Patents Assigned to Senju Metal Industry Co., Ltd.
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Patent number: 11945055Abstract: A flux containing 1 to 10 wt % of an organic sulfonic acid activator, 10 to 40 wt % of a high-molecular-weight nonionic surfactant that is a nonionic surfactant having a mass-average molecular weight Mw of more than 1200 and 5 to 75 wt % of a low-molecular-weight nonionic surfactant that is a nonionic surfactant having a mass-average molecular weight Mw of 1200 or less, in which the content of the low-molecular-weight nonionic surfactant is equal to or larger than the content of the organic sulfonic acid activator. This flux contains no cationic surfactant or contains more than 0 wt % and 5 wt % or less of the cationic surfactant. A solder paste containing this flux and a Sn-based solder metal.Type: GrantFiled: October 14, 2021Date of Patent: April 2, 2024Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Hiroshi Sugii, Yasuhiro Kajikawa, Yo Yamada
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Publication number: 20240100635Abstract: A core material has a core 12; a solder layer 16 made of a (Sn—Bi)-based solder alloy provided on an outer side of the core 12; and a Sn layer 20 provided on an outer side of the solder layer 16. The core contains metal or a resin. When a concentration ratio of Bi contained in the solder layer 16 is a concentration ratio (%)=a measured value of Bi (% by mass)/a target Bi content (% by mass), or a concentration ratio (%)=an average value of measured values of Bi (% by mass)/a target Bi content (% by mass), the concentration ratio is 91.4% to 106.7%. The thickness of the Sn layer 20 is 0.215% or more and 36% or less of the thickness of the solder layer 16.Type: ApplicationFiled: November 29, 2023Publication date: March 28, 2024Applicant: SENJU METAL INDUSTRY CO., LTD.Inventors: Shigeki Kondoh, Masato Tsuchiya, Hiroki Sudo, Hiroshi Okada, Daisuke Souma
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Patent number: 11931829Abstract: A flux containing 0.1 to 20 wt % of 2-hydroxyisobutyric acid as an activator, 10 to 60 wt % of a cationic surfactant and 5 to 60 wt % of a nonionic surfactant. A solder paste contains a flux containing 0.1 to 20 wt % of 2-hydroxyisobutyric acid as an activator, 10 to 60 wt % of a cationic surfactant, and 5 to 60 wt % of a nonionic surfactant and a metal powder.Type: GrantFiled: August 20, 2021Date of Patent: March 19, 2024Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Tomohiro Yamagame, Yo Yamada
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Patent number: 11911854Abstract: Provided is a solder alloy, a solder paste, a solder preform, and a solder joint which suppress chip cracking during cooling, improve the heat dissipation characteristics of the solder joint, and exhibit high joint strength at high temperatures. The solder alloy has an alloy composition of, by mass: Sb: 9.0 to 33.0%; Ag: more than 4.0% and less than 11.0%; and Cu: more than 2.0% and less than 6.0%, with the balance of Sn. Moreover, the solder paste, the solder preform, and the solder joint all contain said solder alloy.Type: GrantFiled: December 14, 2019Date of Patent: February 27, 2024Assignee: Senju Metal Industry Co., Ltd.Inventors: Yoshie Tachibana, Takeshi Sakamoto
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Patent number: 11904416Abstract: Provided are a solder alloy, a solder powder, a solder paste, and a solder joint having a low liquidus temperature and not too low solidus temperature. The solder alloy has an alloy composition of, by mass: Ag: 2.0 to 4.0%; Cu: 0.51 to 0.79%; and Bi: more than 4.0% and 8.0% or less, with the balance being Sn. The solder alloy has a liquidus temperature of less than 217° C.Type: GrantFiled: March 9, 2022Date of Patent: February 20, 2024Assignee: Senju Metal Industry Co., Ltd.Inventors: Yoshie Tachibana, Tomoki Sasaki, Norikazu Sakai, Yoshihiro Yamaguchi
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Publication number: 20240042539Abstract: Provided is a soldering apparatus including: a furnace body including a processing chamber in which boards are processed; a gasket provided at least to a part of the furnace body, and configured to seal the furnace body; a sealed space isolated from the processing chamber, and defined by the furnace body and the gasket; a gas supply apparatus configured to supply a first gas into the sealed space; and a measuring apparatus configured to measure one of pressure in the sealed space and concentration of a second gas in the sealed space.Type: ApplicationFiled: October 17, 2023Publication date: February 8, 2024Applicant: SENJU METAL INDUSTRY CO., LTD.Inventors: Tsutomu HIYAMA, Nobuhiro KOJIMA
