Patents Examined by Elvis O. Price
  • Patent number: 9169180
    Abstract: The present invention relates to a method for preparing an anhydrosugar alcohol using hydrol (namely, a crystalline mother liquor remaining after obtaining crystalline glucose from a crude glucose liquor). More particularly, the present invention relates to a method for preparing an anhydrosugar alcohol in a method for performing a dehydration reaction on the hydrogenated sugar so as to convert the hydrogenated sugar to an anhydrosugar alcohol, wherein the method for preparing an anhydrosugar alcohol is configured to use, as at least a portion of the hydrogenated sugar, the product obtained from the hydrogenation of the hydrol which is a by-product or waste generated during the production of glucose, thus relatively lowering the cost for a material as compared with a case of using a high purity raw material (for example, high purity sorbitol), to thus improve economical advantages, and further reduce the amount of waste and cost for disposal of the waste during the production of glucose.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: October 27, 2015
    Assignee: SAMYANG GENEX CORPORATION
    Inventors: Hoon Ryu, Young Jae Jung, Jin Kyung Kim, Do Hyun Kyung, Hyuk Min Park, Seong Ho Cho
  • Patent number: 9163106
    Abstract: A straight-chain unsaturated hydrocarbon group having equal to or more than 10 carbon atoms is bonded to at least one or more of meta positions of all of phenol structure units.
    Type: Grant
    Filed: May 29, 2013
    Date of Patent: October 20, 2015
    Assignee: SUMITOMO BAKELITE CO., LTD.
    Inventor: Yuji Suzuki
  • Patent number: 9156754
    Abstract: A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
    Type: Grant
    Filed: December 16, 2014
    Date of Patent: October 13, 2015
    Assignee: Celanese International Corporation
    Inventors: David Lee, Adam Orosco, Claudio Ribeiro, R. Jay Warner, Robert Alan Deck, Emily Duff, Victor J. Johnston
  • Patent number: 9150492
    Abstract: The invention relates to nonyl alcohols with a low degree of branching and derivatives produced using them. In particular the present invention relates to mixture of primary nonyl alcohols in which at least 80% of the alkyl chains are linear and at least 15% of the alkyl chains are branched at the 2-carbon position and its derivatives. The low degree of branching produces derivatives that are more elongated and less bulky that similar derivatives produced with more highly branched alcohols.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: October 6, 2015
    Assignee: Shell Oil Company
    Inventors: Paul Theodore Sharko, Julian Richard Barnes, James Grace Crump
  • Patent number: 9150478
    Abstract: Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
    Type: Grant
    Filed: December 15, 2014
    Date of Patent: October 6, 2015
    Assignee: Celanese International Corporation
    Inventors: David Lee, Fred Ronald Olsson, Adam Orosco, Nathan Kirk Powell, Manuel Salado, Lincoln Sarager, R. Jay Warner, Radmila Wollrab, Victor J. Johnston
  • Patent number: 9150474
    Abstract: Purifying and/or recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid. Separation and purification processes of crude ethanol mixture are employed to allow recovery of ethanol and remove impurities. In addition, the process involves the esterification of acetic acid in a column used for recovering the ethanol.
    Type: Grant
    Filed: April 26, 2012
    Date of Patent: October 6, 2015
    Assignee: Celanese International Corporation
    Inventors: Zhenhua Zhou, Victor J. Johnston, David Lee, Heiko Weiner
  • Patent number: 9149736
    Abstract: Disclosed is a process for the separation of water from a liquid phase medium containing an aliphatic carboxylic acid using azeotropic distillation in the presence of an entrainer. The entrainer, water, and organics are subsequently separated, wherein the entrainer is recycled back to the azeotropic distillation column and organics recycled back to the oxidation reactor.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: October 6, 2015
    Assignee: INVISTA North America S.a.r.l.
    Inventor: Alan Macpherson Ure
  • Patent number: 9132417
    Abstract: In a process for preparing a supported hydrogenation catalyst with increased hydrogenation activity, which comprises a hydrogenating metal and/or an oxide of a hydrogenating metal on an Al2O3-containing support material, said calcined supported hydrogenation catalyst is treated before or after the final shaping thereof and before use thereof in the hydrogenation with a base solution having a pH of >10 at a temperature in the range from 20 to 120° C. for 1 to 300 hours.
