Patents Assigned to W. R. Grace & Co.-Conn.
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Patent number: 8453405Abstract: Disclosed is a waterproofing membrane that bonds to concrete cast against it (i.e., post-cast concrete). The membrane includes a flexible carrier sheet, a pressure sensitive adhesive and reflective particles on the surface of the adhesive. The reflective particles should have an average diameter equal to or greater than the thickness of the pressure sensitive adhesive. Preferably, the reflective particles are ground white cement, ground hydrated white cement, ground partially-hydrated white cement or a mixture of two or more of these. The membrane does not have a removable release sheet that is typically used to prevent the adhesive portion of the membrane from adhering to the carrier sheet or other portion of the membrane when the membrane is rolled up.Type: GrantFiled: February 8, 2010Date of Patent: June 4, 2013Assignee: W. R. Grace & Co.-Conn.Inventors: Robert A. Wiercisnki, Hongmei Ding, Xia Cao
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Patent number: 8410197Abstract: The composition of this invention is an inorganic oxide particulate comprising at least 10% by weight organic material in which the particulate has an auto-ignition temperature which is at least 20° C. higher than the auto-ignition temperature of the particulate and organic material which does not contain antioxidant and/or inhibitor. Accordingly, a method has been developed in which one is able to elevate the auto-ignition temperature of such organic containing particulates. In a preferred embodiment the method comprises including antioxidant or inhibitor in the organic material prior to combining it with the inorganic oxide.Type: GrantFiled: June 26, 2002Date of Patent: April 2, 2013Assignee: W. R. Grace & Co. -Conn.Inventor: Volker Petry
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Patent number: 8397553Abstract: A flow controller for use with a liquid chromatography detector. The flow controller includes a flow channel comprising an inlet portion, a control channel portion in communication with the inlet portion, and an outlet portion in communication with said control channel portion. The control channel portion has a cross-sectional area smaller than a cross-sectional area of a drift tube of the liquid chromatography detector for channeling the flow of droplets through the smaller cross-sectional area. The flow controller is shaped and sized to reduce pressure fluctuations and turbulence in the droplet stream of the liquid chromatography detector.Type: GrantFiled: December 6, 2007Date of Patent: March 19, 2013Assignees: The Curators of the University of Missouri, W.R. Grace & Co.-ConnInventors: Zhi Xu, Rakesh Bose, James M. Anderson
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Publication number: 20130001134Abstract: Catalytic cracking catalyst compositions and processes for cracking hydrocarbons to maximize light olefins production are disclosed. Catalyst compositions comprise at least one zeolite having catalytic cracking activity under catalytic cracking conditions, preferably Y-type zeolite, which zeolite has low amounts of yttrium in specified ratios to rare earth metals exchanged on the zeolite. Catalyst and processes of the invention provide increased yields of light olefins and gasoline olefins during a FCC process as compared to conventional lanthanum containing Y-type zeolite FCC catalysts.Type: ApplicationFiled: March 8, 2011Publication date: January 3, 2013Applicant: W. R. Grace & Co.-Conn.Inventors: Yuying Shu, Richard F. Wormsbecher, Wu-Cheng Cheng
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Publication number: 20130005565Abstract: This invention relates to a process of preparing a catalyst from zeolite and peptized alumina. The invention comprises adding a yttrium compound to the zeolite, either prior to, during, or after its combination with the peptized alumina. The yttrium compound can be added to the zeolite via exchange of yttrium onto the zeolite prior to addition of peptized alumina, or the yttrium can be added as a soluble salt during the combination of the zeolite and peptized alumina. In either embodiment, the zeolite catalyst is then formed from the zeolite, yttrium and peptized alumina, optionally containing other inorganic oxide. This invention is suitable for preparing fluid cracking catalysts.Type: ApplicationFiled: March 1, 2011Publication date: January 3, 2013Applicant: W. R. Grace & Co.-Conn.Inventors: Yuying Shu, Richard F. Wormsbecher, Wu-Cheng Cheng
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Publication number: 20120329639Abstract: This invention relates to a process of preparing an improved catalyst comprising a clay derived zeolite. In particular, the invention comprises combining an yttrium compound with a zeolite produced by treating clay with a silica source and under alkaline conditions. The clay derived zeolite can be further combined with conventional matrix and/or binder precursors to form particulates suitable for use as catalysts in fluid catalytic cracking (FCC). Alternatively, the clay that is treated with the silica source and alkaline conditions can be in particulate form having sizes suitable for use in FCC, and the zeolite is produced in situ within the particulate. Yttrium compound is then combined with the zeolite in the particulate, e.g., via impregnation. It has been shown that the addition of the yttrium compound improves zeolite surface area retention, and zeolite stability in catalysts comprising clay derived zeolites.Type: ApplicationFiled: March 1, 2011Publication date: December 27, 2012Applicant: W. R. Grace & Co.-Conn.Inventors: Yuying Shu, Richard F. Wormsbecher, Wu-Cheng Cheng, Michael D. Wallace
