Patents Assigned to Nippon Shokubai Kagaku Kogyo Co., Ltd.
  • Patent number: 5080992
    Abstract: Coloring fine particles produced by heating spheroidal coloring fine particles with an average fine particle diameter of 1-100 .mu.m obtained by suspension polymerization to a temperature of 30.degree. to 200.degree. C., thereby causing the particles to fuse together in a block without completely destroying the particle interfaces, and then crushing the block to substantially the same average particle diameter of the spheroidal coloring particle before melting, and a toner for developing electrostatic images using the same.
    Type: Grant
    Filed: August 29, 1989
    Date of Patent: January 14, 1992
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshikuni Mori, Hayato Ikeda, Mitsuo Kushino, Nobuaki Urashima, Keiichi Uehara, Masuji Izubayashi, Yoshinori Sano
  • Patent number: 5079034
    Abstract: A method of preparation of an absorbent composite in which an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization is applied to a substrate, and the monomer is polymerized while the substrate to which the aqueous solution is applied is, on both the sides, held in contact with polymerization-inert surfaces facing each other. A continuous manufacturing method includes the sequential steps of continuously passing a substrate through (1) a region applying to the substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, and (2) a region of polymerizing the monomer while maintaining the substrate, on both the sides, in contact with polymerization-inert surfaces facing each other.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: January 7, 1992
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Koji Miyake, Nobuyuki Harada, Kazumasa Kimura, Tadao Shimomura
  • Patent number: 5078934
    Abstract: In a method for the production of a fiber-reinforced thermosetting resin molding material by a procedure of leading a mixture of a liquid thermosetting resin composition with reinforcing fibers to an impregnation apparatus and deaerating the mixture and impregnating the reinforcing fibers with the resin composition, apparatus including at least one pair of vertically opposed endless belts adapted to be driven in the directions of taking in and nipping the mixture and at least one pair of vertically opposed rollers adapted to depress the mixture across the endless belts, at least one of the opposed rollers being a flexible roller possessing elasticity.
    Type: Grant
    Filed: March 28, 1989
    Date of Patent: January 7, 1992
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shigehiro Yamamoto, Katsushige Tamura, Hideo Saijyo, Terukuni Hashimoto
  • Patent number: 5077256
    Abstract: A silver catalyst for the production of ethylene oxide having 5 to 25% by weight, based on the amount of a finished catalyst, of finely divided metallic silver and 0.001 to 0.05 gram equivalent weight of cesium per kg of the finished catalyst carried on an .alpha.-alumina carrier having the outer surface thereof and the surface of pores in said carrier coated with amorphous silica, and a method for production thereof by supporting finely divided metallic silver and cesium and then subjecting the supported carrier to a high temperature heat treatment in an inert gas at a temperature of 400.degree. to 950.degree. C.
    Type: Grant
    Filed: January 19, 1990
    Date of Patent: December 31, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Takeshi Yamamoto, Shinichi Nagase, Hirohiko Tanabe
  • Patent number: 5075353
    Abstract: This invention relates to a molding material composed of a liquid thermosetting resin composition containing styrene monomer as a cross-linking component thereof and chopped glass fiber strands which can give a large molded product having high impact strength in high productivity and a method for manufacture thereof characterized by using glass fiber strands such that the number of glass filaments used in the glass fiber strands falls in the range of 600 to 1,400 per strand, the amount of a binder deposited on the glass fibers is not less than 1.0% by weight, and the percentage of styrene monomer insoluble binder falls in the range of 40 to 90% by weight.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: December 24, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Terukuni Hashimoto, Hideo Nakanishi, Shigehiro Yamamoto, Toshio Iga
  • Patent number: 5073612
    Abstract: A hydrophilic polymer having the water absorption capacity thereof 1 to 30 times to its own weight by a process of manufacture which comprises preparing a monomer component comprising (a) 2 to 25 mol % of a hydroxyl group-containing alpha,beta-ethylenically unsaturated monomer, (b) 5 to 30 mol % of a carboxyl group-containing alpha,beta-ethylenically unsaturated monomer, and (c) 93 to 45 mol % of a carboxylate group-containing alpha,beta-ethylenically unsaturated monomer, providing that the total of (b) and (c) is in the range of 98 to 75 mol %, radically polymerizing said monomer component, and heat-treating the resultant polymer thereby causing the hydroxyl group and carboxyl group possessed by the polymer to react with each other and form a crosslinked structure, a method for the production thereof, and uses found therefor including a cation sequestrating resin, a coolant and a coating material.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: December 17, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo, Co., Ltd.
    Inventors: Yoshio Irie, Shigeyasu Morihiro, Teruaki Fujiwara, Masazumi Sasabe, Kaoru Iwasaki
  • Patent number: 5071816
    Abstract: A catalyst for purification of exhaust gas from a Diesel engine wherein a catalyst component containing (a) refractory inorganic oxide, (b) oxide of at least one element selected from the group consisting of praseodymium, neodymium and samarium, and (c) at least one noble metal selected from the group consisting of platinum, palladium and rhodium provided that palladium is never selected alone is borne on a refractory three-dimensional structure.
