Patents Assigned to Nippon Yakin Kogyo Co., Ltd.
  • Publication number: 20240011126
    Abstract: A nickel alloy having superior surface properties by controlling the composition of non-metallic inclusions that affect surface properties, and a method for producing the same. A nickel alloy includes: all by mass %, Ni: 99.0% or more, C: 0.020% or less, Si: 0.01 to 0.3%, Mn: 0.3% or less, S: 0.010% or less, Cu: 0.2% or less, Al: 0.001 to 0.1%, Fe: 0.4% or less, O: 0.0001 to 0.0050% or less, Mg: 0.001 to 0.030%, Ca: 0.0001 to 0.0050%, B: 0.0001 to 0.01%, and the balance of inevitable impurities; the alloy including non-metallic inclusions, in which the non-metallic inclusions include one or more of MgO, CaO, CaO—Al2O3-based oxides, CaO—SiO2-based oxides, CaO—MgO-based oxides, and MgO·Al2O3, the MgO·Al2O3 has a number ratio of number 50% or less with respect to all oxide-based, non-metallic inclusions.
    Type: Application
    Filed: March 7, 2022
    Publication date: January 11, 2024
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Fumiaki KIRIHARA, Daiki OGASAWARA
  • Publication number: 20230357879
    Abstract: A highly corrosion-resistant austenite stainless steel that, even when exposed to temperatures in a range in which a ? phase is precipitated and corrosion resistance varies greatly, the stainless steel remains corrosion resistant, the steel consisting of, in mass %: C: 0.005 to 0.030%, Si: 0.05 to 0.30%, Mn: 0.05 to 0.40%, P: 0.005 to 0.050%, S: 0.0001 to 0.0010%, Ni: 22.0 to 32.0%, Cr: 19.0 to 28.0%, Mo: 5.0 to 7.0%, N: 0.18 to 0.25%, Al: 0.005 to 0.100%, Cu: 0.05 to 0.50%, W: not more than 0.05%, Sn: 0.0005 to 0.0150%, Co: 0.030 to 0.300%, B: 0.0005 to 0.0050%, Fe as a remainder and inevitable impurities, in which the stainless steel satisfies the following formula (1), an area ratio of ? phase is not more than 1%, and CPT based on ASTM G48 Method C as corrosion resistance property is not less than 60° C. 0.05?10[% B]+2[% P]+6[% Sn]+0.03[% Si]?0.
    Type: Application
    Filed: July 27, 2021
    Publication date: November 9, 2023
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Takayuki WATANABE, Shigeru HIRATA
  • Publication number: 20230287550
    Abstract: Fe—Ni—Cr alloy contains, in mass, from 0.001% to 0.050% of C, from 0.18% to 1.00% of Si, from 0.20% to 0.80% of Mn, 0.030% or less of P, 0.0001% to 0.0020% of S, from 12% to 21% of Ni, from 18% to 24% of Cr, from 0.20% to 1.50% of Mo, 0.30% or less of Cu, from 0.10% to 0.70% of Al, from 0.10% to 0.70% of Ti, from 0.002% to 0.015% of N, from 0.0001% to 0.0010% of B, from 0.0002% to 0.0030% of O, 0.002% or less of Ca, and from 0.0010% to 0.0150% of REM in total, said REM being composed of one or more elements selected from among La, Ce and Y, with the balance being made up of Fe and unavoidable impurities, and which satisfies formulae 1 and 2. Formula 1: 0.575xNi+1.25xCr+3.43xMo-39xP-5.3xAl-641xREM-1018xO?20.0 Formula 2: 1.5xMn+41.3xSi+1469xS-1.67xAl-1.34xTi-150xO-620xREM?5.0.
