Abstract: The present invention is directed to an addition polymer comprising an addition polymer backbone; at least one moiety comprising a phosphorous acid group, the moiety being covalently bonded to the addition polymer backbone by a carbon-carbon bond; and at least one carbamate functional group. The present invention is also directed towards methods of making the addition polymer, aqueous resinous dispersions and electrodepositable coating compositions comprising the addition polymer, methods of coating a substrate and coated substrates.

Abstract: The present invention is directed to compositions comprising a first component, a second component, and elastomeric particles. The first component comprises an epoxy-containing compound. The second component comprises a diamine comprising a cyclic ring and/or a polyamine comprising a cyclic ring. The diamine may chemically react with the epoxy-containing compound. Optionally, the cyclic ring of the diamine and/or the polyamine has at least one carbon positioned between the amino functional groups and the cyclic ring structure. Optionally, at least 50% by weight of the elastomeric particles comprise a styrene butadiene core based on total weight of the elastomeric particles. The present invention is also directed to methods of making the compositions, methods of coating a substrate, and coated substrates.

Abstract: Polythioether prepolymers that have a low nucleation temperature. The symmetry of the polythioether prepolymers is modified by including pendent groups extending from the backbone of the polythioether prepolymer chain and/or the symmetry is modified by including segments having a different number of —C(R)2— groups between heteroatoms. The polythioether prepolymers are stable at low temperature storage conditions for an extended period of time. Compositions prepared using the low nucleation temperature polythioether prepolymers are useful as sealants.

Abstract: A composition for application to a substrate comprising a carrier, a permanganate ion source, and a corrosion inhibitor comprising a rare earth ion, an alkali metal ion, an alkaline earth metal ion, and/or a transition metal ion is disclosed. A substrate or article including the composition for application to a substrate, and a method of treating a substrate comprising applying the composition to a substrate to form a permanganate treated surface of the substrate, and applying a lithium containing composition on the permanganate treated surface are also disclosed.

Abstract: The present invention is directed to a curable film-forming composition comprising: (a) a curing agent comprising reactive isocyanate functional groups; (b) a film-forming compound comprising functional groups reactive with the reactive isocyanate functional groups in (a); (c) a photo-latent catalyst; (d) a beta-diketone having a flash point higher than 60 C (140 F); and (e) a beta-diketone having a flash point lower than or equal to 60 C (140 F). The invention is further directed to methods of controlling the rate of cure and increasing the wet-edge time of a curable film-forming composition comprising an isocyanate functional curing agent, by adding to the curable film-forming composition a catalyst component comprising: (i) a photo-latent catalyst; (ii) a beta-diketone having a flash point higher than 60 C (140 F); and (iii) a beta-diketone having a flash point lower than or equal to 60 C (140 F).

Abstract: Sealant cartridge press fixtures are disclosed. The fixtures include a bracket comprising first and second side arms that receive a sealant cartridge therebetween. A transverse support bar connected to the first and second side arm is attached to a sealant filling nozzle. An air pressure cylinder mounted on the bracket includes a reciprocating piston rod that contacts and deforms a sidewall of the sealant cartridge at the beginning of a filling operation to allow trapped air to escape from the cartridge. An empty sealant cartridge having a slidable plunger therein is mounted at its front end on the sealant filling nozzle. The sealant is initially dispensed into the cartridge in the space between the front end of the cartridge and the plunger. While pressing and deforming the sidewall, it temporarily creates a gap between an interior surface of the sidewall and a plunger. The gap allows unwanted trapped air to escape from the sealant cartridge.

Abstract: The present invention is directed to an addition polymer comprising an addition polymer backbone; at least one moiety comprising a sulfonic acid group; and at least one carbamate functional group. The present invention is also directed towards methods of making the addition polymer, aqueous resinous dispersions comprising the addition polymer, methods of coating a substrate and coated substrates.

Abstract: The present invention is directed to a compound of formula I, wherein R1 comprises hydrogen, an alkyl group, or an aryl group; R2 comprises hydrogen or a methyl group; R3 comprises a divalent organic group; R4 comprises a divalent organic group; and X comprises oxygen, NH, or N(R5), wherein R5 comprises a monovalent organic group. The present invention is also directed towards polymers comprising a pendant carbamate-functional moiety comprising the structure: wherein R1 comprises hydrogen, an alkyl group, or an aryl group; R2 comprises hydrogen or a methyl group; R3 comprises a divalent organic group; R4 comprises a divalent organic group; and X comprises oxygen, NH, or N(R5) wherein R5 comprises a monovalent organic group. The present invention is also directed to methods of preparing such compounds and polymers, compositions comprising such polymers, and coatings produced from such compositions.

