Abstract: Adducts and prepolymers comprising pendent alkyl groups are disclosed. Polythiol adducts prepared by reacting a polythiol with a ketone and urethane-extended polythiol adducts. The polythiol adducts can be terminated with isocyanate groups. Compositions comprising the isocyanate-terminated polythiol adducts, isocyanate-terminated sulfur-containing prepolymers, and diisocyanates can be combined with polyamine or polyepoxide curing agents to provide curable compositions. Cured compositions are suitable for aerospace coating and sealant applications. The compositions can also include a low specific gravity filler and, when cured, meet the requirements of aerospace sealant applications.

Abstract: Photocurable adhesion-promoting compositions containing organic titanates and/or organic zirconates and partially reacted alkoxysilanes and the use of the photocurable adhesion-promoting compositions to provide adhesion between metal substrates and an overlying radiation-cured sealant are disclosed.

Abstract: Low density aerospace compositions and sealants are disclosed. The low density compositions and sealants are characterized by a high volume percent loading of low density microcapsules.

Abstract: Adhesion-promoting compositions and the use of the adhesion-promoting compositions to provide adhesion-promoting interlayers to enhance adhesion between adjoining layers of sulfur-containing sealants are disclosed. In repair applications, the adhesion-promoting compositions can enhance the adhesion of an overlying radiation-curable sulfur-containing sealant to a damaged or aged sulfur-containing sealant.

Abstract: Dual cure compositions include a combination of an organoborane complex and a radical oxidizing agent as co-catalysts. The compositions are curable under dark conditions and can be used to catalyze thiol-ene reactions. The compositions are useful as sealants.

Abstract: Chemically resistant sealant compositions include high equivalent weight sulfur-containing prepolymers. Upon exposure to chemicals the properties of sealants prepared using the prepolymers exhibit excellent fuel and phosphate ester resistance.

Abstract: Coating systems are used to visually hide low-profile surface features and to establish the optical properties of high profile surface features. The coating systems are useful in hiding build lines on the surface of articles fabricated using three-dimensional printing. Using the coating systems, the optical properties of intentional surface features such as patterns and textures can be modified to achieve a desired optical effect.

Abstract: The present invention is directed to a phosphated epoxy resin comprising at least one terminal group comprising a phosphorous atom covalently bonded to the resin by a carbon-phosphorous bond or by a phosphoester linkage; and at least one carbamate functional group. The present invention is also directed towards aqueous resinous dispersions comprising the phosphated epoxy resin, methods of coating a substrate, coated substrates, and methods of making a phosphated epoxy resin.

Abstract: Disclosed herein is a first composition comprising a trivalent chromium cation and an aqueous carrier. Also disclosed herein is a second composition comprising a permanganate anion and an aqueous carrier. Also disclosed herein is a system for treating a metal substrate comprising a first composition comprising a trivalent chromium cation and an aqueous carrier and optionally a second composition comprising a permanganate anion and an aqueous carrier. Also disclosed herein is a method of treating a metal substrate comprising contacting at least a portion of the substrate surface with a first composition comprising a trivalent chromium cation and an aqueous carrier and optionally contacting at least a portion of the substrate surface with a second composition comprising a permanganate anion and an aqueous carrier.

Abstract: Mixers for adhesives and sealants that include automatic stroke length adjustment for different sizes and configurations of adhesive and sealant cartridges are disclosed. The mixers include a sensor for detecting when a mixing impeller reaches the top of a cartridge and the bottom of a cartridge, which sends a signal to a main pressure cylinder to reverse direction. The stroke length of the mixer is automatically adjusted without the necessity of manual selection based upon a particular cartridge size.

Abstract: Actinic radiation-curable compositions containing polythiols and urethane/urea-containing polyalkenyl prepolymers that can be used for aerospace coatings and sealants. The coatings can be applied to surfaces and rapidly cured.

Abstract: The present invention is directed to an addition polymer comprising an addition polymer backbone; at least one moiety comprising a phosphorous acid group, the moiety being covalently bonded to the addition polymer backbone by a carbon-carbon bond; and at least one carbamate functional group. The present invention is also directed towards methods of making the addition polymer, aqueous resinous dispersions and electrodepositable coating compositions comprising the addition polymer, methods of coating a substrate and coated substrates.

Abstract: The present invention is directed to a compound of formula I, wherein R1 comprises hydrogen, an alkyl group, or an aryl group; R2 comprises hydrogen or a methyl group; R3 comprises a divalent organic group; R4 comprises a divalent organic group; and X comprises oxygen, NH, or N(R5), wherein R5 comprises a monovalent organic group. The present invention is also directed towards polymers comprising a pendant carbamate-functional moiety comprising the structure: wherein R1 comprises hydrogen, an alkyl group, or an aryl group; R2 comprises hydrogen or a methyl group; R3 comprises a divalent organic group; R4 comprises a divalent organic group; and X comprises oxygen, NH, or N(R5) wherein R5 comprises a monovalent organic group. The present invention is also directed to methods of preparing such compounds and polymers, compositions comprising such polymers, and coatings produced from such compositions.

Abstract: The present invention is directed to an addition polymer comprising an addition polymer backbone; at least one moiety comprising a sulfonic acid group; and at least one carbamate functional group. The present invention is also directed towards methods of making the addition polymer, aqueous resinous dispersions comprising the addition polymer, methods of coating a substrate and coated substrates.

Abstract: A corrosion resistant pretreatment composition for coating a metal substrate is provided. The composition comprises an aqueous carrier, one or more Group IA metal ions, wherein at least one of the Group 1A metal ions comprises a lithium compound, a hydroxide; and a phosphate or a halide. A process for treating a metal substrate with a lithium based coating is also provided, as well as a process for treating a metal substrate with a non-chrome conversion coating process.

Abstract: Controlled release polyurea microcapsules can be prepared from a combination of polyisocyanates using emulsion polymerization. Encapsulated catalysts prepared using the polyurea microcapsules can be used to control the cure rate of coatings and sealants.

Abstract: Sulfur-containing polymeric particles having a high sulfur content can be prepared using emulsion polymerization. The sulfur-containing polymeric particles are useful in aerospace coatings and sealants.

Abstract: A composition for application to a substrate comprising a carrier, a permanganate ion source, and a corrosion inhibitor comprising a rare earth ion, an alkali metal ion, an alkaline earth metal ion, and/or a transition metal ion is disclosed. A substrate or article including the composition for application to a substrate, and a method of treating a substrate comprising applying the composition to a substrate to form a permanganate treated surface of the substrate, and applying a lithium containing composition on the permanganate treated surface are also disclosed.

Abstract: A coating comprising epoxy functional resin, corrosion resistant particles, and a multi-functional crosslinker are disclosed as are methods of using such a coating to coat at least a portion of a substrate and a substrate coated thereby.