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Publication number: 20240033863Abstract: Provided is a flux for resin-cored solder that is used in resin-cored solder that is supplied into a through hole formed along a central axis of a soldering iron. The flux includes 60% by mass to 99.9% by mass of a rosin ester to a total mass of the flux, 0.1% by mass to 15% by mass of a covalent halogen compound to the total mass of the flux, and more than 0% by mass to 10% by mass of rosin amine, N,N-diethyloctylamine, or rosin amine and N,N-diethyloctylamine to the total mass of the flux.Type: ApplicationFiled: November 10, 2021Publication date: February 1, 2024Applicants: Senju Metal Industry Co., Ltd., DENSO CORPORATIONInventors: Yoko Kurasawa, Motohiro Onitsuka, Hisashi Tokutomi, Kei Endo, Kazuyuki Hamamoto
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Patent number: 11872656Abstract: A core material has a core 12; a solder layer 16 made of a (Sn—Bi)-based solder alloy provided on an outer side of the core 12; and a Sn layer 20 provided on an outer side of the solder layer 16. The core contains metal or a resin. When a concentration ratio of Bi contained in the solder layer 16 is a concentration ratio (%)=a measured value of Bi (% by mass)/a target Bi content (% by mass), or a concentration ratio (%)=an average value of measured values of Bi (% by mass)/a target Bi content (% by mass), the concentration ratio is 91.4% to 106.7%. The thickness of the Sn layer 20 is 0.215% or more and 36% or less of the thickness of the solder layer 16.Type: GrantFiled: September 30, 2020Date of Patent: January 16, 2024Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Shigeki Kondoh, Masato Tsuchiya, Hiroki Sudo, Hiroshi Okada, Daisuke Souma
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Patent number: 11865645Abstract: A soldering apparatus includes a cooling zone, upper and lower vent holes, an external channel, a blower unit, a heat exchanger, a pair of bypass channels, and a ventilation plate. The vent holes are provided, respectively, above and below a pair of rails configured to transport a board in the cooling zone. The external channel connects the vent holes with each other outside the cooling zone. The blower unit causes gas in the external channel to flow through the upper vent hole, the cooling zone, and the lower vent hole. The heat exchanger is provided in a lower opening linked to the lower vent hole in the cooling zone. The pair of bypass channels deliver gas above the pair of rails to the lower opening while bypassing locations of the pair of rails. The ventilation plate is provided in a space formed between the pair of bypass channels.Type: GrantFiled: June 14, 2021Date of Patent: January 9, 2024Assignee: SENJU METAL INDUSTRY CO., LTD.Inventor: Yuta Saito
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Patent number: 11858071Abstract: Provided are a solder alloy, a solder paste, a solder ball, a solder preform, and a solder joint, which have a melting temperature within a predetermined range, and high tensile strength and shear strength, suppress generation of voids, and have excellent mountability due to their thin oxide films. The solder alloy has an alloy composition consisting of, by mass %, Ag: 2.5 to 3.7%, Cu: 0.25 to 0.95%, Bi: 3.0 to 3.9%, and In: 0.5 to 2.3%, with the balance being Sn, and the alloy composition satisfies the following relations (1) and (2): 8.1?Ag+2Cu+Bi+In ?11.5 (1), and 1.00?(Bi+In)/Ag?1.66 (2). Ag, Cu, Bi and In in the relations (1) and (2) each represent the contents (mass %) in the alloy composition.Type: GrantFiled: October 21, 2022Date of Patent: January 2, 2024Assignee: Senju Metal Industry Co., Ltd.Inventors: Yoshie Tachibana, Ryuki Horie
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Patent number: 11858072Abstract: A flux according to the present invention contains a rosin methyl ester in which the flux is a solid or solid-like flux at 25° C., and is used for an inside of a flux-cored solder or an exterior of a flux-coated solder.Type: GrantFiled: February 1, 2021Date of Patent: January 2, 2024Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Yoko Kurasawa, Hiroaki Iseki, Kenta Nakajima
