Patents Assigned to NGK Adrec Co., Ltd.
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Patent number: 10393449Abstract: A heat storage member including a substrate containing a SiC sintered body as a principal ingredient and a heat storage material configured to store and radiate heat by a reversible chemical reaction with a reaction medium or a heat storage material configured to store and radiate heat by physical adsorption to a reaction medium and physical desorption from a reaction medium. The substrate has a three-dimensional network structure including a skeleton having porosity of 1% or less. A void ratio of a void formed in the three-dimensional network structure of the substrate is ranging from 30 to 95%. The heat storage material is disposed at least in a part of a surface of the void in the three-dimensional network structure of the substrate.Type: GrantFiled: March 24, 2017Date of Patent: August 27, 2019Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd., Tokyo Institute of TechnologyInventors: Shinichi Miwa, Toshiharu Kinoshita, Iori Himoto, Yukitaka Kato, Jun Kariya
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Patent number: 10371460Abstract: A heat storage member including: a substrate containing a SiC sintered body as a principal ingredient; a coating layer disposed at least to a part of surface of the substrate; and a heat storage material disposed at least to a part of a surface of the coating layer and configured to store and radiate heat by a reversible chemical reaction with a reaction medium or a heat storage material configured to store and radiate heat by physical adsorption to a reaction medium and by physical desorption from a reaction medium. A softening point of the coating layer is a temperature at 1000° C. or less.Type: GrantFiled: March 24, 2017Date of Patent: August 6, 2019Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Shinichi Miwa, Toshiharu Kinoshita, Iori Himoto
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Publication number: 20170284747Abstract: A heat storage member including: a substrate containing a SiC sintered body as a principal ingredient; a coating layer disposed at least to a part of surface of the substrate; and a heat storage material disposed at least to a part of a surface of the coating layer and configured to store and radiate heat by a reversible chemical reaction with a reaction medium or a heat storage material configured to store and radiate heat by physical adsorption to a reaction medium and by physical desorption from a reaction medium. A softening point of the coating layer is a temperature at 1000° C. or less.Type: ApplicationFiled: March 24, 2017Publication date: October 5, 2017Applicants: NGK INSULATORS, LTD., NGK Adrec Co., Ltd.Inventors: Shinichi MIWA, Toshiharu KINOSHITA, Iori HIMOTO
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Publication number: 20170284746Abstract: A heat storage member including a substrate containing a SiC sintered body as a principal ingredient and a heat storage material configured to store and radiate heat by a reversible chemical reaction with a reaction medium or a heat storage material configured to store and radiate heat by physical adsorption to a reaction medium and physical desorption from a reaction medium. The substrate has a three-dimensional network structure including a skeleton having porosity of 1% or less. A void ratio of a void formed in the three-dimensional network structure of the substrate is ranging from 30 to 95%. The heat storage material is disposed at least in a part of a surface of the void in the three-dimensional network structure of the substrate.Type: ApplicationFiled: March 24, 2017Publication date: October 5, 2017Applicants: NGK INSULATORS, LTD., NGK Adrec Co., Ltd.Inventors: Shinichi MIWA, Toshiharu KINOSHITA, Iori HIMOTO
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Patent number: 8784098Abstract: A shelf assembly for firing including plural struts for supporting shelf boards arranged upright in two or more rows in a cross direction and in three or more rows in a longitudinal direction on a longitudinally-long car with tie-beams connecting the struts. A thermal stress relief structure is provided in which the struts arranged upright in the adjacent rows in the longitudinal direction are connected only with tie-beams slanted in a cross direction between the struts, with the thermal stress relief structure preventing warpage or damage of the struts resulting from a bending stress generated in the longitudinal direction at the fixing parts of the struts.Type: GrantFiled: November 17, 2009Date of Patent: July 22, 2014Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Nobuhiro Matsumoto