    Type: Application
    Filed: December 20, 2021
    Publication date: September 14, 2023
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Kazuhito TAKIMOTO, Tomofumi FUKUYAMA, Murotsune YABE
  • Publication number: 20230250518
    Abstract: A highly corrosion-resistant Ni—Cr Mo—N alloy including in weight %, Ni: 22.0% or more, Cr: 22.0% or more, Mo: 5.0% or more, N: 0.180% or more, Si, Al, Mn, Fe as a remainder, and inevitable impurities, wherein the composition satisfies the following Formulas (1) to (3), and an area ratio of a sigma phase in a cross-sectional structure measured by EBSD after holding at 950° C. for 30 minutes is 1.0% or less Cr+3.3×Mo+16×N?43.0??(1) 7.3×Mo—Ni?21.0??(2-1) 1.3×?5.7??(2-2) 1.6×Si+0.99×Mn+2.2×Al?0.95??(3).
    Type: Application
    Filed: July 27, 2021
    Publication date: August 10, 2023
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Takayuki WATANABE, Shigeru HIRATA
  • Publication number: 20230151458
    Abstract: A Ni—Cr—Mo—Nb alloy consists of, in mass %, C: not more than 0.020%, Si: 0.02 to 1.0%, Mn: 0.02 to 1.0%, P: not more than 0.03%, S: not more than 0.005%, Cr: 18.0 to 24.0%, Mo: 8.0 to 10.0%, Al: 0.005 to 0.4%, Ti: 0.1 to 1.0%, Fe: not more than 5.0%, Nb: 2.5 to 5.0%, N: 0.002 to 0.02%, and at least one of W: 0.02 to 0.3% and V: 0.02 to 0.3%, and Ni as a remainder and inevitable impurities, in which an freely selected cross section of alloy, sum of number of particles of NbC carbide and (Ti, Nb)N nitride is 100 to 1000 particles/mm2, number of particles of the NbC carbide is not more than 40 particles/mm2, and number of particles of the (Ti, Nb)N nitride is 100 to 1000 particles/mm2.
    Type: Application
    Filed: March 31, 2021
    Publication date: May 18, 2023
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Taiki MAEDA, Fugao WEI
  • Patent number: 11535914
    Abstract: A duplex stainless steel has reduced precipitation risks of Al nitride and Cr nitride which are undesirable precipitates, and has superior low temperature toughness. The duplex stainless steel has in mass %, indicated as “%”, C: 0.001 to 0.030%, Si: 0.05 to 0.5%, S: not more than 0.002%, Ni: 6 to 7.5%, Cr: 23 to 26%, Mo: 2 to 4.0%, N: 0.20 to 0.40%, Al: 0.005 to 0.03%, Mn: 0.05 to 0.3%, B: 0.0001 to 0.0050% and Fe, and the remainder being inevitable impurities. The duplex stainless steel has an impact value of not less than 87.5 J/cm2 at ?46±2° C. as defined in Japanese Industrial Standards Z2242.
    Type: Grant
    Filed: June 26, 2019
    Date of Patent: December 27, 2022
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Takayuki Watanabe, Fugao Wei
  • Publication number: 20210317555
    Abstract: Alloy compositions, structures, and production methods for an appropriate slit cut surface shape improve productivity by increasing welding speed and stabilizing quality during high speed welding in Ti-containing Fe—Ni—Cr alloy production. The Ti-containing Fe—Ni—Cr alloy contains, hereinafter in weight %, C: 0.001 to 0.03%, Si: 0.05 to 1.25%, Mn: 0.10 to 2.00%, P: 0.001 to 0.030%, S: 0.0001 to 0.0030%, Ni: 15 to 50%, Cr: 17 to 25%, Al: 0.10 to 0.80%, Ti: 0.10 to 1.5%, N: 0.003 to 0.025%, 0: 0.0002 to 0.007%, Fe as a remainder, and inevitable impurities, and when the number and size of titanium nitrides contained in material are evaluated in a freely selected field of view of 5 mm2, the titanium nitrides having sizes of not more than 15 ?m are not less than 99.3% of total of the titanium nitrides.
