Patents Examined by Gennadiy Mesh
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Patent number: 12269922Abstract: A method for preparing an aramid nanofiber dispersion includes dissolving an aromatic polyamide-based polymer in a solution including a basic material and an aprotic polar solvent, while performing stirring so that a nanofiber is produced, wherein the aromatic polyamide-based polymer is a polymer in a form of a solid which is not spun into a fiber form, the stirring is performed at a temperature of 50° C. or lower and at a speed of 10-1000 rpm so that a time taken for the aromatic polyamide-based polymer to be dissolved and formed into an aramid nano-fiber dispersion is 80 hours or less, an aramid nanofiber in the aramid nanofiber dispersion has an average diameter of 1 to 100 nm and an average length of 0.1 to 100 ?m, and the basic material includes potassium hydroxide or sodium hydroxide.Type: GrantFiled: March 19, 2019Date of Patent: April 8, 2025Assignee: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Jeyoung Park, Dong Yeop Oh, Sung Yeon Hwang, Hyun Gil Cha, Jong Geon Jegal, Ho Jun Kim, Seul A Park
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Patent number: 12269923Abstract: A molding compound contains polyether block amide (PEBA) based on a subunit 1 made of at least one linear aliphatic diamine having 5 to 15 C atoms and at least one linear aliphatic or aromatic dicarboxylic acid having 6 to 16 C atoms. The PEBA also contains a subunit 2 made of at least one polyether diol having at least 3 C atoms per ether oxygen and primary OH groups at the chain ends. The sum of the C atoms of diamine and dicarboxylic acid is odd and is 19 or 21, and the number-average molar mass of the subunit 2 is 200 to 900 g/mol. A molded object can be created from the molding compound, which can be a molded part, a film, a bristle, a fiber, or a foam.Type: GrantFiled: October 9, 2019Date of Patent: April 8, 2025Assignee: Evonik Operations GmbHInventors: Franz-Erich Baumann, Kathrin Salwiczek, Alexander Richter
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Patent number: 12269919Abstract: The present invention relates to a polybutylene terephthalate resin composition comprising 20 to 50 mass % of a polybutylene terephthalate resin (A) having an intrinsic viscosity of 0.60 to 1.0 dl/g, 20 to 45 mass % of a fibrous filler (B), 1 to 20 mass % of a polycarbonate resin (C) having a melt volume rate (MVR) of 30 cm3/10 min or more, 3 to 20 mass % of a copolymerized polybutylene terephthalate resin (D), and 0 to 20 mass % of an inorganic filler (E) other than the fibrous filler (B). The polybutylene terephthalate resin composition can form a molding that remedies sink marks, maintains high heat deflection temperature, and has excellent appearance.Type: GrantFiled: March 24, 2020Date of Patent: April 8, 2025Assignee: TOYOBO MC CORPORATIONInventors: Motonobu Kamiya, Yasuto Fujii, Takahiro Shimizu, Kaori Furukawa
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Patent number: 12264218Abstract: Provided is a polycarbonate resin having excellent solubility in low-boiling-point non-halogenated solvents and having a high glass transition temperature. The polycarbonate resin includes constituent units (A) represented by general formula (1) (for example 4,4?-(4-methylpentane-2,2-diyl)diphenol) and constituent units (B) represented by general formula (2) (for example 4,4?-(1-phenylethane-1,1-diyl)diphenol), the molar ratio of the constituent units (A) to the constituent units (B), A/B, being 45/55 to 95/5, and includes a terminal structure selected from formula (T1) (for example p-t-butylphenol) and/or formula (T2) (for example 3-(2H-benzotriazol-2-yl)-4-hydroxyphenethylmethacrylate).Type: GrantFiled: June 1, 2020Date of Patent: April 1, 2025Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Toshihito Goto, Noriyoshi Ogawa
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Patent number: 12258442Abstract: The present disclosure provides a polyester including residues of formulas (i), (ii), (iii), and (iv): for example, terephthalic acid, for example, ethylene glycol, for example, cyclohexanedimethanol, and for example, tricyclodecane dimethanol, in which R1 is an aromatic group, R2 is a C2-C6 straight-chain hydrocarbon group, * represents a linking bond. Based on 100 mol % of a sum of the residues of the formula (ii), the formula (iii) and the formula (iv), a content of the residue of the formula (iii) ranges from 50 mol % to 85 mol %, and the residue of the formula (iv) ranges from 12 mol % to 40 mol %.Type: GrantFiled: March 23, 2023Date of Patent: March 25, 2025Assignee: Chang Chun Plastics Co., Ltd.Inventors: Ching-Jui Huang, Ping-Chieh Wang, June-Yen Chou
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Patent number: 12221512Abstract: The present invention relates to a polybutylene terephthalate resin composition having excellent heat resistance properties and high toughness, comprising 85 to 99.5 parts by mass of a polybutylene terephthalate resin (A) having an intrinsic viscosity (IV) of 1.0 to 1.3 dl/g, 0 to 13 parts by mass of a polyester elastomer (B), and 0.05 to 2 parts by mass of a talc (C) having an average particle size of 5 ?m or less, based on 100 parts by mass in total of components (A), (B) and (C), wherein in the case where the polyester elastomer (B) is contained, the mass ratio of hard segment/soft segment constituting the polyester elastomer (B) is 85/15 to 50/50.Type: GrantFiled: February 21, 2020Date of Patent: February 11, 2025Assignee: TOYOBO MC CORPORATIONInventors: Takuya Shimoharai, Wenli Peng