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Patent number: 8317918Abstract: The present invention discloses additive compositions, cementitious compositions, and methods for controlling air in cementitious compositions, wherein a polyalkoxylated polyalkylene polyamine defoamer is deployed in combination with one or more air-entraining agents, such as higher alkanolamines, water-reducing agents including oxyalkylene-containing superplasticizers, or other air entraining agents.Type: GrantFiled: April 25, 2012Date of Patent: November 27, 2012Assignee: W. R. Grace & Co.-Conn.Inventor: Lawrence L. Kuo
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Patent number: 8307861Abstract: Preferred processes are provided for unloading a particulate substance from a container using a cover system comprising a cover and a wand extending through the cover. The processes can include installing the cover system on the container so that the cover mates with the container and the wand extends into the particulate substance, connecting a pipe or a hose to the wand, and drawing the particulate substance through the wand and the pipe or hose.Type: GrantFiled: July 27, 2011Date of Patent: November 13, 2012Assignee: W R Grace & Co -Conn.Inventors: Alfred F Jordan, Lenny L. Albin, Sr., Charles A Cross
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Patent number: 8307859Abstract: Preferred processes are provided for unloading a particulate substance from a container using a cover system comprising a cover and a wand extending through the cover. The processes can include installing the cover system on the container so that the cover mates with the container and the wand extends into the particulate substance, connecting a pipe or a hose to the wand, and drawing the particulate substance through the wand and the pipe or hose.Type: GrantFiled: July 27, 2011Date of Patent: November 13, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Alfred F Jordan, Lenny L. Albin, Sr., Charles A Cross
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Patent number: 8309749Abstract: Processes for preparing aluminoxane comprising: bringing into contact under reaction conditions in an inert atmosphere a liquid containing reaction mixture comprising: (i) a water in oil emulsion comprising water and at least one emulsifier in a first hydrocarbon solvent; and (ii) an organoaluminum compound capable of forming aluminoxane in a second hydrocarbon solvent; provided that the aluminoxane produced by the reaction is present in solution under the reaction conditions. In a preferred embodiment a support carrier for the aluminoxane: (i) is present during the contact step or (ii) is introduced following contact. A polymerization catalyst can be prepared wherein the support carrier is SiO2 and a Group 3 to Group 10 metal containing single site complex is mixed with the aluminoxane. Catalysts suitable for polymerizing an olefin such as ethylene or copolymerizing an olefin with at least one C3 to C20 alpha-olefin can be produced.Type: GrantFiled: June 9, 2010Date of Patent: November 13, 2012Assignee: W R Grace & Co-ConnInventors: Xinggao Fang, Timothy A. Boyer, John Henry Hain, Jr.
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Patent number: 8298661Abstract: Disclosed is a waterproofing membrane that performs well at both high and low temperatures. The waterproofing membrane comprises a carrier support layer and an adhesive layer, wherein the adhesive layer comprises a pressure sensitive bitumen composition comprising bitumen (asphalt), synthetic rubber, high density polyethylene, ground vulcanized crumb rubber and, optionally, a plasticizer. The waterproofing membrane also may optionally include a removable release sheet on the adhesive layer.Type: GrantFiled: August 28, 2009Date of Patent: October 30, 2012Assignee: W. R. Grace & Co.-ConnInventors: Susnata Samanta, Robert A. Wiercinski
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Patent number: 8298662Abstract: Disclosed is a waterproofing membrane that performs well at both high and low temperatures. The waterproofing membrane comprises a carrier support layer and an adhesive layer, wherein the adhesive layer comprises a pressure sensitive bitumen composition comprising bitumen (asphalt), synthetic rubber, high density polyethylene, amorphous polyolefin, ground vulcanized crumb rubber and, optionally, a plasticizer. The waterproofing membrane also may optionally include a removable release sheet on the adhesive layer.Type: GrantFiled: August 28, 2009Date of Patent: October 30, 2012Assignee: W.R. Grace & Co.-Conn.Inventors: Susnata Samanta, Robert A. Wiercinski
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Patent number: 8291668Abstract: The present invention relates to a multi-layer fluid delivery device for post-installation in-situ barrier creation. The device provides a medium for post-installation injection of remedial substances such as waterproofing polymeric resins or cementitious materials, insecticides, mold preventatives, rust retardants and the like. The device comprises a first layer and a second layer, with optionally an intermediate layer therebetween, and a plurality of tubes extending outwardly from the first layer. The first layer is preferably semi-permeable; the second layer is non-permeable; the optional intermediate layer is a void-inducing layer. The multi-layered device is attached to a structural substrate and a construction material such as concrete or shotcrete is applied against its surface (and around the plurality of tubes). Thereafter, a free flowing active substance can be injected through the tubes to fill the air space in the multi-layered device.Type: GrantFiled: June 3, 2009Date of Patent: October 23, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Brian J. Iske, Jyoti Seth, Xia Cao, Sonya M. Santos, Enzo J. Orellana