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Patent number: 11833620Abstract: Provided are flux in which solder wettability is improved, and a solder paste in which the flux is used. The flux contains 0.5-20.0 wt % of a (carboxyalkyl)isocyanurate adduct, and 5.0-45.0 wt % of a rosin, and furthermore contains a solvent. The (carboxyalkyl)isocyanurate adduct is a mono(carboxyalkyl)isocyanurate adduct, a bis(carboxyalkyl)isocyanurate adduct, a tris(carboxyalkyl)isocyanurate adduct, or a combination of two or more of these.Type: GrantFiled: January 16, 2019Date of Patent: December 5, 2023Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Yutaka Hashimoto, Kazuyori Takagi, Tomoko Nagai, Nanako Miyagi, Kazuya Kitazawa, Akiko Takaki, Kazuhiro Minegishi, Teppei Otsuki, Rina Horikoshi, Ryuichi Tsuda, Hiroyoshi Kawasaki, Masato Shiratori
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Patent number: 11826860Abstract: A flux containing an organic acid, a water-soluble base agent, and a solvent, but not containing water is adopted. In this flux, the organic acid includes 1,2,3-propanetricarboxylic acid. The water-soluble base agent is one or more selected from the group consisting of a nonionic surfactant and a weak cationic surfactant. The content of the 1,2,3-propanetricarboxylic acid is 1% by mass or more and 15% by mass or less with respect to the total amount of the entire flux, the total content of the water-soluble base agent is 30% by mass or more and 65% by mass or less with respect to the total amount of the entire flux, and the total content of the solvent is 30% by mass or more and 65% by mass or less with respect to the total amount of the entire flux. According to this flux, the wettability of solder can be enhanced and ball missing after reflow and flux residue washing is suppressed.Type: GrantFiled: February 17, 2021Date of Patent: November 28, 2023Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Hiroyoshi Kawasaki, Masato Shiratori, Kazuhiro Minegishi, Yuji Kawamata
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Patent number: 11819952Abstract: Provided is a soldering apparatus including: a furnace body including a processing chamber in which boards are processed; a gasket provided at least to a part of the furnace body, and configured to seal the furnace body; a sealed space isolated from the processing chamber, and defined by the furnace body and the gasket; a gas supply apparatus configured to supply a first gas into the sealed space; and a measuring apparatus configured to measure one of pressure in the sealed space and concentration of a second gas in the sealed space.Type: GrantFiled: May 24, 2021Date of Patent: November 21, 2023Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Tsutomu Hiyama, Nobuhiro Kojima
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Patent number: 11819955Abstract: A solder alloy is provided which can withstand the severe characteristics of a temperature cycle between a low temperature of ?40° C. and a high temperature of 125° C., withstand an external force applied due to, for example, riding on a curb or collision with a vehicle ahead for a long period of time, and can suppress change in viscosity of a solder paste over time. In addition, a solder paste, a solder ball, and a solder preform in which the solder alloy is used; a solder joint formed through the use thereof; and an on-board electronic circuit, an ECU electronic circuit, an on-board electronic circuit device, and an ECU electronic circuit device which include this solder joint are provided. The solder alloy contains, by mass %, 1% to 4% of Ag, 0.5% to 1.0% of Cu, 1.5% to 5.5% of Bi, 1.0% to 5.3% of Sb (or greater than 5.5% and less than or equal to 7.0% of Bi and 2.0% to 5.3% of Sb), 0.01% to 0.2% of Ni, 0.0040% to 0.0250% of As, and a balance of Sn.Type: GrantFiled: May 21, 2020Date of Patent: November 21, 2023Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Hiroyoshi Kawasaki, Masato Shiratori, Yuji Kawamata
