Patents Assigned to Shanghai Research Institute of Petrochemical Technology Sinopec
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Patent number: 9242236Abstract: A catalyst composition comprising on weight basis the following components: a) 30 to 99.5% of at least one intergrowth molecular sieve; b) 0 to 20% of a rare earth element or oxides thereof; c) 0 to 10% of at least one element from Group VA of the Periodic Table or oxides thereof; d) 0 to 10% of at least one element from Group IIIA of the Periodic Table or oxides thereof; e) 0 to 20% of at least one element from Group IB or IIB of the Periodic Table or oxides thereof; f) 0 to 20% of at least one element from Group IA or IIA of the Periodic Table or oxides thereof; and g) 0 to 65% of a binder, wherein the components b), c), d), e) and f) are supported on the component a), and contents of at least two of the components b), c), d), e) and f) are larger than zero, is described. A process for preparing said catalyst composition and a process for the production of olefins via catalytic cracking by using said catalyst composition are also described.Type: GrantFiled: April 3, 2008Date of Patent: January 26, 2016Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Guangwei Ma, Weimin Yang, Hui Yao, Xiaqin Yang
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Patent number: 9233350Abstract: The invention provides a start-up method for a reaction-regeneration unit for preparing light olefins from methanol, which comprises: (a) heating a regenerator with an auxiliary combustion chamber and a reactor with a start-up furnace; (b) charging a catalyst into the regenerator and reactor; (c) closing a spent catalyst slide valve and a regenerated catalyst slide valve after the reactor reaches about 350° C. or more; (d) feeding methanol to the reactor after the dense phase stage of the regenerator reaches about 350° C. or more; (e) opening the spent catalyst slide valve and introducing a carbon deposited catalyst from the reactor to the regenerator after the dense phase stage reaches about 400° C. or more and the average amount of carbon deposits on the catalyst in the reactor reaches about 2.5% or more; (f) raising the regenerator to above about 580° C.; and (g) stopping the start-up furnace and auxiliary combustion chamber.Type: GrantFiled: January 8, 2013Date of Patent: January 12, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPECInventors: Guozhen Qi, Siqing Zhong, Zhinan Yu, Yongming Jin
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Patent number: 9221724Abstract: A process for producing at least one light olefin, comprising converting three raw materials in the presence of at least one catalyst comprising at least one molecular sieve and regenerating said at least one catalyst into three separate product streams.Type: GrantFiled: June 13, 2011Date of Patent: December 29, 2015Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SINOPECInventors: Guozhen Qi, Songyuan Gu, Siqing Zhong, Yongming Jin
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Patent number: 9212105Abstract: A process for producing at least one light olefin comprising: (a) contacting a first raw material comprising methanol with a least one catalyst in a first reaction zone to produce at least one light olefin and at least one inactivated catalyst; (b) transporting the at least one inactivated catalyst to a first regeneration zone to produce at least one first regenerated catalyst, and transporting a portion of the at least one first regenerated catalyst to the first reaction zone; (c) transporting another portion of the at least one first regenerated catalyst to a second regeneration zone to obtain at least one second regenerated catalyst; and (d) transporting the at least one second regenerated catalyst to a second reaction zone, and contacting the at least one second regenerated catalyst with a second raw material comprising C4 olefins to produce a product stream II comprising at least one light olefin.Type: GrantFiled: March 3, 2011Date of Patent: December 15, 2015Assignees: Shanghai Research Institute of Petrochemical Technology, Sinopec, China Petroleum & Chemical CorporationInventors: Guozhen Qi, Siqing Zhong, Hongtao Wang, Yongming Jin
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Patent number: 9102583Abstract: A process for producing ethylene glycol includes contacting an oxalate with a fluidized bed catalyst under the following conditions: a reaction temperature of from about 170 to about 270° C., a weight space velocity of oxalate of from about 0.2 to about 7 hours?1, a hydrogen/ester molar ratio of about 20˜200:1, a reaction pressure of from about 1.5 to about 10 MPa, and a reaction temperature difference T of from about 1 to about 15° C. The fluidized bed catalyst includes: a) from about 5 to about 80 parts by weight of copper and the oxide thereof, b) from about 10 to about 90 parts by weight of at least one carrier selected from silica, molecular sieve or alumina, c) from about 0.01 to about 30 parts by weight of bismuth and tungsten metallic elements or the oxides thereof, or cerium and niobium metallic elements or the oxides thereof.Type: GrantFiled: February 24, 2012Date of Patent: August 11, 2015Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPECInventors: Weimin Yang, Juntao Liu, Wanmin Wang, Jun Kuai
