Abstract: A rechargeable electrochemical cell is provided having a pressure-responsive apparatus for determining a charge termination point. In particular, a reversible pressure-responsive switch may be disposed in a cap at the open end of a rechargeable metal hydride cell. The reversible pressure-responsive switch may also contain a vent system for releasing the cell internal pressure. Alternatively, a rechargeable cell may include a strain gauge disposed in its outer surface whose resistance changes as the outer surface of the battery expands due to internal pressure accumulation during charging. Additionally, a rechargeable cell is used combination with a charging source that can supply constant voltage, constant current, alternating current, or voltage that varies between a minimum threshold and a maximum threshold.

Abstract: Alkaline electrochemical cells having extended service life and acceptable gassing and corrosion properties are disclosed. An amphoteric surfactant can be incorporated into the gelled anode mixture of an alkaline electrochemical cell, optionally with an organic phosphate ester surfactant or a sulfonic acid type organic surfactant or both. Zinc particles having a defined distribution of particle sizes can also be incorporated into a zinc anode. The electrolyte included in the anode mixture can have a reduced hydroxide concentration.

Abstract: An electrochemical cell such as an alkaline battery has improved shelf-life and manufacturability. The cell has a gasket for sealing an open end of a metal container of the battery that forms a seal with a current collector shank of the battery without introducing cracks or other defects in the gasket that can lead to failure of the seal over time. Moreover, the gasket is configured to fix the current collector relative to the gasket upon assembly with the gasket so that the components of the subassembly remain fixed in position relative to each other during manufacture. A method of assembling an electrochemical cell is also disclosed.

Abstract: An anode is provided for an electrochemical cell having an ionically conductive additive, such as Laponite® or any alternative clay suitable to improve the transport of hydroxyl ions into anode during discharge.

Abstract: According to the present invention an alkaline electrochemical cell can contain an anode having an anode active material, an alkaline electrolyte, a gelling agent and an oxazoline surfactant additive. The invention relates to an anode mix, to an anode containing the mix, and to an electrochemical cell containing the anode and to methods for making the anode mix, the anode and the cell. Performance improvements can be realized when the oxazoline surfactant is provided in the anode, which can include increased operating voltage, good high rate pulse capability, elimination of initial potential dip, good shelf life and reduced sensitivity to open circuit rest.

Abstract: A rechargeable electrochemical cell is provided having a pressure-responsive apparatus for determining a charge termination point. In particular, a reversible pressure-responsive switch may be disposed in a cap at the open end of a rechargeable metal hydride cell. The reversible pressure-responsive switch may also contain a vent system for releasing the cell internal pressure. Alternatively, a rechargeable cell may include a strain gauge disposed in its outer surface whose resistance changes as the outer surface of the battery expands due to internal pressure accumulation during charging. Additionally, a rechargeable cell is used combination with a charging source that can supply constant voltage, constant current, alternating current, or voltage that varies between a minimum threshold and a maximum threshold.

Abstract: An air manager is provided for supplying air to a battery that may be disposed in a battery compartment of an electrical device. The battery includes at least one air-depolarized cell to supply power to the device. The air manager achieves a dual function of stimulating flow within the battery compartment as well as delivering air over the at least one cell. In particular, the air entering the air manager is split into two streams, the first stream delivering air to the cell, and the second stream stimulating flow within the battery compartment. The air manager may use a fan, peristaltic air pump, or any alternative air mover. The battery may have a “Figure-8” design to provide adjacent cell compartments that are received in a battery compartment configured to receive standard size alkaline cells.

Abstract: A method is disclosed for preparing cathodes loaded with manganese oxide that are suitable for use in metal-air cells. The manganese oxide is prepared from the reduction of potassium permanganate by sodium formate at a substantially neutral pH level to produce manganese oxide sols. The sols are then mixed with a carbon slurry to produce a colloidal suspension. The suspension is subsequently waterproofed before being filtered, washed, dried, and rolled to produce the active catalyst layer for the cathode during discharge of the cell. The catalyst layer is then laminated with a current collector and air diffusion layer. A separator is then added to provide a carbon-based air cathode loaded with manganese oxide.

Abstract: A battery pack suitable for use with button cell batteries. The battery pack includes a flexible card and a cover rotatably fixed relative to said flexible card. A backing is interposed between the card and said cover, and fixed relative to said card. The backing and cover define an enclosed space interposed between the cover and the backing for receiving batteries. Batteries disposed in the space are enclosed by the cover and backing to inhibit pilfering by bending the card.

Abstract: An electrochemical cell having a cell can that includes an interior surface, a current collector, a solid cathode contained in the can and in conductive contact therewith, an organic or solid polymer electrolyte comprising lithium salt solutes and aprotic organic solvents has improved storage properties when a coating comprising carbon powder is diposed on the current collector surface and on the adjacent interior surface of the cell can. Further, the cell has advantageous enhanced discharge properties over an expanded temperature range when the cathode additionally comprises a fluoropolymer resin binder.

