Abstract: A lithium fluoride thermo-luminescent material with increased sensitivity, which comprises crystals or powdery crystallites of lithium fluoride having present therein (A) luminescent center consisting of magnesium and at least one element or more selected from the elemental group consisting of copper, silver, and gold, and (B) sensitizer therefor consisting of at least one element or more selected from the elemental group consisting of carbon, phosphorus, sulfur, arsenic, selenium and tellurium.