    Type: Application
    Filed: September 17, 2019
    Publication date: October 14, 2021
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Toshio MIURA, Kazuhito TAKIMOTO, Fumiaki KIRIHARA, Shigeru HIRATA
  • Patent number: 11118250
    Abstract: Ti, N, Al, Mg, and Ca concentrations are controlled in order to prevent aggregation of TiN inclusions. Furthermore, not only is a Fe—Cr—Ni alloy having superior surface property provided, but also a method is proposed in which the Fe—Cr—Ni alloy is produced at low cost using commonly used equipment. The Fe—Cr—Ni alloy includes C?0.05%, Si: 0.1 to 0.8%, Mn: 0.2 to 0.8%, P?0.03%, S?0.001%, Ni:16 to 35%, Cr: 18 to 25%, Al: 0.2 to 0.4%, Ti: 0.25 to 0.4%, N?0.016%, Mg: 0.0015 to 0.008%, Ca?0.005%, O: 0.0002 to 0.005%, freely selected Mo: 0.5 to 2.5% in mass % and Fe and inevitable impurities as the remainder, wherein Ti and N satisfy % N×% Ti?0.0045 and the number of TiN inclusions not smaller than 5 ?m is 20 to 200 pieces/cm2 at a freely selected cross section.
    Type: Grant
    Filed: June 21, 2017
    Date of Patent: September 14, 2021
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Kenji Mizuno, Hidekazu Todoroki, Yosuke Baba, Yusuke Kobayashi, Waki Nishijima
  • Patent number: 10927438
    Abstract: Provided is an Fe—Ni—Cr alloy that has excellent surface characteristics and enables formation of a blackened coating having excellent blackening characteristics and peeling resistance. The Fe—Ni—Cr alloy has a chemical composition containing, by mass %, C, Si, Mn, P, S, Cr, Ni, Mo, Co, Cu, N, Ti, Al, O, and H, the balance being Fe and inevitable impurities, and satisfying formulae (1) to (4): (1) T1=11×[% N]+0.1; (2) T2=?39×[% N]?1.0; (3) A1=7.5×[% N]+0.1; (4) A2=?42.5×[% N]+1.0, where [% M] represents content (mass %) of element M in the alloy, and T1, T2, A1, and A2 satisfy relationships T1<[% Ti]<T2 and A1<[% A1]<A2.
    Type: Grant
    Filed: March 14, 2017
    Date of Patent: February 23, 2021
    Assignee: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Kazuhiro Yamakawa, Shigeru Hirata, Kun Wang, Hidekazu Todoroki
  • Publication number: 20200347488
    Abstract: Ti, N, Al, Mg, and Ca concentrations are controlled in order to prevent aggregation of TiN inclusions. Furthermore, not only is a Fe—Cr—Ni alloy having superior surface property provided, but also a method is proposed in which the Fe—Cr—Ni alloy is produced at low cost using commonly used equipment. The Fe—Cr—Ni alloy includes C?0.05%, Si: 0.1 to 0.8%, Mn: 0.2 to 0.8%, P?0.03%, S?0.001%, Ni:16 to 35%, Cr: 18 to 25%, Al: 0.2 to 0.4%, Ti: 0.25 to 0.4%, N?0.016%, Mg: 0.0015 to 0.008%, Ca?0.005%, O: 0.0002 to 0.005%, freely selected Mo: 0.5 to 2.5% in mass % and Fe and inevitable impurities as the remainder, wherein Ti and N satisfy % N×% Ti?0.0045 and the number of TiN inclusions not smaller than 5 ?m is 20 to 200 pieces/cm2 at a freely selected cross section.