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Patent number: 12215186Abstract: A process for making a polycondensation pre-polyester, a polyester or both, comprising the following steps: following steps: A. Acylation of at least one diacid chloride with at least one alcohol to form at least one diester; B. Partial hydrolysis of the diester product of Step A to form at least one monoacid; C. Esterifying the monoacid of Step B with at least one diol to form a diester; D. Reacting the diester of Step C under acidic conditions to form a diacid; and subsequently, performing either Step E or Step F as follows: E. Bisalkylation of the diacid of Step D with at least one haloalcohol to form a pentamer, or F. Esterifiying the diacid of Step D under esterification conditions with at least one diol to form a pentamer, provided that the diol is not the same as the diol used in Step C.Type: GrantFiled: June 26, 2020Date of Patent: February 4, 2025Assignee: Eastman Chemical CompanyInventors: Robert Jacks Sharpe, Emmett Dudley Crawford
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Patent number: 12195583Abstract: A biodegradable resin composition is obtained by subjecting an aliphatic dicarboxylic acid or an acid component comprising a mixture of an aliphatic dicarboxylic acid and an aromatic dicarboxylic acid, and an aliphatic diol sequentially to esterification, transesterification, polycondensation, chain extension and solid-state polymerization reactions in the presence of a polyfunctional compound represented by the following Formula 1: wherein n is an integer ranging from 1 to 11, and m is an integer ranging from 2 to 30.Type: GrantFiled: November 23, 2020Date of Patent: January 14, 2025Assignee: ANKOR BIOPLASTICS CO., LTD.Inventors: Heon Young Lim, Yoon Cho, Myung Je You
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Patent number: 12187844Abstract: In various embodiments, the present invention provides well-defined biodegradable poly(lactone-b-propylene fumarate) diblock and triblock polymers formed using a novel one-pot, scalable ring-opening block-order copolymerization (ROBOCOP) technique that utilizes magnesium 2,6-di-tert-butyl-4-methylphenoxide (Mg(BHT)2(THF)2) to “switch” from the ROP of cyclic esters to the ROCOP of maleic anhydride (MAn) and propylene oxide (PO) to produce PPF based block copolymers for application in additive manufacturing and patient specific regenerative medicine. These block copolymers are fully resorbable and can be photochemically crosslinked in a number of applications, including 3D printing. By adding the lactone block to the PPF polymer, the viscosity of the resulting block copolymer at working temperatures can be precisely controlled and the quantity of the reactive diluent in printable resins can be reduced or eliminated.Type: GrantFiled: March 20, 2018Date of Patent: January 7, 2025Assignee: The University of AkronInventors: Matthew Becker, James Wilson, Shannon Petersen
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Patent number: 12180332Abstract: A plasticizer and a method for producing the same are provided. The method for producing the plasticizer includes: reacting a reaction mixture at each of a plurality of temperature holding stages in a heating process to form a semi-finished product; and purifying the semi-finished product at each of a plurality of low pressure stages of a decompression process to obtain a plasticizer. A temperature range of the heating process is from 140° C. to 220° C., a pressure range of the decompression process is from 750 Torr to 20 Torr, and the reaction mixture contains dibasic acid (e.g., adipic acid), diol (e.g. 1,4-butanediol), monohydric alcohol (e.g., 2-ethylhexanol), and catalyst (e.g., titanium catalyst).Type: GrantFiled: July 16, 2021Date of Patent: December 31, 2024Assignee: NAN YA PLASTICS CORPORATIONInventors: Te-Chao Liao, Jung-Jen Chuang, Zhang-Jian Huang, Che-Jung Hsu
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Patent number: 12173116Abstract: A method of producing a degradable material comprising steps of hydrogenating 2-ethylidene-6-hepten-5-olide (EVL) by introducing hydrogen to the EVL in order to obtain modified EVL; combining the modified EVL with a catalyst to form a reaction mixture; and subjecting the reaction mixture to reaction conditions that will allow the modified EVL to react by ring-opening polymerization in the presence of the catalyst to form a product composition including polymeric-EVL, wherein the polymeric-EVL is hydrolytically degradable, wherein the reaction conditions include a reaction temperature of from ?40° C. to 70° C.Type: GrantFiled: September 8, 2021Date of Patent: December 24, 2024Assignee: THE UNIVERSITY OF AKRONInventors: James M. Eagan, Luis D. Garcia Espinosa
