Patents Assigned to Tokai Carbon Co., Ltd.
  • Patent number: 5265118
    Abstract: A silicon carbide whisker production apparatus manufactured by placing a plurality of lidded reaction vessels in the longitudinal direction of an Acheson furnace at intervals, packing graphite grains in the gaps between the adjacent reaction vessels and around the reaction vessels along the longitudinal direction of the furnace starting with the furnace-side ends of terminal electrodes to form a surrounding heating zone, and packing a heat insulating packing around the surrounding heating zone.
    Type: Grant
    Filed: March 18, 1992
    Date of Patent: November 23, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Takashi Takenaka, Shigeto Mori, Osamu Machida
  • Patent number: 5256243
    Abstract: A process for producing a titanium carbide whisker, comprising the steps of: mixing 100 parts by weight of a titanium source comprising titanium dioxide and/or an alkali metal titanate with 50 to 200 parts by weight of a carbon source and 1 to 30 parts by weight of a transition metal chloride; and heating the resultant mixture at 1300.degree. to 1700.degree. C. in an inert gas atmosphere.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: October 26, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Tohru Kida
  • Patent number: 5252297
    Abstract: An apparatus for producing carbon black comprises a reaction chamber which consists of a tapered throat and a downstream extension of the throat having the same diameter as that of the narrowest portion of the throat and provided with a plurality of ribs on its inner wall which define a plurality of flits parallel to the axis of the reaction chamber. The reaction chamber is equipped, on the upstream side of the extension, with means for introducing the feedstock oil perpendicularly to the axis of the chamber.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: October 12, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Kiyonari Nakai
  • Patent number: 5246894
    Abstract: A silicon carbide reinforced composite material comrpising a base material and, dispersed therein, a reinforcement comprising a silicon carbide whisker and an elliptical silicon carbide particle.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: September 21, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Hiroshi Okuda, Itsuro Imazu
  • Patent number: 5231129
    Abstract: A rubber composition comprising 100 parts by weight of a rubber ingredient compounded with 35-100 parts of a carbon black, said carbon black having a nitrogen adsorption specific surface area (N.sub.2 SA) of 60-160 m.sup.2 g and a dibutyl phthalate adsorption number (DBP) of 90-150 ml/100 g, and the intraaggregate mode diameter (Dp mode diameter) of the carbon black satisfying the following formula:Dp mode diameter .gtoreq.75.2.times.(DBP/N.sub.2 SA)+8.0 wherein the Dp mode diameter refers to a mode diameter at the maximum frequency in the pore diameter distribution of carbon black particles measured by means of a differential scanning calorimeter (DSC).
    Type: Grant
    Filed: April 23, 1992
    Date of Patent: July 27, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Shinji Misono
  • Patent number: 5230878
    Abstract: A carbon black of the category of hard carbon blacks having a nitrogen adsorption specific surface area (N.sub.2 SA) of 120 to 165 m.sup.2 /g and a DBP absorption number of 120 ml/100 g or more and satisfying requirements respectively represented by the following formulae (1) and (2):Dst.ltoreq.(4.35.times.dn)-10.0 (1) ##EQU1## In the formulae (1) and (2), dn is the arithmetic average diameter (nm) measured by electron microscopy, .DELTA.Dst (nm) is the difference between two Stokes diameters each obtained in a frequency of 50% of the maximum frequency in a distribution curve of the aggregate Stokes diameter, Dst (nm) is the Stokes diameter of the maximum frequency in the distribution curve of the aggregate Stokes diameter, N.sub.2 SA is the nitrogen adsorption specific surface area (m.sup.2 /g) and IA is the iodine adsorption number (mg/g).
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: July 27, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Kiyonari Nakai, Fumio Takemura
  • Patent number: 5225475
    Abstract: A rubber composition comprising 100 parts by weight of a rubber component which consists of a natural rubber alone or a blend of a natural rubber with a dienic synthetic rubber and from 35 to 100 parts by weight of a carbon black compounded into the rubber. The carbon black has a nitrogen adsorption specific surface area (N.sub.2 SA) of 100 to 160 m.sup.2 /g and also a true specific gravity and a mode diameter of intraaggregate pore (Dp) which satisfy, respectively, the relations1 true specific gravity.ltoreq.1.8379-0.0006.times.N.sub.2 SA(1) ##EQU1## where Dp in the formula (2) represents the mode diameter at the maximum frequency in the intraaggregate pore diameter distribution of the carbon black determined with a differential scanning calorimeter (DSC), and DBP represents the dibutyl phthalate absorption number.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: July 6, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Shinji Misono
  • Patent number: 5198205
    Abstract: There is disclosed carbon black for a tire tread rubber which has a nitrogen adsorption specific surface area (N.sub.2 SA) of 60 to 160 m.sup.2 /g and a dibutyl phthalate absorption (DBP) of 90 to 150 ml/100 g which belong to the respective regions of hard grades of carbon black, and an intraaggregate void volume Vp (ml/g) at least equal to the value calculated according to the equation: [0.00976.times.DBP-0.0358].