    Type: Grant
    Filed: November 16, 2010
    Date of Patent: September 15, 2015
    Assignee: BASF SE
    Inventors: Rolf Tompers, Heiko Urtel, Rolf Pinkos, Gerd-Dieter Tebben, Jens Heimann, Maria Guixa Guardia, Sabine Borchers
  • Patent number: 9132407
    Abstract: Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy or sugary materials, to produce ethanol and/or butanol, e.g., by fermentation.
    Type: Grant
    Filed: May 5, 2015
    Date of Patent: September 15, 2015
    Assignee: XYLECO, INC.
    Inventor: Marshall Medoff
  • Patent number: 9126125
    Abstract: The present invention relates to the recovery of alcohols, in particular ethanol, from a crude ethanol product obtained from the hydrogenation of acetic acid using a reduced energy process. The crude ethanol product may be fed to a distillation column in which a substantial portion of the water is removed with the acetic acid in the residue. Additional water may be removed by using a pressure swing adsorption unit, molecular sieve, and/or membrane. Ethanol extraction may also be used to reduce the ethanol concentration in the recycle streams.
    Type: Grant
    Filed: April 26, 2012
    Date of Patent: September 8, 2015
    Assignee: Celanese International Corporation
    Inventors: Victor J. Johnston, Radmila Jevtic, David Lee, Adam Orosco, R. Jay Warner, Heiko Weiner, Zhenhua Zhou, Emily Duff
  • Patent number: 9126194
    Abstract: The present invention relates to a catalyst composition having a support that contains tin. The catalyst is used for converting acetic acid to ethanol. The catalyst may also comprise one or more active metals and a support modifier.
    Type: Grant
    Filed: February 29, 2012
    Date of Patent: September 8, 2015
    Assignee: Celanese International Corporation
    Inventors: Heiko Weiner, Zhenhua Zhou, Radmila Jevtic, Victor J. Johnston
  • Patent number: 9115046
    Abstract: A process for producing ethanol from synthesis gas by reacting the hydrogen and carbon monoxide of the synthesis gas to provide methanol, which then is subjected to dehydration to produce at least one ether, such as dimethyl ether. The ether, such as dimethyl ether, then is subjected to carbonylation with unreacted carbon monoxide from the synthesis gas to provide at least one acetate, such as methyl acetate. The acetate then is subjected to hydrogenolysis to produce ethanol.
    Type: Grant
    Filed: December 11, 2012
    Date of Patent: August 25, 2015
    Assignee: Enerkem, Inc.
    Inventors: David Lynch, Esteban Chornet, Charles Bureau, Stephane Marie-Rose
  • Patent number: 9109196
    Abstract: The present invention relates to the production of fermentation products such as alcohols including ethanol and butanol, and processes employing in situ product removal methods.
    Type: Grant
    Filed: September 12, 2013
    Date of Patent: August 18, 2015
    Assignee: Butamax Advanced Biofuels LLC
    Inventors: Stephane Francois Bazzana, Adam Bernfeld, Keith H. Burlew, James Timothy Cronin, Michael Charles Grady, Brian Michael Roesch, Joseph J. Zaher, Raymond Richard Zolandz
  • Patent number: 9102581
    Abstract: Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid. Separation and purification processes of crude ethanol product are employed to allow recovery of ethanol and remove impurities. In addition, the process involves separating the crude ethanol product using an extractive distillation column that employs an extraction agent, such as a recycled stream comprising water.
    Type: Grant
    Filed: October 4, 2012
    Date of Patent: August 11, 2015
    Assignee: Celanese International Corporation
    Inventors: R. Jay Warner, Radmila Wollrab, Wael Amleh, Gerald Grusendorf, Trinity Horton Hale, Victor J. Johnston, Fred Ronaold Olsson, Nathan Kirk Powell, Manuel Salado, Lincoln Sarager
  • Patent number: 9101917
    Abstract: The present invention relates to novel structured catalysts based on sintered metal fibers (SMF) coated by a basic oxide layer with Pd-nanoparticles, to reactions of organic compounds with hydrogen in the presence of said catalyst and an organic base as well as to vitamins, carotinoids, perfume ingredients, and/or food or feed ingredients prepared by using this reaction.
    Type: Grant
    Filed: July 1, 2011
    Date of Patent: August 11, 2015
    Assignee: DSM IP ASSETS B.V.