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Patent number: 8288486Abstract: Disclosed is an improved coating composition for food containers that is resistant to high pH processing environments. The improved coating composition is based upon an epoxy-amino resin coating composition that has been modified with other components to improve its performance in high pH environments balanced with flexibility, formability and abrasion resistance. Typically, the coating composition includes an epoxy resin, an amino resin cross-linking agent, a blocked polyisocyanate and a saturated polyester.Type: GrantFiled: October 12, 2011Date of Patent: October 16, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Armi G. Garcia, Benedick M. Francisco
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Patent number: 8277556Abstract: Lightweight cementitious foams of the invention have excellent dynamic and dimensional stability due to use of foaming system comprising polycarboxylate surfactant foam generating agent, foam stabilizer (e.g., PVOH), and shrinkage reducing admixture to inhibit plastic shrinkage and micro-cracking of cement. The foaming system can be used in conventional cement mortars or concretes as well as with exemplary cementitious slurry systems of the invention, which include an expansive agent, a cross-linking agent for the foam stabilizer. Microfibers can be used in the foam, slurry, or both, to prevent micro-cracking. Cementitious foams can be made without use of autoclave or lightweight aggregates to achieve enhanced compressive strength and thermal insulation properties that compare favorably with conventional foams and insulation materials at comparable densities.Type: GrantFiled: June 5, 2009Date of Patent: October 2, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Neal S. Berke, Jordan S. Merritt, Lianfang Li, Antonio J. Aldykiewicz, Jr., Robert A. Wiercinski, Michael D. Morgan
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Patent number: 8277915Abstract: Disclosed is a self-adhered, vapor permeable, air barrier membrane that is easy to install. The membrane has a Young's modulus of 3000 to 80,000 psi, most preferably 4000 to 15,000 psi, in the cross-direction and 5000 to 100,000 psi, most preferably 5000 to 20,000 psi, in the machine direction.Type: GrantFiled: June 28, 2011Date of Patent: October 2, 2012Assignee: W. R. Grace & Co.-Conn.Inventor: Marysusan Couturier
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Publication number: 20120180872Abstract: A system is adapted to automatically maintain a desired yield level for a slurry flow. Measurements of the electrical conductivity of a slurry are taken and corrected for the effects of temperature and pressure. The corrected conductivity measurements are used to arrive at a value for system yield. The system automatically determines if the yield is too high or too low relative to a desired level, and controls the rate at which accelerator is added to the slurry in order to increase or decrease yield.Type: ApplicationFiled: March 23, 2012Publication date: July 19, 2012Applicant: W. R. GRACE & CO.-CONN.Inventors: Dennis M. Hilton, Karl Taub, Keith Lipford, Philip A. Zanghi
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Patent number: 8221615Abstract: The invention is a composition that is suitable for reducing sulfur species from products produced by petroleum refining processes, especially gasoline products produced by fluidized catalytic cracking (FCC) processes. The composition comprises zeolite, yttrium, and at least one element selected from the group consisting of zinc, magnesium and manganese, wherein the yttrium and element are present as cations. The yttrium and zinc are preferably present as cations that have been exchanged onto the zeolite. The zeolite is preferably a zeolite Y.Type: GrantFiled: February 1, 2011Date of Patent: July 17, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Ruizhong Hu, Richard Franklin Wormsbecher
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Patent number: 8211254Abstract: Disclosed are a can cap sealing composition having superior squeeze-out resistance and sealing performance and a method for using the same. A cap is coated with a sealing composition comprising a rubber component, a tackifier, a filler and an organic peroxide as essential ingredients, the cap is seamed to a filled can and then the sealed can is subjected to a heat-treatment in which a sterilization and a cross-linking reaction take place simultaneously.Type: GrantFiled: June 12, 2008Date of Patent: July 3, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Yoichi Kishi, Shigeki Hayashi, Yasushi Ikeshiro
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Patent number: 8206123Abstract: A system is adapted to automatically maintain a desired yield level for a slurry flow. Measurements of the electrical conductivity of a slurry are taken and corrected for the effects of temperature and pressure. The corrected conductivity measurements are used to arrive at a value for system yield. The system automatically determines if the yield is too high or too low relative to a desired level, and controls the rate at which accelerator is added to the slurry in order to increase or decrease yield.Type: GrantFiled: June 5, 2007Date of Patent: June 26, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Dennis M. Hilton, Karl Taub, Keith Lipford, Philip A Zanghi