    Type: Grant
    Filed: September 13, 1991
    Date of Patent: March 30, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Yasuharu Yoshii, Shinji Misono, Hitoshi Ue
  • Patent number: 5194409
    Abstract: The present invention discloses a process for producing a boron nitride-coated SiC whisker, comprising dissolving a borazine represented by the following formula (I) in hexane, dispersing a SiC whisker in the resultant solution, collecting the SiC whisker thus treated by filtration, drying and baking it in a non-oxidizing atmosphere at 1000.degree. to 1800.degree. C. to form a boron nitride coating on the surface of the SiC whisker: ##STR1## wherein R is an atom or a group selected from the group consisting of Cl, N(C.sub.2 H.sub.5).sub.2, NH.sub.2, NHCH.sub.3 and CH.sub.3, and R' is an atom or a group selected from the group consisting of H and CH.sub.3.
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: March 16, 1993
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Takaomi Sugihara
  • Patent number: 5162421
    Abstract: A rubber composition comprising 100 parts by weight of a rubber component and compounded therewith 30 to 100 parts by weight of a carbon black of the category of hard carbon blacks having a nitrogen adsorption specific surface area (N.sub.2 SA) of 58 to 139 m.sup.2 /g, a DBP absorption number of 90 to 150 ml/100 g and having such selective characteristics that the intraaggregate void size, D.sub.p (nm), as measured by mercury porosimetry is equal to or higher than a value calculated by the relational formula [-0.22.times.(N.sub.2 SA)+60.8].
    Type: Grant
    Filed: April 15, 1991
    Date of Patent: November 10, 1992
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Hitoshi Ue, Yasuharu Yoshii, Shinji Misono
  • Patent number: 5143746
    Abstract: A process for producing a magnetite-coated electrode which comprises kneading an iron oxide powder, water and an organic binder under pressure sufficient to prepare a molded article, baking the molded article in a gas atmosphere mainly composed of a member selected from the group consisting of carbon dioxide and steam to prepare a magnetite sinter having an Fe to 0 ratio of 3:3.7 to 4.0, pulverizing the sinter to prepare a powder, and subjecting a metallic substrate to plasma spray coating, plasma jet spray coating, explosive spray coating and water plasma spray coating by making use of the powder as the spray coating source in a neutral gas atmosphere to form a magnetite coating on the surface of the metallic substrate.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: September 1, 1992
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Hideo Inoue, Setsuo Yoshimoto, Sakae Ikegami
  • Patent number: 5120354
    Abstract: A method of disposing of a fiber reinforced aluminum alloy composite, which comprises putting an aluminum alloy composite reinforced with inorganic short fibers into a molten steel in the deoxidizing process for steel production.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: June 9, 1992
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Takashi Ichiki
  • Patent number: 5105448
    Abstract: A device for counting the number of very small projections on a surface of an object, which includes a casing therein housing a probe to be scanned in contact with the surface of the object having continuously occurring very small projections, a tip end portion of the probe being projected out of a forward end of the casing; a detecting unit including an acceleration sensor; a comparator for converting electric signals emitted from the detecting unit into pulse signals; a latching device provided with a delay circuit for latching the pulse signals received and maintaining its emitted signals for a certain length of time; and a display device for counting and displaying the output signals from the latching device.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: April 14, 1992
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Tarou Kashiwabara
  • Patent number: 5100637
    Abstract: Carbon black for compounding into a tire tread rubber which has a nitrogen adsorption specific surface area (N.sub.2 SA) of 120 to 165 m.sup.2 /g and a dibutyl phthalate absorption of at least 120 ml/100 g which belong to the respective regions of hard grade of carbon black, and has such a value G defined by the following equation (1) as satisfying the following formula (2): ##EQU1## wherein [.DELTA.D.sub.st ] stands for a difference between two equivalent Stokes diameters at two points on the distribution curve of aggregates at which the absorbance is 50% of the maximum absorbance; [D.sub.st ] stands for an equivalent Stokes diameter (nm) at the maximum absorbance of the distribution curve of aggregates; [N.sub.2 SA] stands for a nitrogen adsorption specific surface area (m.sup.
