Patents Assigned to Nippon Shokubai Kagaku Kogyo Co., Ltd.
  • Patent number: 4994520
    Abstract: A carbon black-graft polymer, produced by causing a polymer possessing within the molecular unit thereof at least one reactive group selected from the class consisting of aziridine group, oxazoline group. N-hydroxyalkylamide group, epoxy group, and thioepoxy group to react with carbon black. The polymer can be used as a toner for electrostatically charged image, resin composition, coating composition, ink for thermographic transfer, coating agent for magnetic recording medium, rubber composition, and carbon black dispersion and the like.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: February 19, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hayato Ideda, Nobuaki Urashima, Masuji Izubayashi, Shigeru Tanimori, Yoshihiro Arita, Kiyoshi Kawamura, Kenji Minami, Yoshinori Sano
  • Patent number: 4989538
    Abstract: Described herein is a resin composition sprinkling mechanism useful in the production of a fiber reinforced resinous molding material, the sprinkling mechanism employing a transfer roller which is resiliently abutted against a sprinkling roller rotating in a fixed position to sprinkle completely in finely divided form a liquid resin composition being transferred along the surface of the transfer roller, thereby permitting to produce continuously a fiber reinforced resinous molding material of uniform quality.
    Type: Grant
    Filed: October 25, 1989
    Date of Patent: February 5, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Katsushige Tamura, Shigehiro Yamamoto, Hideo Saijyo
  • Patent number: 4985514
    Abstract: The present invention is a method for the production of a water absorbent resin, which comprises preparing a monomer component possessing an ability to form a cross-linked structure and convert itself into a hydrated gel polymer during the course of aqueous solution polymerization, possessing an acid group-containing monomer content of at least 50 mol %, and having 10 to 50 mol % of said acid group-containing monomer neutralized and subjecting said monomer component to aqueous solution polymerization within a reaction vessel having a plurality of rotary shafts each fitted with stirring blades.
    Type: Grant
    Filed: August 9, 1988
    Date of Patent: January 15, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kazumasa Kimura, Takumi Hatsuda, Yoshio Irie, Tadao Shimomura
  • Patent number: 4983710
    Abstract: A method for the production of methylolaminotriazine condensate by the reaction of cyclohexanecarboguanamine (A) and formaldehyde (B), which method comprises preparing a solution of formaldehyde (B) or a solution containing cyclohexanecarboguanamine (A) and formaldehyde (B) in such amounts that the molar ratio of (A)/(B) will be not more than 1/2.5, keeping the temperature of said solution in the range of 55.degree. to 150.degree. C. and, at the same time, gradually supplying cyclohexanecarboguanaimine (A) thereto.
    Type: Grant
    Filed: August 10, 1989
    Date of Patent: January 8, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Hidetaka Yatagai, Jiro Iriguchi, Souichi Yamada, Tsuguo Takaya
  • Patent number: 4980416
    Abstract: A heat-resistant resin composition, comprising (A) 30 to 95% by weight of at least oen unsaturated ester compound selected from the group consisting of (I) unsaturated ester compounds represented by the formula I: ##STR1## wherein R.sup.1 s independently stand for one member selected from the class consisting of ##STR2## wherein R.sup.3 and R.sup.4 independently stand for a hydrogen atom or a methyl group, and a hydrogen atom, and at least one R.sup.1 stands for ##STR3## wherein R.sup.3 and R.sup.4 independently stand for a hydrogen atom or a methyl group, and R.sup.2 s independently stand for an atom or an organic group selected from the class consisting of a hydrogen atom, halogen atoms, a methoxy group, and alkyl groups of 1 to 5 carbon atoms, and m stands for 0 or an integer in the range of 1 to 10, and (II) unsaturated ester compounds represented by the formula II; ##STR4## wherein R.sup.5 s independently stand for one member selected from the class consisting of ##STR5## wherein R.sup.3 and R.sup.
    Type: Grant
    Filed: January 3, 1989
    Date of Patent: December 25, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Toshio Awaji, Takao Omi, Kenichi Ueda
  • Patent number: 4980483
    Abstract: A method for the production of a maleimide, which comprises effecting a former-stage reaction by adding maleic anhydride and a primary amine in amounts such that the molar ratio of said maleic anhydride to said primary amine is less than 1 under application of heat to a water-insoluble or water-immisible inert organic solvent containing an acid catalyst and subsequently carrying out a latter-stage reaction by adding to the reaction system maleic anhydride in an amount such that the molar ratio of the total amount of maleic anhydride to be added to said reaction system to the total amount of said primary amine added to said reaction system exceeds 1.