Abstract: Sulfur-containing poly(alkenyl) ethers can be incorporated into the backbone of polythioether prepolymers and can be used as curing agents in thiol-terminated polythioether prepolymer compositions. Cured sealants prepared using compositions containing sulfur-containing poly(alkenyl) ether-containing polythioether prepolymers and/or sulfur-containing poly(alkenyl) ether curing agents exhibit improved physical properties suitable for use in aerospace sealant applications.

Abstract: Methods and compositions for treating a substrate are provided. The composition contains a corrosion-inhibiting metal cation and a conjugated compound.

Abstract: Compositions include a polythiol and a wetted filler. The composition comprises from 0.1 wt % to 10 wt % water based on the total weight of the composition. The compositions exhibit an extended working time and a rapid onset of cure. The compositions can be used as sealants.

Abstract: Polyurethane prepolymers having non-linear short chain diols and/or soft diisocyanates incorporated into the backbone are used to provide cured polyurethane coatings having a high hard segment content and low haze. The polyurethane prepolymers can also be used to improve the dispersion of filler in cured polyurethane compositions having a high filler loading. Cured coatings prepared from the two-part polyurethane systems meet the requirements for aerospace applications.

Abstract: Adhesion-promoting compositions and the use of the adhesion-promoting compositions to provide adhesion-promoting interlayers to enhance adhesion between adjoining layers of sulfur-containing sealants are disclosed. In repair applications, the adhesion-promoting compositions can enhance the adhesion of an overlying radiation-curable sulfur-containing sealant to a damaged or aged sulfur-containing sealant.

Abstract: Sealant dispensing cartridge assemblies including radially expandable collets are disclosed. A plunger head assembly includes a ram head attached to a plunger rod. As the plunger rod is advanced into the sealant cartridge, the ram head presses against a rear side of a movable plunger against an opposing force created by a sealant contained in the cartridge on a front side of the plunger. As the plunger rod is further advanced, the collet contacts the ram head and radially expands against the inner sidewall of the plunger. The resulting radial force presses the sidewall of the plunger against the inner surface of the cartridge to thereby reduce or prevent unwanted leakage of the sealant around the plunger.

Abstract: The present invention is directed to a curable film-forming composition comprising: (a) a curing agent comprising reactive isocyanate functional groups; (b) a film-forming compound comprising functional groups reactive with the reactive isocyanate functional groups in (a); (c) a photo-latent catalyst; (d) a beta-diketone having a flash point higher than 60 C (140 F); and (e) a beta-diketone having a flash point lower than or equal to 60 C (140 F). The invention is further directed to methods of controlling the rate of cure and increasing the wet-edge time of a curable film-forming composition comprising an isocyanate functional curing agent, by adding to the curable film-forming composition a catalyst component comprising: (i) a photo-latent catalyst; (ii) a beta-diketone having a flash point higher than 60 C (140 F); and (iii) a beta-diketone having a flash point lower than or equal to 60 C (140 F).

Abstract: Disclosed is a method for treating an anodized metal substrate, including contacting at least a portion of the substrate surface with a sealing composition having a pH of 9.5 to 12.5 and comprising a lithium metal cation. Also disclosed is a system that includes a sealing composition having a pH of 9.5 to 12.5 and comprising a lithium metal cation and an aqueous composition for contacting a surface of the metal substrate following contacting with the sealing composition. Also disclosed are substrates treated with the system and method.

Abstract: The present invention is directed to a phosphated epoxy resin comprising at least one terminal group comprising a phosphorous atom covalently bonded to the re sin by a carbon-phosphorous bond or by a phosphoester linkage; and at least one carbamate functional group. The present invention is also directed towards aqueous resinous dispersions comprising the phosphated epoxy resin, methods of coating a substrate, coated substrates, and methods of making a phosphated epoxy resin.

Abstract: Compositions that are resistant to hydraulic fluid and aviation fuel contain sulfur-containing prepolymers and solvent-resistant organic fillers. The compositions are useful in aerospace sealant applications.

Abstract: Isocyanate-terminated chain-extended polythioether prepolymers, compositions thereof, and methods of use thereof are disclosed. The isocyanate-terminated chain-extended polythioether prepolymers are useful in sprayable coatings and sealants and especially sprayable coatings and sealants having a high filler content.