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Patent number: 9084984Abstract: The present invention discloses a process for the selective hydrogenation of phenylacetylene in the presence of styrene, comprising contacting a phenylacetylene and styrene-containing hydrocarbon fraction feedstock with a carbon-containing catalyst under hydrogenation reaction conditions, wherein the carbon-containing catalyst has a carbon content of from 0.02 to 8 wt % based on the weight of the catalyst.Type: GrantFiled: December 17, 2009Date of Patent: July 21, 2015Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SinopecInventors: Siqin Li, Juntao Liu, Fengxia Sun, Wanmin Wang, Yuanlin Cheng
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Patent number: 9085501Abstract: A process for increasing the yield of ethylene and propylene, comprising: (1) feeding a feedstock into a reaction zone with a catalyst to produce (i) a product stream and a catalyst to be regenerated; (2) stripping and then dividing the catalyst to be regenerated into at least two parts, wherein a first part is recycled into the reaction zone at a first position, and a second part is regenerated in the regenerator to form a regenerated catalyst and then recycled into the reaction zone at a second position; and (3) controlling the temperature increase in the reaction zone.Type: GrantFiled: November 16, 2011Date of Patent: July 21, 2015Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SinopecInventors: Guozhen Qi, Zhe Yang, Huiming Zhang, Li Wang, Ju Wang, Xiaohong Li, Huawen Wang
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Patent number: 9051236Abstract: A method for improving the quality of ethylene glycol products, which mainly solves the technical problem of low UV-light transmittance of the ethylene glycol products present in the prior art. The method successfully solves the problem by use of the technical solution wherein the ethylene glycol raw material and hydrogen are passed through a rotating packed bed reactor loaded with solid oxide catalyst at a temperature of about 20 to about 280° C., a pressure of about 0.1 to about 4.0 MPa, a space velocity of about 0.2 to about 100.0 hr?1 and a molar ratio of hydrogen to ethylene glycol of from about 0.01 to 40:1, and ethylene glycol is obtained after the reaction. The solid oxide catalyst is at least one of copper-based, nickel-based and palladium-based catalysts, and the rotation rate of the rotating packed bed reactor is about 300 to about 5000 rpm.Type: GrantFiled: February 24, 2012Date of Patent: June 9, 2015Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPECInventors: Juntao Liu, Yuhong Zhang, Wanmin Wang
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Publication number: 20150119619Abstract: A method for producing isopropyl benzene includes the following steps. Step A: feeding a first stream containing benzene and a first stream containing propylene into a first reaction zone to contact a first catalyst for alkylation, and obtaining a first stream containing isopropyl benzene from the first reaction zone, dividing the first stream containing isopropyl benzene into a stream Ia and a stream IIa, the stream Ia circulating back into the first reaction zone and the stream IIa entering into a second reaction zone, having the stream entering the second reaction zone to contact a second catalyst for alkylation, and obtaining a second stream containing isopropyl benzene from the second reaction zone, and purifying at least a partial stream IIIa of the second stream containing isopropyl benzene, and obtaining a product isopropyl benzene.Type: ApplicationFiled: October 28, 2014Publication date: April 30, 2015Applicants: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SINOPECInventors: Huanxin GAO, Hongyuan ZONG, Yilun WEI, Hui YAO, Ruifang GU, Hua FANG, Shufang JI
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Patent number: 8962895Abstract: The present invention relates to a method for the production of ethylene glycol using a feedstock comprising an oxalate and a catalyst containing copper and/or a copper oxide, comprising contacting the feedstock with the catalyst in a reactor under the conditions of a temperature in the range from about 170 to about 270° C., a weight hourly space velocity of the oxalate in the range from about 0.2 to about 5 h?1, a molar ratio of hydrogen to the oxalate in the range from about 40:1 to about 200:1 and a reaction pressure in the range from about 1.5 to about 10 MPa, to produce an effluent containing ethylene glycol, in which the reactor is a tube-array reactor using partitioned heat exchange and adopting outer and inner tubes configured in a double-tube structure to facilitate the heat exchange of the catalyst.Type: GrantFiled: February 24, 2012Date of Patent: February 24, 2015Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SinopecInventors: Juntao Liu, Weimin Yang, Lei Li, Wanmin Wang, Linna Zhang, Haifeng Song