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Patent number: 8105675Abstract: There is disclosed a honeycomb structure 1 which is made of a ceramic material and in which a plurality of honeycomb segments 12 having cell structures 5 and porous outer walls 7 on outer peripheries of the cell structures 5 are integrated by bonding the outer walls 7 to one another with a bonding material, each of the cell structures being provided with a plurality of cells 3 constituting fluid channels divided by porous partition walls 2, wherein the bonding material contains a bio-soluble fiber. The honeycomb structure 1 of the present invention has a performance equivalent to that of a honeycomb structure in which a heretofore used ceramic fiber is contained.Type: GrantFiled: September 4, 2008Date of Patent: January 31, 2012Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Naoshi Masukawa, Atsushi Watanabe, Shuichi Ichikawa, Osamu Yamakawa, Tetsuhiro Honjo
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Patent number: 7988781Abstract: A non-settling refractory mortar is provided, which includes 100 mass % of a ceramic powder such as cordierite, mullite, alumina, or silicon carbide, 0.5 to 1.5 mass % of a clay mineral, and a colloidal oxide solution, in which the Ca content in the total solid component is defined at 0.01 to 0.5 mass % as converted to oxide so as to be provided with a thixotropic property. As a result, the coating performance is not lowered if stored for a long period after kneading, the dimension change rate after coating is small, and cracks or gaps are not formed on the coat surface. The median diameter of ceramic powder is preferred to be 10 to 50 ?m, and in order to reduce the dimension change rate after coating, the content of particles of 0.1 to 5 ?m in ceramic powder is desired to be 1 to 20%.Type: GrantFiled: February 21, 2008Date of Patent: August 2, 2011Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Tetsuhiro Honjo, Akito Higuchi
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Patent number: 7833923Abstract: A monolithic refractory material is provided by a method including the steps of kneading cordierite powder having a median diameter in a range of 10 to 50 ?m, and having a sharp mountain-like particle size distribution in which the content of particles smaller than 10 ?m is 1% or more to 36% or less, the content of particles ranging from 10 ?m or more to 50 ?m or less is 50% or more to 75% or less, and the content of particles of 51 ?m or more is 1% or more to 14% or less, and a solvent including water and alumina sol or silica sol solution.Type: GrantFiled: February 21, 2008Date of Patent: November 16, 2010Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Tetsuhiro Honjo, Akito Higuchi
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Patent number: 7820278Abstract: A refractory mortar cured material is formed in the surface or joint portions of a ceramic refractory material, such as fire bricks used in the lining of melting furnace or firing furnace used at high temperature, and includes ceramic particles with an inorganic binder having silanol group that are kneaded together with water. The kneaded mortar is applied on the surface of a ceramic base material. The average particle size of ceramic particles in the refractory mortar is 10 to 50 ?m, and the difference between the 90% particle size and the 10% particle size is 10 ?m or more to 60 ?m or less. The average pore size of the refractory mortar cured material is 5 to 25 ?m, and the width of pore size distribution is 20 to 80 ?m, so that the cracks are suppressed. In addition, the bulk density is 0.9 to 1.5 g/cm3.Type: GrantFiled: February 21, 2008Date of Patent: October 26, 2010Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Tetsuhiro Honjo, Akito Higuchi
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Patent number: 7799417Abstract: A Si—SiC based fired body includes a plurality of silicon carbide (SiC) particles serving as an aggregate, and silicon (Si) which serves as a binder and which is filled into gaps between the above-described silicon carbide particles, wherein the maximum particle diameter of the above-described silicon carbide particles is 0.5 mm or more, the content of silicon is 5 to 40 percent by mass, and the porosity is 0 to 5%. Preferably, the Si—SiC based fired body is in a thick-walled shape having a thickness of 20 to 200 mm.Type: GrantFiled: September 28, 2007Date of Patent: September 21, 2010Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Seiichi Hori
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Publication number: 20100133220Abstract: A shelf assembly for firing includes: plural struts for supporting shelf boards arranged upright in two or more rows in a cross direction and in three or more rows in a longitudinal direction on a longitudinally-long car; and tie-beams connecting between the struts. A thermal stress relief structure is provided in which the struts arranged upright in the adjacent rows in the longitudinal direction are connected only with tie-beams slanted in a cross direction between the struts, thereby solving the problems such as warpage or damage of the struts resulting from a bending stress generated in the longitudinal direction at the fixing parts of the struts whose tops are secured.Type: ApplicationFiled: November 17, 2009Publication date: June 3, 2010Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo KOMIYAMA, Nobuhiro MATSUMOTO