    Type: Application
    Filed: June 21, 2017
    Publication date: November 5, 2020
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Kenji MIZUNO, Hidekazu TODOROKI, Yosuke BABA, Yusuke KOBAYASHI, Waki NISHIJIMA
  • Publication number: 20200048748
    Abstract: A duplex stainless steel has reduced precipitation risks of Al nitride and Cr nitride which are undesirable precipitates, and has superior low temperature toughness. The duplex stainless steel has in mass %, indicated as “%”, C: 0.001 to 0.030%, Si: 0.05 to 0.5%, S: not more than 0.002%, Ni: 6 to 7.5%, Cr: 23 to 26%, Mo: 2 to 4.0%, N: 0.20 to 0.40%, Al: 0.005 to 0.03%, Mn: 0.05 to 0.3%, B: 0.0001 to 0.0050% and Fe, and the remainder being inevitable impurities. The duplex stainless steel has an impact value of not less than 87.5 J/cm2 at ?46±2° C. as defined in Japanese Industrial Standards Z2242.
    Type: Application
    Filed: June 26, 2019
    Publication date: February 13, 2020
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Takayuki WATANABE, Fugao WEI
  • Patent number: 10513756
    Abstract: The Ni-based alloy exhibits superior grain boundary corrosion resistance including C: 0.005 to 0.03 mass %, Si: 0.02 to 1 mass %, Mn: 0.02 to 1 mass %, P: not more than 0.03 mass %, S: not more than 0.005 mass %, Cr: 18 to 24 mass %, Mo: 8 to 10 mass %, Nb: 2.5 to 5.0 mass %, Al: 0.05 to 0.4 mass %, Ti: not more than 1 mass %, Fe: not more than 5 mass %, N: not more than 0.02 mass %, and Ni as a remainder and inevitable impurities. The C concentration range, the ratio of (Nb, Ti) C carbides to all carbides is not less than 90%, and the number of (Nb, Ti) C carbides satisfies the following formula: ?30×T+37220=<number of (Nb, Ti) C carbides (number/mm2)=<?7.7×T2+15700×T?7866000 under a condition of 2000×% C+890=<T(temperature ° C.)=<1150.
    Type: Grant
    Filed: August 28, 2018
    Date of Patent: December 24, 2019
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Takafumi Kikutake, Fugao Wei
  • Publication number: 20190360079
    Abstract: Provided is an Fe—Ni—Cr alloy that has excellent surface characteristics and enables formation of a blackened coating having excellent blackening characteristics and peeling resistance. The Fe—Ni—Cr alloy has a chemical composition containing, by mass %, C, Si, Mn, P, S, Cr, Ni, Mo, Co, Cu, N, Ti, Al, O, and H, the balance being Fe and inevitable impurities, and satisfying formulae (1) to (4): (1) T1=11×[% N]+0.1; (2) T2=?39×[% N]?1.0; (3) A1=7.5×[% N]+0.1; (4) A2=?42.5×[% N]+1.0, where [% M] represents content (mass %) of element M in the alloy, and T1, T2, A1, and A2 satisfy relationships T1<[% Ti]<T2 and A1<[% A1]<A2.
    Type: Application
    Filed: March 14, 2017
    Publication date: November 28, 2019
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Kazuhiro YAMAKAWA, Shigeru HIRATA, Kun WANG, Hidekazu TODOROKI
  • Patent number: 10400317
    Abstract: Fe—Cr—Ni—Mo alloy having superior surface properties and a method for producing the same using a commonly used apparatus at low cost. The Fe—Cr—Ni—Mo alloy has (% indicates mass %): C: ?0.03%, Si: 0.15 to 0.5%, Mn: 0.1 to 1%, P: ?0.03%, S: ?0.002%, Ni: 20 to 32%, Cr: 20 to 26%, Mo: 0.5 to 2.5%, Al: 0.1 to 0.5%, Ti: 0.1 to 0.5%, Mg: 0.0002 to 0.01%, Ca: 0.0002 to 0.01%, N: ?0.02%, O: 0.0001 to 0.01%, freely contained components of Co: 0.05 to 2% and Cu: 0.01 to 0.5%, Fe as a remainder, and inevitable impurities, wherein MgO, MgO.Al2O3 spinel type, and CaO—Al2O3—MgO type are contained as oxide type non-metallic inclusions, ratio of number of MgO.Al2O3 spinel type to all oxide type non-metallic inclusions is ?50%, and CaO—Al2O3—MgO type contains CaO: 30 to 70%, Al2O3: 5 to 60%, MgO: 1 to 30%, SiO2: ?8%, and TiO2: ?10%.