    Inventors: Werner Bonrath, Lioubov Kiwi-Minsker, Igor Iouranov
  • Patent number: 9102693
    Abstract: Silicon precursors for forming silicon-containing films in the manufacture of semiconductor devices, such as films including silicon carbonitride, silicon oxycarbonitride, and silicon nitride (Si3N4), and a method of depositing the silicon precursors on substrates using low temperature (e.g., <550° C.) chemical vapor deposition processes, for fabrication of ULSI devices and device structures.
    Type: Grant
    Filed: July 17, 2014
    Date of Patent: August 11, 2015
    Assignee: ENTEGRIS, INC.
    Inventors: Ziyun Wang, Chongying Xu, Bryan Hendrix, Jeffrey Roeder, Tianniu Chen, Thomas H. Baum
  • Patent number: 9102582
    Abstract: A method of making alcohols involves forming of alcohol esters from liquid alkane halides and a solution of metallic salts of organic acids to produce gaseous alcohol esters for reaction with magnesium or metal hydroxides to form the alcohol and the metal salt of the organic acids. In an improvement method liquid phase alcohol esters instead of gaseous alcohol esters are produced from liquid alkane halides and a solution of metal salts of organic acids whose alkane esters are less soluble in water than that of the alkane halide and treating of the alcohol ester formed with magnesium or metal hydroxides to form the alcohol and the metal salt of the organic acids.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: August 11, 2015
    Assignee: Sajet Development LLC
    Inventors: Jorge Miller, Luisa Kling Miller
  • Patent number: 9090529
    Abstract: The present invention has an object of providing a method for producing 1,2-dichloro-3,3,3-trifluoropropene by a vapor-phase reaction easily and in an industrial scale. A method for producing 1,2-dichloro-3,3,3-trifluoropropene of the present invention includes putting 1,2-dichloro-1-halogeno-3,3,3-trifluoropropane with an activated carbon catalyst in a vapor phase. According to the present invention, 1,2-dichloro-3,3,3-trifluoropropene is produced in an industrial scale at a high yield by use of 1,2-dichloro-1-halogeno-3,3,3-trifluoropropane, which is available at low cost, as a material.
    Type: Grant
    Filed: March 19, 2015
    Date of Patent: July 28, 2015
    Assignee: CENTRAL GLASS COMPANY, LIMITED
    Inventors: Yoshio Nishiguchi, Satoru Okamoto, Fuyuhiko Sakyu
  • Patent number: 9090530
    Abstract: A method for producing 1,2-dichloro-3,3,3-trifluoropropene of the present invention includes reacting 1,2-dichloro-1-halogeno-3,3,3-trifluoropropane with a base in a liquid phase; and extracting generated 1,2-dichloro-3,3,3-trifluoropropene to the outside of a reaction system to recover while the reaction is continued. According to the present invention, 1,2-dichloro-3,3,3-trifluoropropene is obtained at a high yield by a simple method. Thus, 1,2-dichloro-3,3,3-trifluoropropene is produced in an industrial scale.
    Type: Grant
    Filed: March 19, 2015
    Date of Patent: July 28, 2015
    Assignee: CENTRAL GLASS COMPANY, LIMITED
    Inventors: Yoshio Nishiguchi, Satoru Okamoto, Fuyuhiko Sakyu
  • Patent number: 9079819
    Abstract: A production method of cis-1,3,3,3-tetrafluoropropene according to the present invention includes the steps of: subjecting 1,1,1,3,3-pentafluoropropane to dehydrofluorination to form a reaction mixture (A) containing cis-1,3,3,3-tetrafluoropropene, trans-1,3,3,3-tetrafluoropropene and unreacted 1,1,1,3,3-pentafluoropropane; distilling the reaction mixture (A) to separate the trans-1,3,3,3-tetrafluoropropene from the reaction mixture (A) and collect a reaction mixture (B) containing the cis-1,3,3,3-tetrafluoropropene and the 1,1,1,3,3-pentafluoropropane; and reacting the reaction mixture (B) with a base and thereby obtaining the cis-1,3,3,3-tetrafluoropropene from the reaction mixture (B). This production method enables efficient production of high-purity cis-1,3,3,3-tetrafluoropropene and thus has industrial advantages.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: July 14, 2015
    Assignee: Central Glass Company, Limited
    Inventors: Satoshi Yoshikawa, Satoru Okamoto, Yoshio Nishiguchi, Fuyuhiko Sakyu