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Patent number: 8921592Abstract: A process of producing oxalate by CO gas phase method includes the following steps: a) introducing nitrite salt, water and an inorganic acid first into a reactor I to produce a NO containing effluent I; and separating the resultant effluent to obtain the effluent II of NO; b) introducing the effluent II of NO, a C1-C4 alkanol and oxygen into a reactor II to be subjected to the reaction, and separating the resultant effluent to obtain the effluent IV of C1-C4 alkyl nitrites; c) introducing the effluent IV of C1-C4 alkyl nitrites and a CO gas stream into a coupling reactor where they are reacted to produce a NO containing effluent VI. The reactor I and/or the reactor II are preferably rotating supergravity reactors. Therefore, the process is applicable to the industrial production of oxalate by CO gas phase method.Type: GrantFiled: June 9, 2011Date of Patent: December 30, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SINOPECInventors: Weimin Yang, Juntao Liu, Wanmin Wang, Lei Li
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Method for selective hydrogenation of phenylacetylene using composite bed in the presence of styrene
Patent number: 8916736Abstract: The present invention discloses a process for the selective hydrogenation of phenylacetylene in the presence of styrene conducted in a combined bed, which process comprises under hydrogenation reaction conditions, passing a hydrocarbon fraction feedstock containing phenylacetylene and styrene through a combined bed reactor containing a catalyst A and a catalyst B to contact the feedstock with the catalyst A and the catalyst B in turn, wherein the catalyst A is a nickel-based catalyst, the catalyst B is at least one selected from the group consisting of palladium-based catalysts and copper-based catalysts, and a weight ratio of the catalyst A loaded to the catalyst B loaded is from 0.5:1 to 5:1.Type: GrantFiled: December 17, 2009Date of Patent: December 23, 2014Assignees: Shanghai Research Institute of Petrochemical Technology, Sinopec, China Petroleum & Chemical CorporationInventors: Siqin Li, Juntao Liu, Zhiyan Zhu, Junhua Zhu, Jun Kuai -
Patent number: 8906205Abstract: A process for separating ethylene glycol and 1,2-butanediol. A material flow containing ethylene glycol and 1,2-butanediol gets into the lower-middle part of the azeotropic rectification column C3 after the light components are removed by the separating columns C1 and C2, wherein the ethylene glycol and the azeotropic agent added from the top of the column form azeotrope which is distilled out from the top of the column and gets into the phase separator D1 after being condensed, the upper phase enriched with azeotropic agent after the phase was separated returns to the top of the column to continue to participate in azeotropy, and the lower phase enriched with ethylene glycol gets into the fourth separating column C4 to be refined to obtain the ethylene glycol product.Type: GrantFiled: January 8, 2013Date of Patent: December 9, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SINOPECInventors: Jian Xiao, Yanzi Guo
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Patent number: 8871968Abstract: The present invention relates to a process of producing oxalate by CO gas phase method for chiefly solving the technical problem of the low utilization efficiency of nitrogen oxides or nitrous acid esters in the prior art.Type: GrantFiled: April 13, 2011Date of Patent: October 28, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Juntao Liu, Fengxia Sun, Jun Kuai
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Publication number: 20140221719Abstract: The present disclosure provides a premixer for at least two gases, comprising: a tabular body having a closed end and an opposite, open end; a first flow passage for receiving a first gas, the first flow passage axially extending through the closed end into the tabular body in a sealable manner; a conical tube arranged in the tabular body, wherein a small end of the conical tube communicates with the first flow passage, and a large end of the conical tube extends toward the open end with an edge thereof being fixed to an inner wall of the tabular body, thereby defining a sealed distribution chamber between the tabular body and the conical tube; and a second flow passage arranged on a side portion of the tabular body for receiving a second gas, wherein the second flow passage communicates with the distribution chamber, so that the second gas can be introduced into said conical tube via the distribution chamber in a substantially radial manner.Type: ApplicationFiled: January 27, 2014Publication date: August 7, 2014Applicants: Shanghai Research Institute of Petrochemical Technology, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Weimin YANG, Wenjie LIU, Yunqun HUANG, Yi GUO, Depan SHI