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Publication number: 20100025324Abstract: A filtering medium for molten metal which is excellent in inclusion removal performance and durability and further may provide sufficient throughput and a method for producing the same. A filtering medium for molten metal in the present invention includes a two-layered structure of a macropore ceramic layer at the inflow side and a micropore ceramic layer at the outflow side. The average pore diameter of the micropore ceramic layer is from 100 to 500 ?m and the average pore diameter of the macropore ceramic layer is 1.1 to 3.0 times as large as that of the micropore ceramic layer. When respective layers are formed of aggregates bonded with an inorganic binder and the inorganic binder has a needle crystal structure with an aspect ratio of 2 to 50, the inside of filtering medium may be contributed to the filtration and the compatibility between inclusion-trapping performance and lifetime may be ensured.Type: ApplicationFiled: July 2, 2009Publication date: February 4, 2010Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Akito Higuchi, Hiroyuki Hotta
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Publication number: 20090169848Abstract: The refractory mortar cured material of the invention formed in the surface or joint portions of a ceramic refractory material such as fire bricks used in the lining of melting furnace or firing furnace used at high temperature is composed by kneading ceramic particles with an inorganic binder having silanol group together with water, and forming the kneaded mortar on the surface of a ceramic base material. The average particle size of ceramic particles in the refractory mortar is 10 to 50 ?m, the difference of 90% particle size and 10% particle size is 10 ?m or more to 60 ?m or less, the average pore size of the refractory mortar cured material is 5 to 25 ?m, and the width of pore size distribution is 20 to 80 ?m, so that the cracks may be suppressed. More preferably, the bulk density is 0.9 to 1.5 g/cm3.Type: ApplicationFiled: February 21, 2008Publication date: July 2, 2009Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Tetsuhiro Honjo, Akito Higuchi
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Publication number: 20090149311Abstract: The invention relates to a Monolithic refractory material used in refractories and refractory ceramic products, and more particularly to a Monolithic refractory material having low expansibility, high strength, and crack extension resistance used for the purpose of repairing, protecting, modifying, filling, and forming the surface, adhesive surface, interface, or joint of low-expansion fire bricks and refractory ceramic products. The Monolithic refractory material of the invention is a Monolithic refractory material prepared by kneading cordierite powder, having a median diameter in a range of 10 to 50 ?m, and a sharp mountain-like particle size distribution in which the content of particles smaller than 10 ?m is 1% or more to 36% or less, the content of particles ranging from 10 ?m or more to 50 ?m or less is 50% or more to 75% or less, and the content of particles of 51 ?m or more is 1% or more to 14% or less, and a solvent composed of water and alumina sol or silica sol solution.Type: ApplicationFiled: February 21, 2008Publication date: June 11, 2009Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Tetsuhiro Honjo, Akito Higuchi
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Publication number: 20090145334Abstract: The non-settling refractory mortar of the invention contains 100 parts of ceramic powder such as cordierite, mullite, alumina, or silicon carbide, 0.5 to 1.5 parts of clay mineral, and colloidal oxide solution, in which the Ca content in total solid component is defined at 0.01 to 0.5% as converted to oxide so as to be provided with thixotropic property. As a result, the coating performance is not lowered if stored for a long period after kneading, the dimension change rate after coating is small, and cracks or gaps are not formed on the coat surface. The median diameter of ceramic powder is preferred to be 10 to 50 ?m, and in order to reduce the dimension change rate after coating, the content of particles of 0.1 to 5 ?m in ceramic powder is desired to be 1 to 20%.Type: ApplicationFiled: February 21, 2008Publication date: June 11, 2009Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Tetsuhiro Honjo, Akito Higuchi
