to alkalinize the reaction mixture so that the reaction product is hydrolyzed.The mercapto compound represented by the formula (1) can be reacted with at least one cyanate compound selected from the group consisting of polyisocyanate compounds, polyisothiocyanate compounds and isocyanate-group-containing isothiocyanate compounds to form a sulfur- containing urethane resin. A lens made of the resin is colorless and transparent, has high refractive index and low dispersion characteristics, and is excellent especially in heat resistance.Type: GrantFiled: December 20, 1993Date of Patent: October 4, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Yoshinobu Kanemura, Katsuyoshi Sasagawa, Seiichi Kobayashi
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Patent number: 5350843Abstract: A method for preparing a mixture of the halogenated alkoxyphthalocyanines represented by the formula (8) which comprises the step of reacting alkoxyphthalocyanines represented by the formula (7) and a mixture thereof with a halogenating agent in a mixed solvent of an organic solvent and water.Type: GrantFiled: July 6, 1992Date of Patent: September 27, 1994Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, IncorporatedInventors: Hisato Itoh, Takahisa Oguchi, Shin Aihara, Kenichi Sugimoto
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Patent number: 5349236Abstract: The present invention is a reusable fixture for holding a TCP carrier tape that is of simple structure, allows the carrier tape to be held securely, and eliminates powder produced by friction during mounting of the carrier tape. The structure includes a reusable fixture with a bottom element for receiving the carrier tape, a frame that surrounds and protects an outer periphery of the bottom element, and a pair of resilient tape holding members for holding the carrier tape that can be deformed by a pair of engaging members that move in opposing directions along the same line so as to allow mounting of the carrier tape, the tape holding members being attached on at least one pair of opposing inner side faces of the frame at positions to allow the tape holding members to extend above the upper surface of the mounted carrier tape.Type: GrantFiled: July 16, 1993Date of Patent: September 20, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Fumio Oshino, Masahiko Yamaki
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Patent number: 5346982Abstract: A polyimide-based heat-resistant adhesive having excellent peel strength and heat resistance comprising polyimide composed of 10 to 99% by mole of structural units having the formula (1) and 1 to 90% by mole of structural units having the formula (2) or comprising polyamic acid precursor which corresponds to the polyimide.Type: GrantFiled: June 7, 1993Date of Patent: September 13, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Shoji Tamai, Katsuaki Iiyama, Akihiro Yamaguchi
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Patent number: 5345003Abstract: A method for preparing 2,3-dichloro-1-propanol and 3-chloro-1-propanol is here disclosed which comprises the step of reacting 1,2-dichloroethane with methanol by the irradiation of light in the presence of at least one compound selected from the group consisting of europium compounds, samarium compounds and ytterbium compounds, and if necessary, in the additional presence of a zeolite.Type: GrantFiled: May 18, 1993Date of Patent: September 6, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Hiroyoshi Watanabe, Fumie Hayakawa
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Patent number: 5342974Abstract: High-purity 1,4,5,8-tetraanilidoanthraquinones which are substituted at the p-position of at least one of four anilido benzene rings by a halogen atom are good near infrared rays absorbing filters and at prepared from high purity 1,4,5,8-tetrachloroanthraquinone by reaction with a correspondingly substituted aniline or mixture of anilines in the presence of a salt of an aliphatic carboxylic acid,. a benzyl alcohol derivative and copper ions as reaction catalyst.Type: GrantFiled: December 28, 1988Date of Patent: August 30, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tsukasa Ohyama, Shizuo Kuroda, Keisuke Takuma, Hiroshi Aiga
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Patent number: 5340848Abstract: A radiation-resistant polypropylene resin composition is disclosed which comprises a polypropylene having a substantially syndiotactic structure, and if desired, a phosphorus-containing anti-oxidant, an amine-containing anti-oxidant and/or a nucleating agent. Molded articles obtained from this resin composition can be utilized as containers for foods and medicines, and their physical properties scarcely deteriorate during sterilization by radiation.Type: GrantFiled: June 9, 1993Date of Patent: August 23, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tadashi Asanuma, Shigeru Kimura, Nobutaka Uchikawa, Tetsunosuke Shiomura