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: December 10, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Makoto Horiuchi, Koichi Saito
  • Patent number: 5072018
    Abstract: In a method for the production of cyclohexanecarboguanamine by the reaction of cyanocylohexane with dicyandiamide in an organic solvent possessing a hydroxyl group in the molecular unit thereof at a temperature in the range of 90.degree. to 200.degree. C. in the presence of a basic catalyst, the improvement which comprises carrying out the reaction using 0.60 to 0.95 mol of dicyandiamide per mol of cyanocylohexane in an atmosphere substantially incapable of producing any effect of oxygent.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: December 10, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Hidetaka Yatagai, Osamu Kaieda, Jiro Iriguchi, Souichi Yamada, Tsuguo Takaya
  • Patent number: 5066813
    Abstract: A method for the production of a 1,3-thiazolidin-2-one represented by the general formula II: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently hydrogen atom or a lower alkyl group, which method comprises causing a 1,3-thiazolidine represented by the general formula I: ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 R.sup.5, and R.sup.6 are independently hydrogen atom or a lower alkyl group to react with urea.
    Type: Grant
    Filed: March 7, 1990
    Date of Patent: November 19, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Masao Kitano, Mitsuaki Yagisawa, Yutaka Morimoto
  • Patent number: 5057360
    Abstract: The present invention discloses a ceramic precursor composition, comprising (A) 100 parts by weight of at least one fine ceramic powder selected from the group consisting of zirconia and alumina and having an average particle diameter in the range of 0.01 to 2 microns and (B) 10 to 40 parts by weight of a copolymer produced by copolymerizing (a) 10 to 50% by weight of an alkyl or cycloalkyl acrylate having an alkyl group of 1 to 10 carbon atoms or a cycloalkyl group of 4 to 8 carbon atoms, (b) 30 to 80% by weight of an alkyl or cycloalkyl methacrylate having an alkyl group of 1 to 20 carbon atoms or a cycloalkyl group of 4 to 8 carbon atoms, (c) 1 to 5% by weight of a copolymerizable unsaturated carboxylic acid, and (d) 0 to 59% by weight of a hydroxyalkyl acrylate having a hydroxyalkyl group of 2 to 10 carbon atoms (providing that the total amount of the monomers is 100% by weight) and having a number average molecular weight in the range of 10,000 to 100,000 and a glass transition point in the range of -40.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: October 15, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shigemi Osaka, Kazuo Hata, Norikazu Aikawa, Masato Adachi
  • Patent number: 5055442
    Abstract: A carrier for catalyst using refractory particles as cores and having a refractory inorganic powder and optionally whiskers, inorganic oxide sols, or mixtures thereof deposited on the cores, and a method for the production thereof.
    Type: Grant
    Filed: February 16, 1990
    Date of Patent: October 8, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shigemi Osaka, Kazuo Hata, Tsukasa Takashashi
  • Patent number: 5054197
    Abstract: A method for joining a structural member made of a synthetic resin such as fiber reinforced plastic (FRP) with a further synthetic resin or other structural member. The method is effective when using synthetic resin members instead of conventional lumber or steel members in a main framework of a cooling tower. FRP members increase the corrosion resistance and simplify the assembly of such towers.
    Type: Grant
    Filed: March 13, 1990
    Date of Patent: October 8, 1991
    Assignees: Ishikawajima-Harima Jukogyo Kabushiki Kaisha, Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kanji Kato, Kesaaki Mochizuki, Akira Hamamoto, Hiroshi Oya, Kozo Ando, Kazuo Namaritani, Kenichi Fujita, Futami Nagaoka
  • Patent number: 5045233
    Abstract: A method for inhibiting polymerization of a maleimide, which comprises adding to said maleimide, as a polymerization inhibitor, at least one compound selected from the group consisting of thiodipropionic esters, 4-t-butyl-catechol, 2,4-dimethyl-6-t-butyl phenol, 2,5-di-t-butylhydroquinone, 2-t-butyl-hydroquinone, 2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-trizaine, 2,2'-thiobis-(4-methyl-6-t-butylphenol), 4,4'-thiobis-(6-butyl-m-cresol), and triethyleneglycol-bis-[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate].