Abstract: Cathode cans for use in air depolarized cells, and cells made with such cans. The side wall is stronger than the bottom wall, and has a smoother outwardly-disposed surface than the respective bottom wall surface. Strength, and thus hardness, of the side wall relates to strength, and thus hardness, of the bottom wall, as hardness of 130-185 relates, to hardness of 93-117, on the Vickers scale. Preferred hardness of the side wall is about 130 to 185; and of the bottom wall is about 93 to 117. The side wall is drawn, and an outwardly-disposed surface of the side wall is ironed. As ironed, the surface finish is related to surface finish of the bottom wall, at the same stage, as surface finish RA of less than 2, preferably about 0.5 to about 1.5, microinches, is related to surface finish RA of about 2 to about 5, preferably about 2.5 to about 4.5, microinches. Thickness of the side wall is generally up to about 85 percent as great as thickness of the bottom wall.

Abstract: A retail package for round cell batteries is a transparent single sheet thermoformed clamshell having a cover connected along a hinge to a base which receives an array of upwardly extending batteries. The base has a side wall which extends upwardly from a flat bottom wall. The side wall has a lower section which is substantially perpendicular to the bottom wall and has a zero degree draft angle. Semicylindrical pockets are defined by the base wall lower portion and batteries are positioned in the pockets two abreast. Thus, each battery is engaged by a portion of the side wall and another battery. Hence, a partially emptied container will still retain most of the batteries upright. The cover has a downwardly extending skirt with an inwardly extending semicircular closure tab which engages beneath a lip formed on the base side wall. The lid closure may be released by pressing the base side wall.

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12), a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) walls of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: An elongate, generally tubular, air depolarized electrochemical cell (10) comprising a cathode (14), including an air cathode assembly (26), extending about the tubular circumference, and along the tubular length, of the cell (10), an anode (12), a separator (16) between the anode (12) and the cathode (14), electrolyte, a top closure member (177, 200), and a bottom closure member (114, 202). The cathode assembly (26) is fixedly held, by a friction fit, in a slot (116) at the bottom of the cell. The slot can be developed, for example, by inner (110) and outer (114) wars of a cathode can (28), by inner (226) and outer (224) walls of a bottom closure member (202), or by an outer wall (114) of a cathode can (28) and an opposing outer wall of a plug (128) on the interior of the cell.

Abstract: A retail package for round cell batteries is a transparent single sheet thermoformed clamshell having a cover connected along a hinge to a base which receives an array of upwardly extending batteries. The base has a side wall which extends upwardly from a flat bottom wall. The side wall has a lower section which is substantially perpendicular to the bottom wall and has a zero degree draft angle. Semicylindrical pockets are defined by the base wall lower portion and batteries are positioned in the pockets two abreast. Thus, each battery is engaged by a portion of the side wall and another battery. Hence, a partially emptied container will still retain most of the batteries upright. The cover has a downwardly extending skirt with an inwardly extending semicircular closure tab which engages beneath a lip formed on the base side wall. The lid closure may be released by pressing the base side wall.

Abstract: Improved cathode cans, for use in electrochemical cells. Broadly, the cans comprise corrosion-susceptible core layers, and protective metal layers such as nickel overlying the core layer and disposed between the core layer and a, preferably electroless plated, duplex coating layer such as nickel, which overlies severed edges of the core layer, and also typically overlies the protective metal layers. Thickness of the duplex coating layer is less, preferably no more than 75%, of the thickness of the protective metal layer. Combined thickness of the protective metal layer and duplex coating layer is preferably about 75 microinches (0.002 mm) to 200 microinches (0.005 mm). Thickness of the duplex coating layer alone is preferably about 25 microinches (0.0006 mm) to 100 microinches (0.0025 mm). Combined thickness of the protective metal layer and the duplex coating layer is preferably at least 1.25 times, up to no more than 2 times, thickness of the protective metal layer.

Abstract: An air depolarized cell comprises an anode, a cathode, including an air cathode assembly openly exposed to the ambient environment and/or defining at least a portion of the outer surface of the cell. The cell can comprise a bottom member defining a bottom of the cell, and a top member defining a top of the cell, the air cathode assembly extending between the bottom member and the top member as the exposed or outer portion of the cell. An anode cavity can be disposed inwardly of the separator and upwardly of the bottom member, and contain a mass of electroactive anode material. An elongate anode current collector preferably extends into the anode material. The top member can comprise a top contour washer having inner and outer downwardly depending legs receiving an upper edge portion of the cathode assembly in a slot therebetween, and an insulating grommet in the slot, electrically insulating the cathode assembly from the top contour washer and sealing against liquid leakage out of the cell through the slot.