    Type: Grant
    Filed: March 11, 1991
    Date of Patent: March 31, 1992
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Kiyonari Nakai
  • Patent number: 5069892
    Abstract: The present invention discloses a carbon black having an N.sub.2 SA of 75 to 105 m.sup.2 /g and a compressive DBP absorption of at least 110 ml/100 g and, at the same time, having the following selective characteristic values:true specific gravity.ltoreq.1.9080-0.0016.times.N.sub.2 SA;void diameter of particle aggregates (nm).gtoreq.62.2-0.236.times.N.sub.2 SA; andrange of aggregate size distribution [.DELTA.Dst (nm)].gtoreq.30.6+0.6118.times.Dst.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: December 3, 1991
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Kiyonari Nakai
  • Patent number: 5059408
    Abstract: There is disclosed carbon black for a tire tread which has a cetyltrimethylammonium bromide specific surface area (CTAB) of 120 to 160 M.sup.2 /g, a dibutly phthalate absorption number of compressed sample (24M4DBP) of at least 100 to 145 ml/100g, a tinting strength (Tint) of 100 to 150%, and such a value Ma defined by the following equation (1) as to satisfy the relationship expressed by the following formula (2): ##EQU1## wherein N.sub.2 SA is a nitrogen adsorption specific surface area (m.sup.2 /g), and Dst is the equivalent Stokes diameter (nm) at the maximum absorbance of the distribution curve of aggregates determined by the centrifugal classification method, and psMa.gtoreq.1.7-0.005 [CTAB]TM . . . (2).
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: October 22, 1991
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Masahiko Mito
  • Patent number: 5053278
    Abstract: A granular carbonaceous heat insulator comprising a carbon black pellet the surface of which is coated with a carbon layer having a dense structure is disclosed. This heat insulator is prepared by adhering a binder solution to a carbon black pellet, heating the resulting coating to remove a solvent from the binder solution and, at the same time, to cure the binder, and baking the carbon black pellet coated with the cured binder in a non-oxidizing atmosphere to carbonize the cured binder. Alternatively, the heat insulator is prepared by subjecting a carbon black pellet having specific characteristics to wet granulation in the presence of a binder solution to crush the carbon black pellet and, at the same time, to granulate the crushed pellet, thereby preparing a granulated carbon black pellet, followed by removal of the solvent from the prepared pellet, curing of the binder and baking of the cured binder in the same manner as that described above.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: October 1, 1991
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Toshio Nakada, Fumio Takemura, Masao Ishiwata
  • Patent number: 4995999
    Abstract: Magnetic carbon black, a process for preparing the same, and a method of modifying magnetic carbon black are provided. The magnetic carbon black is prepared by process A in which when a hydrocarbon is supplied into a high temperature combustion gas stream formed by combustion of a fuel to prepare carbon black, an organic transition metal compound is supplied together with the hydrocarbon and, at the same time, an oxygen gas is supplied from the circumference of the hydrocarbon, process B in which a transition metal compound is supplied together with a hydrogen gas on the downstream side of the supply position of the hydrocarbon, and process C in which a hydrocarbon is supplied into a high temperature combustion gas stream on both the upstream side and the downstream side and a transition metal compound is supplied from a position between the supply positions of the hydrocarbon.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: February 26, 1991
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Toshio Nakada, Fumio Takemura, Yoshihito Sema, Kazuhito Kataoka
  • Patent number: 4973463
    Abstract: The present invention discloses carbon black for a tire tread having a cetyltrimethyl ammonium bromide specific surface area (CTAB) of 120 to 160 m.sup.2 /g, a dibutyl phthalate absorption number of compressed sample (24M4) of 95 to 135 ml/100 g, and a tinting strength (Tint) of 100 to 150% and exhibits an M value defined by the following formula (1) and satisfying the following formula (2): ##EQU1## wherein IA is the iodine adsorption number (mg/g), N.sub.2 SA is the nitrogen adsorption specific surface area (m.sup.2 /g), Dst is the equivalent Stokes diameter (nm) at the maximum absorbance of the distribution curve of aggregates determined by the centrifugal classification method, and .DELTA.Dst is the difference (nm) between two equivalent Stokes diameters at two points on the distribution curve of aggregates at which the absorbance is 50% of the maximum absorbance.
    Type: Grant
    Filed: April 25, 1989
    Date of Patent: November 27, 1990
    Assignee: Tokai Carbon Co., Ltd.
    Inventor: Kiyonari Nakai
  • Patent number: 4929472
    Abstract: Disclosed are surface-coated SiC whiskers, proceses for preparing the same, a ceramic reinforced with the same, and a process for preparing said reinforced ceramic. The surface-coated SiC whiskers are SiC whiskers (I) having a surface coated with a thin carbonaceous layer having a thickness of 7 to 100 .ANG., or SiC whiskers (II) having a surface coated with an Si.sub.3 N.sub.4 layer. The SiC whiskers (I) can be prepared by dispersing SiC whiskers in a homogeneous solution of a thermosetting resin in an organic solvent, separating the whiskers by filtration and drying it, curing the thermosetting resin, and firing the cured thermosetting resin in a non-oxidizing atmoshpere at 800.degree. to 1,600.degree. C. The SiC whiskers (II) can be prepared by dispersing SiC whiskers in a solution of an organosilicon polymer in an organic solvent, separating the whiskers by filtration and drying it, heating the whiskers coated with the organosilicon polymer in a nitriding atmoshpere at 1,200.degree. to 1,600.degree. C.
    Type: Grant
    Filed: May 31, 1988
    Date of Patent: May 29, 1990
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Kanji Sugihara, Motohiro Yamamoto, Tohru Kida, Minoru Fukazawa