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: September 3, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuichi Kita, Kentaro Sakamoto, Masao Baba, Tomoaki Tobo
  • Patent number: 5043318
    Abstract: The present invention provides dye transfer type thermal printing sheet comprising a base sheet, a dye-containing layer formed on the base sheet and a dye-permeable layer which is formed on the dye-containing layer and comprises at least one water dispersible polysiloxane graft polymer which is obtainable by polymerizing (B) 0.05 to 10% by weight of a polymerizable silane compound, (C) 1 to 30% by weight of an unsaturated organic acid and (D) 40 to 97.95% by weight of a monomer which is copolymerizable with the silane compound (B) and the unsaturaed organic acid (C) in the presence of (A) 1 to 20% by weight of a polysiloxane having terminal hydroxyl groups (provided that the total of the components (A), (B), (C) and (D) is 100% by weight) in an organic solvent except an alcohol or at least one salt of said graft polymer with a base, which has good storage stability, generates images with improve weather durability and prevents great decrease of print density as increase of the number of printing times.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: August 27, 1991
    Assignees: Matsushita Electric Industrial Co., Ltd., Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tetsuji Kawakami, Hiromu Matsuda, Sigeru Tanimori, Yoshinori Sano
  • Patent number: 5039787
    Abstract: Methods are disclosed for the production of (I) a cationic water-soluble resin by the reaction of a polyethylene glycol polyhalohydrin ether resulting from the reaction between polyethylene glycol and an epihalohydrin with an aziridine compound and (II) and (III) cationic water-soluble resins by the reaction of (I) the resin with an epihalohydrin and/or a polyfunctional epoxy compound in the presence or absence of a polyalkyleneimine. The resins (I), (II), and (III) are stable over a wide range of pH value and are useful as a water-treating agent.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: August 13, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo, Co., Ltd.
    Inventors: Yasumasa Tanaka, Shigehiro Nishimura, Masatoshi Kurahashi, Yugi Sugiura, Yoshinori Sano
  • Patent number: 5026880
    Abstract: A method for the production of a 1,3-dioxolane represented by the general formula III: ##STR1## wherein R.sup.1 is hydrogen atom or an alkyl group of 1 to 5 carbon atoms and R.sup.2 is hydrogen atom or an alkyl group of 1 to 2 carbon atoms or a phenyl group, which method comprises reacting an aldehyde represented by the general formula I ##STR2## wherein R.sup.1 has the same meaning as defined above, with an alkylene oxide represented by the general formul II: ##STR3## wherein R.sup.2 has the same meaning as defined above, in an alkylene glycol solvent corresponding to said alkylene oxide in the presence of at least one catalyst selected from the group consisting of bromides of alkali metals, iodides of alkali metals, bromides of alkaline earth metals, and iodides of alkaline earth metals.
    Type: Grant
    Filed: August 9, 1990
    Date of Patent: June 25, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshiaki Urano, Yukio Kadono
  • Patent number: 5026800
    Abstract: Water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less are prepared by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the gel-like polymer so obtained, and crosslinking the surface of the polymer powder. In an alternative process, an aqueous solution of the monomer having a viscosity greater than 15 cps is dispersed in a hydrophobic organic solvent and polymerized to obtain a polymer powder, and the surface of the polymer powder is crosslinked.
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: June 25, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kazumasa Kimura, Kinya Nagasuna, Takashi Namba, Kenji Kadonaga, Koji Miyake, Tadao Shimomura
  • Patent number: 5021227
    Abstract: The present invention concerns a method of removing nitrogen oxides in exhaust gases from a diesel engine by using a catalyst in a reacter under the presence of ammonia, wherein a humidity of in-take air as a specific factor and one or more of engine power, fuel consumption amount of engine, temperature of engine in-take air and exhaust gas temperature as selective factors are measured respectively as the measuring factors and the flow rate of ammonia is controlled based on measured values and ammonia is supplied to an exhaust gas flow channel from the engine to the reactor.
    Type: Grant
    Filed: February 2, 1990
    Date of Patent: June 4, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Motonobu Kobayashi, Futoru Kinoshita, Mitsuharu Hagi, Akira Inoue, Terushige Uno
  • Patent number: 5015617
    Abstract: A catalyst for purifying exhaust gas produced by coating honeycomb carriers of monolithic structure with a catalyst composition comprising cerium oxide particles stabilized with (a) zirconia or (b) zirconia and at least one member selected from the group consisting of yttria and calcia, refractory inorganic oxide particles, 0.02 to 2% by weight of rhodium based on said catalyst composition, and 0 to 10% by weight of at least one platinum-family metal selected from the group consisting of platinum and palladium based on said catalyst composition.
    Type: Grant
    Filed: April 12, 1989
    Date of Patent: May 14, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tomohisa Ohata, Kazuo Tsuchitani, Shinya Kitaguchi
  • Patent number: 5000929
    Abstract: An exhaust gas purification catalyst for purifying carbonaceous fine particles comprising a refractory three-dimensional structure and deposited thereon, (a) a refractory inorganic oxide, (b) palladium and (c) an oxide of at least one element selected from the group consisting of praseodymium, neodymium and samarium as catalyst components.
    Type: Grant
    Filed: February 23, 1990
    Date of Patent: March 19, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Makoto Horiuchi, Yasuo Ikeda, Koichi Saito