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Patent number: 7494949Abstract: A silicon nitride-bonded SiC refractory is provided, which includes SiC as a main phase and Si3N4 and/or Si2N2O as a secondary phase and which has a bending strength of 150 to 300 MPa and a bulk density of 2.6 to 2.9. A method for producing a silicon nitride-bonded SiC refractory is also provided, which comprises a step of mixing 30 to 70% by mass of a SiC powder of 30 to 300 ?m as an aggregate, 10 to 50% by mass of a SiC powder of 0.05 to 30 ?m, 10 to 30% by mass of a Si powder of 0.05 to 30 ?m, and 0.1 to 3% by mass, in terms of oxide, of at least one member selected from the group consisting of Al, Ca, Fe, Ti, Zr and Mg.Type: GrantFiled: July 23, 2004Date of Patent: February 24, 2009Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Toshiharu Kinoshita, Tsuneo Komiyama
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Publication number: 20090011178Abstract: There is disclosed a honeycomb structure 1 which is made of a ceramic material and in which a plurality of honeycomb segments 12 having cell structures 5 and porous outer walls 7 on outer peripheries of the cell structures 5 are integrated by bonding the outer walls 7 to one another with a bonding material, each of the cell structures being provided with a plurality of cells 3 constituting fluid channels divided by porous partition walls 2, wherein the bonding material contains a bio-soluble fiber. The honeycomb structure 1 of the present invention has a performance equivalent to that of a honeycomb structure in which a heretofore used ceramic fiber is contained.Type: ApplicationFiled: September 4, 2008Publication date: January 8, 2009Applicants: NGK INSULATORS, LTD., NGK ADREC CO., LTD.Inventors: Naoshi MASUKAWA, Atsushi WATANABE, Shuichi ICHIKAWA, Osamu YAMAKAWA, Tetsuhiro HONJO
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Publication number: 20080254271Abstract: A Si—SiC based fired body includes a plurality of silicon carbide (SiC) particles serving as an aggregate, and silicon (Si) which serves as a binder and which is filled into gaps between the above-described silicon carbide particles, wherein the maximum particle diameter of the above-described silicon carbide particles is 0.5 mm or more, the content of silicon is 5 to 40 percent by mass, and the porosity is 0 to 5%. Preferably, the Si—SiC based fired body is in a thick-walled shape having a thickness of 20 to 200 mm.Type: ApplicationFiled: September 28, 2007Publication date: October 16, 2008Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Tsuneo Komiyama, Osamu Yamakawa, Seiichi Hori
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Publication number: 20060281625Abstract: The present invention provides a silicon nitride-bonded SiC refractory which contains SiC as a main phase and Si3N4 and/or Si2N2O as a secondary phase and which has a bending strength of 150 to 300 MPa and a bulk density of 2.6 to 2.9, and a method for producing a silicon nitride-bonded SiC refractory, which comprises a step of mixing 30 to 70% by mass of a SiC powder of 30 to 300 ?m as an aggregate, 10 to 50% by mass of a SiC powder of 0.05 to 30 ?m, 10 to 30% by mass of a Si powder of 0.05 to 30 ?m, and 0.1 to 3% by mass, in terms of oxide, of at least one member selected from the group consisting of Al, Ca, Fe, Ti, Zr and Mg. According to the silicon nitride-bonded SiC refractory and the method for production thereof, there can be obtained a refractory which has heat resistance, thermal shock resistance and oxidation resistance and which is high in strength and superior in creep resistance and thermal conductivity.Type: ApplicationFiled: July 23, 2004Publication date: December 14, 2006Applicants: NGK INSULATORS, LTD., NGK ADREC CO., LTD.Inventors: Toshiharu Kinoshita, Tsuneo Komiyama
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High thermal conductive material having high thermal conductivity and process for producing the same
Publication number: 20040183232Abstract: A high thermal conductive material includes substantially silicon carbide and metal silicon, and preferably is formed by impregnating the space between the bonded silicon carbide crystals with the metal silicon. The production process comprises adding an organic binder and a dispersant or a binder having a dispersing effect to a silicon carbide powder to obtain a mixture, forming the mixture by cast forming or pressure forming to obtain a formed product, treating the formed product with heat at 2,100-2,500° C. for 1-5 hours to obtain a base material, impregnating the base material with an organic resin, treating the base material with heat, and impregnating the base material with metal silicon at 1,450-1,800° C. under reduced pressure.Type: ApplicationFiled: March 18, 2004Publication date: September 23, 2004Applicants: NGK Insulators, Ltd., NGK Adrec Co., Ltd.Inventors: Toshiharu Kinoshita, Tsuneo Komiyama