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Publication number: 20230364720Abstract: A brazing paste contain 80% by mass or more and 95% by mass or less of a brazing material; and 5% by mass or more and 20% by mass or less of a binder. The binder contains a solid solvent containing two or more hydroxyl groups and having 5 to 7 carbon atoms, and a liquid solvent.Type: ApplicationFiled: May 3, 2023Publication date: November 16, 2023Applicants: SENJU METAL INDUSTRY CO., LTD., TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yoshie TACHIBANA, Hiroshi KAWANAGO, Takashi AKAGAWA, Satoshi MASUDA, Masaki SUGIYAMA, Yosuke KAZUMOTO, Hisaya SUGIMOTO, Hiroaki HATSUYAMA
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Patent number: 11813686Abstract: An object of the present invention is to provide an Sn—Bi—Cu—Ni solder alloy or the like which has a low melting point, excellent ductility, and high tensile strength, and in which if soldering is performed on a Cu electrode subjected to electroless Ni plating treatment, a solder joint formed through this soldering exhibits high shear strength. In addition, another object of the present invention is to provide an Sn—Bi—Cu—Ni solder alloy in which a solder joint formed through soldering exhibits high shear strength even for a Cu electrode which has not been subjected to plating treatment. Furthermore, still another object of the present invention is to provide, in addition to the above-described objects, a solder alloy or the like of which yellowish discoloration can be suppressed and in which change in viscosity of a solder paste over time can be suppressed. The solder alloy has an alloy composition consisting of, by mass %, 31% to 59% of Bi, 0.3% to 1.0% of Cu, 0.01% to 0.06% of Ni, 0.0040% to 0.Type: GrantFiled: May 15, 2020Date of Patent: November 14, 2023Assignee: SENJU METAL INDUSTRY CO., LTD.Inventors: Hiroyoshi Kawasaki, Masato Shiratori, Yuji Kawamata
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Publication number: 20230356314Abstract: A soldering apparatus includes a cooling zone, upper and lower vent holes, an external channel, a blower unit, a heat exchanger, a pair of bypass channels, and a ventilation plate. The vent holes are provided, respectively, above and below a pair of rails configured to transport a board in the cooling zone. The external channel connects the vent holes with each other outside the cooling zone. The blower unit causes gas in the external channel to flow through the upper vent hole, the cooling zone, and the lower vent hole. The heat exchanger is provided in a lower opening linked to the lower vent hole in the cooling zone. The pair of bypass channels deliver gas above the pair of rails to the lower opening while bypassing locations of the pair of rails. The ventilation plate is provided in a space formed between the pair of bypass channels.Type: ApplicationFiled: June 14, 2021Publication date: November 9, 2023Applicant: SENJU METAL INDUSTRY CO., LTD.Inventor: Yuta SAITO
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Publication number: 20230347437Abstract: Provided is a soldering device in which gas is drawn through suction ports in a first plate more uniformly than in a conventional device. A soldering device according to the present disclosure is a soldering device for performing soldering and includes a blower unit for supplying gas to an object. The blower unit includes: a first plate in which a plurality of suction ports for drawing of the gas outside the blower unit are formed; a second plate that has a plate surface facing the plurality of suction ports; a plurality of nozzles; and a fan for supplying the gas drawn through the plurality of suction ports to the plurality of nozzles. A flow path through which the gas flows and which extends from the plurality of suction ports to go through a heater and the fan and to reach the plurality of nozzles is formed in the blower unit. A part of the flow path surrounds at least a part of the second plate in directions in which the plate surface extends.Type: ApplicationFiled: August 25, 2021Publication date: November 2, 2023Applicant: SENJU METAL INDUSTRY CO., LTD.Inventor: Tsutomu HIYAMA
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Patent number: 11794288Abstract: A rosin-modified product being a reactant of a rosin or a rosin derivative and an alkanolamine represented by a following Formula (1) NH3-n—(R—OH)n(n?3); or??(1) being produced by a reaction of a rosin or a rosin derivative, an organic acid and an alkanolamine.Type: GrantFiled: September 11, 2020Date of Patent: October 24, 2023Assignee: SENJU METAL INDUSTRY CO., LTD.Inventor: Toshio Mizowaki