    Type: Grant
    Filed: February 14, 1989
    Date of Patent: December 25, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuichi Kita, Masakazu Nakagawa, Hitoshi Kanei, Akio Fukui
  • Patent number: 4977118
    Abstract: A method for regeneration of catalyst which comprises phosphorus and alkali metal element and/or alkaline earth metal element and was deteriorated by use to produce aziridine compound represented by the general formula ##STR1## wherein R is hydrogen, a methyl group or an ethyl group, by a catalytic vapor-phase intramolecular dehydration reaction of alkanolamine represented by the general formula ##STR2## wherein R is as defined in the formula (II), X is OH or NH.sub.2, and Y is either NH.sub.2 when X is OH or OH when X is NH.sub.2, characterized in that the deteriorated catalyst is contacted with gaseous volatile phosphorus compound.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: December 11, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Hideaki Tsuneki, Kimio Ariyoshi, Atusi Moriya, Michio Ueshima
  • Patent number: 4973689
    Abstract: In a method for the production of cyclohexanecarboguanamine by the reaction of cyanocyclohexane with dicyandiamide in an organic solvent possessing a hydroxyl group in the molecular unit thereof at a temperature in the range of 90.degree. to 200.degree. C. in the presence of a basic catalyst, the improvement which comprises carrying out the reaction using 0.60 to 0.95 mol of dicyandiamide per mol of cyanocyclohexane in an atmosphere substantially incapable of producing any effect of oxygen.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: November 27, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Hidetaka Yatagai, Osamu Kaieda, Jiro Iriguchi, Souichi Yamada, Tsuguo Takaya
  • Patent number: 4973440
    Abstract: A method for the production of a fiber-reinforced molding material of thermosetting resin, which method comprises supplying a liquid thermosetting resin composition to at least one spreading roller disposed as separated by a gap of not more than 5 mm from the terminal of a supply unit, rotated at speed in the range of 1,000 to 7,000 r.p.m., and provided on the circumferential source thereof with at least one ridge or groove formed parallelly to the rotary axis thereof, thereby causing the liquid thermosetting resin composition to be spread out in the form of particles, allowing said particles to be mixed with separately spread reinforcing fibers, piling the resultant mixture, and then deaerating the piled mixture thereby causing the reinforcing fibers in the piled mixture to be impregnated with the resin composition.
    Type: Grant
    Filed: March 15, 1989
    Date of Patent: November 27, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Katsushige Tamura, Shigehiro Yamamoto, Terukuni Hashimoto, Hideo Saijyo
  • Patent number: 4973640
    Abstract: A resin having a low specific gravity, an excellent impact resistance and a high refractive index can be produced by radical polymerization of a polymerizable monomer mixture composed essentially of [I] at least one polymerizable monomer selected from the group consisting of specific polyfunctional (meth)acrylates, [II] at least one polymerizable monomer selected from the group consisting of styrene and alpha-methylstyrene, and [III] at least one polymerizable monomer selected from the group consisting of unsaturated nitriles. This invention provides an optical material composed of said resin, especially, a lens.
    Type: Grant
    Filed: September 8, 1989
    Date of Patent: November 27, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tatsuhito Matsuda, Yasuaki Funae, Masahiro Yoshida, Tetsuya Yamamoto, Tsuguo Takaya
  • Patent number: 4973632
    Abstract: This invention relates to a water-absorbent resin of a new, novel type obtained from polymerization of water-soluble ethylenically unsaturated monomer and a process for producing this resin.The water-absorbent resin in this invention has average particle diameter in a specially defined range and a narrow range of particle distribution, being superior in water-absorption capacity, and also, being superior in handling properties in a point of that, when being mixed with liquid, formation of a fish-eye is absent. The water-absorbent resin shows an angle-lacking, non-sphere shape and, in a case of shape like this, is superior in handling properties in a point that being hard in falling off from an basis material.
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: November 27, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kinya Nagasuna, Takashi Namba, Koji Miyake, Kazumasa Kimura, Tadao Shimomura
  • Patent number: 4972025
    Abstract: A cement dispersant containing a water-soluble polymer containing at least 10 mol % of structural units represented by the general formula I: ##STR1## wherein X is H or CH.sub.2 R.sup.1, R.sup.1 is H or COO--[--A).sub.m B).sub.n ]H, R is H, CH.sub.3, or COO--[--A).sub.m B).sub.n ]H (providing that R is H where X is CH.sub.2 R.sup.1), A is iminoalkylene having 2 to 4 carbon atoms, B is oxyalkylene having 2 to 4 carbon atoms, m is an average number in the range of 0.1 to 10, n is O or an average positive number not more than 100, --A).sub.m may be in a linear or branched configuration, wherein the sequence of A and B in the segment in parenthesis may be regular or random.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: November 20, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo, Co., Ltd.
    Inventors: Tsuneo Tsubakimoto, Yoshinori Sano, Hideyuki Tahara, Tsuyoshi Hirata, Hiroshi Ito, Yasuhiro Mori
  • Patent number: 4966980
    Abstract: A process for producing an aziridine compound represented by the following general formula ##STR1## wherein R represents hydrogen, or a methyl or ethyl group, which comprises intramolecularly dehydrating an alkanolamine represented by the following formula ##STR2## wherein R is as defined, X is OH or NH.sub.2, and Y is NH.sub.2 when X is OH, and OH when X is NH.sub.
    Type: Grant
    Filed: November 7, 1988
    Date of Patent: October 30, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co. Ltd.