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Patent number: 8796499Abstract: A process for producing light olefins from methanol and/or dimethyl ether is disclosed. It comprises: (a) introducing a feed comprising methanol and/or dimethyl ether into a fluidized-bed reactor from its bottom, and contacting the feed in a dense phase zone and a transition zone of the fluidized-bed reactor with a catalyst, to form an effluent I comprising unreacted feed, reaction products and entrained solid particulate catalyst; (b) introducing a terminating agent consisting of water, alcohol, ether, hydrocarbons, and aromatic at upper portion of the transition zone and/or lower portion of a gas-solid separating zone of the fluidized-bed reactor into the effluent I, to give an effluent II; and (c) passing the effluent II into the gas-solid separating zone in upper portion of the fluidized-bed reactor, where gas-solid separation is accomplished to give a gaseous product stream and solid catalyst.Type: GrantFiled: October 19, 2007Date of Patent: August 5, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Juntao Liu, Siqing Zhong, Huiming Zhang
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Publication number: 20140186231Abstract: A process for producing light olefins is provided. A feedstock enters a pre-reaction zone and contacts a catalyst comprising at least one silicon-aluminophosphate molecular sieve and produces a gas-phase stream; the gas-phase stream and the catalyst enter at least one riser, and the gas-phase stream and the catalyst pass from an outlet of the at least one riser and enter a gas-solid rapid separation zone; the separated gas-phase stream enters a separation section; a first portion of the separated catalyst returns to the pre-reaction zone, and a second portion is regenerated in a regenerator; wherein an inlet of the at least one riser extends into the pre-reaction zone, about 60% to about 90% of the height of the at least one riser passes through a heat exchange zone, and the outlet extends into the gas-solid rapid separation zone.Type: ApplicationFiled: March 5, 2014Publication date: July 3, 2014Applicants: Shanghai Research Institute of Petrochemical Technology, Sinopec, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Guozhen QI, Siqing ZHONG, Wei CHEN, Zhinan YU
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Patent number: 8722918Abstract: The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from ?0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.Type: GrantFiled: April 15, 2011Date of Patent: May 13, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Juntao Liu, Siqin Li, Lei Li, Linna Zhang
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Publication number: 20140066680Abstract: The present disclosure provides a catalyst for oxidative dehydrogenation of butene to butadiene, comprising at least one compound of formula ZnaAlbMcFeeOf.Z(?-Fe2O3), wherein M is at least one element chosen from Be, Mg, Ca, Sr, Mn, Ba, Cu, Co, and Ni, Z represents the percentage by weight of ?-Fe2O3 in the catalyst and ranges from 10% to 70%. Also provided herein is a process of preparing said catalyst and the use of said catalyst in an oxidative dehydrogenation of butene to butadiene processes.Type: ApplicationFiled: September 4, 2013Publication date: March 6, 2014Applicants: Shanghai Research Institute of Petrochemical Technology SINOPEC, China Petroleum & Chemical CorporationInventors: Changxi Miao, Wenhai Wu, Zhigui Fan, Tieqiang Zeng, Chunjing Ma, Sheng Wu
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Publication number: 20130338406Abstract: The present invention relates to a method for the production of ethylene glycol using a feedstock comprising an oxalate and a catalyst containing copper and/or a copper oxide, comprising contacting the feedstock with the catalyst in a reactor under the conditions of a temperature in the range from about 170 to about 270° C., a weight hourly space velocity of the oxalate in the range from about 0.2 to about 5 h?1, a molar ratio of hydrogen to the oxalate in the range from about 40:1 to about 200:1 and a reaction pressure in the range from about 1.5 to about 10 MPa, to produce an effluent containing ethylene glycol, in which the reactor is a tube-array reactor using partitioned heat exchange and adopting outer and inner tubes configured in a double-tube structure to facilitate the heat exchange of the catalyst.Type: ApplicationFiled: February 24, 2012Publication date: December 19, 2013Applicants: SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Juntao Liu, Weimin Yang, Lei Li, Wanmin Wang, Linna Zhang, Haifeng Song