    Type: Grant
    Filed: August 24, 2016
    Date of Patent: September 3, 2019
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Hidekazu Todoroki, Fumiaki Kirihara
  • Publication number: 20190078178
    Abstract: The Ni-based alloy exhibits superior grain boundary corrosion resistance including C: 0.005 to 0.03 mass %, Si: 0.02 to 1 mass %, Mn: 0.02 to 1 mass %, P: not more than 0.03 mass %, S: not more than 0.005 mass %, Cr: 18 to 24 mass %, Mo: 8 to 10 mass %, Nb: 2.5 to 5.0 mass %, Al: 0.05 to 0.4 mass %, Ti: not more than 1 mass %, Fe: not more than 5 mass %, N: not more than 0.02 mass %, and Ni as a remainder and inevitable impurities. The C concentration range, the ratio of (Nb, Ti) C carbides to all carbides is not less than 90%, and the number of (Nb, Ti) C carbides satisfies the following formula: ?30×T+37220=<number of (Nb, Ti) C carbides (number/mm2)=<?7.7×T2+15700×T?7866000 under a condition of 2000×% C+890=<T(temperature ° C.)=<1150.
    Type: Application
    Filed: August 28, 2018
    Publication date: March 14, 2019
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Takafumi KIKUTAKE, Fugao WEI
  • Patent number: 9777356
    Abstract: An austenitic Fe—Ni—Cr alloy comprises C: 0.005˜0.03 mass %, Si: 0.17˜1.0 mass %, Mn: not more than 2.0 mass %, P: not more than 0.030 mass %, S: not more than 0.0015 mass %, Cr: 18˜28 mass %, Ni: 21.5˜32 mass %, Mo: 0.10˜2.8 mass %, Co: 0.05˜2.0 mass %, Cu: less than 0.25 mass %, N: not more than 0.018 mass %, Al: 0.10˜1.0 mass %, Ti: 0.10˜1.0 mass %, Zr: 0.01˜0.5 mass %, and the balance being Fe and inevitable impurities; wherein Cr, Mo, N and Cu satisfy PRE=Cr+3.3×Mo+16×N?20.0 and PREH=411-13.2×Cr-5.8×Mo+0.1×Mo2+1.2×Cu?145.0 and wherein Al, Ti, and Zr satisfy 0.5?Al+Ti+1.5×Zr?1.5, and has an excellent corrosion resistance in air or under a wet environment even at a surface state having an oxide film formed by an intermediate heat treatment.
    Type: Grant
    Filed: September 10, 2015
    Date of Patent: October 3, 2017
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Kazuhiro Yamakawa, Shigeru Hirata, Kun Wang
  • Publication number: 20170058384
    Abstract: Fe—Cr—Ni—Mo alloy having superior surface properties and a method for producing the same using a commonly used apparatus at low cost. The Fe—Cr—Ni—Mo alloy has (% indicates mass %): C: ?0.03%, Si: 0.15 to 0.5%, Mn: 0.1 to 1%, P: ?0.03%, S: ?0.002%, Ni: 20 to 32%, Cr: 20 to 26%, Mo: 0.5 to 2.5%, Al: 0.1 to 0.5%, Ti: 0.1 to 0.5%, Mg: 0.0002 to 0.01%, Ca: 0.0002 to 0.01%, N: ?0.02%, O: 0.0001 to 0.01%, freely contained components of Co: 0.05 to 2% and Cu: 0.01 to 0.5%, Fe as a remainder, and inevitable impurities, wherein MgO, MgO.Al2O3 spinel type, and CaO—Al2O3—MgO type are contained as oxide type non-metallic inclusions, ratio of number of MgO.Al2O3 spinel type to all oxide type non-metallic inclusions is ?50%, and CaO—Al2O3—MgO type contains CaO: 30 to 70%, Al2O3: 5 to 60%, MgO: 1 to 30%, SiO2: ?8%, and TiO2: ?10%.