    Inventors: Teruo Kamei, Yuuji Shimasaki, Hideaki Tsuneki, Koichi Yamamoto, Yutaka Morimoto, Michio Ueshima
  • Patent number: 4962205
    Abstract: Method for the transportation or storage of N-phenyl maleimide, which method comprises mixing N-phenyl maleimide with maleic anhydride in a ratio of 1 to 90 parts by weight of N-phenyl maleimide to 99 to 10 parts by weight of maleic anhydride and handling the resultant mixture in a molten state in the presence of a polymerization inhibitor, and a composition of liquid state.
    Type: Grant
    Filed: August 11, 1989
    Date of Patent: October 9, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo, Co., Ltd.
    Inventors: Yuichi Kita, Kazuo Kishino, Akio Fukui
  • Patent number: 4959060
    Abstract: A body fluid-absorbing article such as, for example, a disposable diaper is provided with at least one absorbent member comprising 50 to 99% by weight of a fibrous material and 50 to 1% by weight of an absorbent polymer, which absorbent member contains at least one compound (A) selected from the group consisting of sulfur-containing reducing agents, antioxidants, and oxidizing agents. By the action of the compound (A), the swelled gel of the absorbent polymer formed in consequence of absorption of body fluid is prevented from being deteriorated or decomposed by aging.
    Type: Grant
    Filed: December 12, 1989
    Date of Patent: September 25, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tadao Shimomura, Nobuyuki Harada, Kunihiko Ishizaki
  • Patent number: 4957717
    Abstract: A method of disposing of organic chlorine compounds by burning them in contact with a catalyst of composite oxides selected from titanium-silicon composite oxides, titanium-zirconium composite oxides, and titanium-silicon-zirconium composite oxides, whereby the resulting hydrogen chloride (HCl) is adsorbed by a basic absorbent.
    Type: Grant
    Filed: January 4, 1990
    Date of Patent: September 18, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Seiichiro Imamura, Sadao Terui, Kunio Sano, Kazuyoshi Nishikawa, Akira Inoue
  • Patent number: 4956493
    Abstract: A process for producing a methacrylic ester which comprises catalytically oxidizing isobutylene, tert-butanol, methacrolein or isobutyl aldehyde in a vapor phase; removing light-boiling substances form the resulting reaction product by distillation or stripping; extracting methacrylic acid from the resulting methacrylic acid aqueous solution using a saturated chain aliphatic hydrocarbon having 6 to 9 carbon atoms as a solvent; recovering the solvent from the obtained solvent solution of methacrylic acid; esterifying the resulting methacrylic acid by the reaction of it with a lower aliphatic alcohol or a lower alicyclic alcohol having 1 to 12 carbon atoms using a porous strongly acidic cation exchange resin as a catalyst for esterfication; and then subjecting the thus obtained esterification reaction product to a purification step.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: September 11, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Masatoshi Ueoka, Syoichi Matsumoto, Hiroshi Yoshida, Masao Baba
  • Patent number: 4954650
    Abstract: This invention relates to a improved method for the production of methacrylic acid by the steps of subjecting isobutylene and/or tertiory hutanol to catalytic vapor-phase oxidation with molecular oxygen in a first reactor, then supplying the resultant gax mixture to a second reactor, a rodlike or plate like insert set being placed in the empty space of gas inlet part of the tube of said second reactor.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: September 4, 1990
    Assignees: Sumitomo Chemical Company, Ltd., Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tadashi Abe, Mitsuyoshi Manabe, Koji Deguchi, Hiroyuki Uhara, Yukio Aoki
  • Patent number: 4946620
    Abstract: The present invention discloses an acid gas absorbent composition, comprising a diethylene glycol dialkyl ether represented by the general formula I:R.sup.1 O(C.sub.2 H.sub.4 O).sub.2 R.sup.2 (I)wherein R.sup.1 and R.sup.2 are independently an alkyl group of 1 to 4 carbon atoms, and a polyethylene glycol dialkyl ether represented by the general formula II:R.sup.3 O(C.sub.2 H.sub.4 O).sub.n R.sup.4 (II)wherein R.sup.3 and R.sup.4 are independently an alkyl group of 1 to 4 carbon atoms and n is an integer in the range of 3 to 8.
    Type: Grant
    Filed: November 21, 1988
    Date of Patent: August 7, 1990
    Assignees: Nippon Shokubai Kagaku Kogyo Co., Ltd., Norton Company
    Inventors: Yukio Kadono, Yoshiaki Urano, Fumio Watanabe
  • Patent number: 4940749
    Abstract: A carbon black-graft polymer, produced by causing a polymer possessing within the molecular unit thereof at least one reactive group selected from the class consisting of aziridine group, oxazoline group. N-hydroxyalkylamide group, epoxy group, and thioepoxy group to react with carbon balck. The polymer can be used as a toner for electrostatically charged image, resin composition, coating composition, ink for thermographic transer, coating gent for magnetic recording medium, rubber composition, and carbon black dispersion and the like.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: July 10, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hayato Ikeda, Nobuaki Urashima, Masuji Izubayashi, Shigeru Tanimori, Yoshihiro Arita, Kiyoshi Kawamura, Kenji Minami, Yoshinori Sano