    Type: Application
    Filed: August 24, 2016
    Publication date: March 2, 2017
    Applicant: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Hidekazu TODOROKI, Fumiaki KIRIHARA
  • Patent number: 9528173
    Abstract: High-Mn austenitic stainless steels having a chemical composition comprising C: 0.02-0.12 mass %, Si: 0.05-1.5 mass %, Mn: 10.0-22.0 mass %, S: not more than 0.0028 mass %, Ni: 4.0-12.0 mass %, Cr: 14.0-25.0 mass % and N: 0.07-0.17 mass % with the balance being Fe and inevitable impurities, provided that these components are contained so that ? cal represented by the following equation is not more than 5.5%: ? cal (mass %)=(Cr+0.48Si)?(Ni+0.11Mn?0.0101Mn2+26.4C+20.1N)?4.7, wherein each element symbol in the equation is a content of the respective element (mass %), and having a magnetic permeability of not more than 1.003 under a magnetic field of 200 kA/m.
    Type: Grant
    Filed: February 21, 2014
    Date of Patent: December 27, 2016
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Shigeru Hirata, Yuji Ikegami, Kazuhiro Yamakawa
  • Patent number: 9303301
    Abstract: A boron-containing stainless steel having excellent hot workability and weldability and a good surface quality is proposed and is a boron-containing stainless steel comprising C: 0.001-0.15 mass %, Si: 0.1-2 mass %, Mn: 0.1-2 mass %, Ni: 5-25 mass %, Cr: 11-27 mass %, B: 0.05-2.5 mass %, Al: 0.005-0.2 mass %, O: 0.0001-0.01 mass %, N: 0.001-0.1 mass %, S: not more than 0.005 mass %, one or both of Mg: 0.0001-0.005 mass % and Ca: 0.0001-0.005 mass % and the remainder being Fe and inevitable impurities provided that a part of Si, Al, Mg, Ca and S is included as a non-metallic inclusion made of sulfide and/or oxysulfide.
    Type: Grant
    Filed: August 22, 2011
    Date of Patent: April 5, 2016
    Assignee: NIPPON YAKIN KOGYO CO., LTD.
    Inventor: Hidekazu Todoroki
  • Publication number: 20150376752
    Abstract: An austenitic Fe—Ni—Cr alloy comprises C: 0.005˜0.03 mass %, Si: 0.17˜4.0 mass %, Mn: not more than 2.0 mass %, P: not more than 0.030 mass %, S: not more than 0.0015 mass %, Cr: 18˜28 mass %, Ni: 21.5˜32 mass %, Mo: 0.10˜2.8 mass %, Co: 0.05˜2.0 mass %, Cu: less than 0.25 mass %, N: not more than 0.018 mass %, Al: 0.10˜4.0 mass %, Ti: 0.10˜1.0 mass %, Zr: 0.01˜0.5 mass %, and the balance being Fe and inevitable impurities; wherein Cr, Mo, N and Cu satisfy PRE=Cr+3.3×Mo+16×N?20.0 and PREH=411-13.2×Cr-5.8×Mo+0.1×Mo2+1.2×Cu?145.0 and wherein Al, Ti, and Zr satisfy 0.5?Al+Ti+1.5×Zr?1.5, and has an excellent corrosion resistance in air or under a wet environment even at a surface state having an oxide film formed by an intermediate heat treatment.
    Type: Application
    Filed: September 10, 2015
    Publication date: December 31, 2015
    Applicant: NIPPON YAKIN KOGYO CO., LTD.
    Inventors: Kazuhiro YAMAKAWA, Shigeru HIRATA, Kun WANG