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Patent number: 12168715Abstract: The present invention describes a process of manufacturing biodegradable PET chips, comprising the steps of providing a purified terephthalic acid (PTA) in a predetermined quantity in a slurry tank; providing virgin monoethylene glycol (MEG) in a predetermined quantity in the slurry tank; transferring the combination of the slurry tank to an esterification reactor for esterification of the combination in the reactor at above 250° C. temperature which releases monomers; transferring the monomers from the esterification reactor to a polymerisation reactor; providing poly-catalysts such as, but not limited, to Ti-based catalyst, sb2O3 or any other suitable catalysts or combination thereof into the polymerisation reactor; and polymerization of the monomers in the polymerisation reactor at above 280° C. temperature, wherein an enzyme based composition is provided either at PTA/MEG stage or poly-catalyst stage or at other stages or combination thereof.Type: GrantFiled: March 13, 2020Date of Patent: December 17, 2024Inventor: Ashok Chaturvedi
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Patent number: 12157823Abstract: An asphalt composition comprising 0.1 to 10.0 wt.-% monomeric methylene diphenyl diisocyanate (MDI) based on the total weight of the composition, wherein the monomeric MDI is carbodiimide modified and wherein the weight percentage of 4,4?-MDI in the carbodiimide modified monomeric MDI is in the range of from 65 to 85% and the weight percentage of carbodiimide is in the range of from 15 to 35% in the carbodiimide modified monomeric MDI; wherein at least 18% by weight based on the total weight of the composition are particles with a sedimentation coefficient above 5000 Sved in a white spirit solvent.Type: GrantFiled: December 9, 2019Date of Patent: December 3, 2024Assignee: BASF SEInventors: Olivier Fleischel, Michael Praw, Waldemar Schatz, Bernie Lewis Malonson, Iran Otero Martinez, Dag Wiebelhaus
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Patent number: 12134680Abstract: A crystallization method that comprises a step of providing a polyester comprising at least one 1,4:3,6-dianhydrohexitol unit, and a step of crystallizing this semi-crystalline polyester at a pressure of at least 600 mbar absolute. The method according to the invention makes it possible to strongly limit, or even eliminate, the phenomenon of polyester expansion during crystallization. Advantageously, the elimination of the expansion phenomenon through pressure conditions implemented according to the invention thus makes it possible to dispense with obtaining very fragile empty spheres that break when agitated and thus cause the formation of undesirable fine particles.Type: GrantFiled: May 29, 2019Date of Patent: November 5, 2024Assignee: Roquette FreresInventors: Nicolas Jacquel, René Saint-Loup, Audrey Dausque, Sébastien Naudin, Nicolas Descamps
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Patent number: 12122871Abstract: The present application is directed to a method for preparing a cyclic carbonate functional polyester, said method comprising the stages of (A) reacting glycerine carbonate with an anhydride to form an Adduct (A), (B) reacting said Adduct (A) with at least one polyepoxide compound to form an Adduct (B), and (C) reacting said Adduct (B) with at least one polycarboxylic acid to form said cyclic carbonate functional polyester.Type: GrantFiled: June 14, 2021Date of Patent: October 22, 2024Assignee: Henkel AG & Co. KGaAInventors: Jose Garcia Miralles, Sonia Flores Penalba, Marta Rodriguez Ble, Vito Maltese, Miguel Paradas-Palomo, Rosa Maria Sebastian Perez, Jorge Marquet Cortes
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Patent number: 12116452Abstract: A blend composition comprising a first polyester and a second polyester. The first and second polyesters each comprises residues of terephthalic acid, neopentyl glycol (NPG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and/or diethylene glycol (DEG). The first polyester comprises NPG, CHDM, and DEG in a combined amount that is less than the second polyester. The blend composition can be useful for producing a shrink film exhibiting high ultimate shrinkage (e.g., >65% at 95° C. for 10 seconds) and a high strain induced crystalline melting point (e.g., greater than 190° C.).Type: GrantFiled: October 8, 2019Date of Patent: October 15, 2024Assignee: Eastman Chemical CompanyInventors: Mark Allen Peters, Jacob E. Napierala, Rondell Paul Little, Jr., James Carl Williams, James Wesley Peer
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Patent number: 12104012Abstract: A polymer is made by polymerization of CBDA-4 monomers with a glycerol linker through a condensation reaction. The resulting polymer is thermally cleavable having a plurality of CBDA-4 monomers linked with the glycerol linkers, making it recyclable when heated and degraded. The resulting intermediate material can be hydrolyzed back to initial starting material for synthesizing CBDA-4 monomers.Type: GrantFiled: November 25, 2019Date of Patent: October 1, 2024Assignee: UNIVERSITY OF NORTH DAKOTAInventors: Qianli Chu, Zhihan Wang
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Patent number: 12104011Abstract: Provided is a biopolymer composition, a preparation method for the same, and a bioplastic using the same, the biopolymer composition comprising at least 83.5 weight % of a copolymer resin of lactic acid (LA) and 3-hydroxypropionate (3HP), an antioxidant, and a lubricant, and the composition having an elongation percentage of at least 90% but not greater than 500%.Type: GrantFiled: September 16, 2020Date of Patent: October 1, 2024Assignee: LG Chem, Ltd.Inventors: Banseok Choi, Jung Yun Choi, Chul Woong Kim, Sungwoon Heo, Eungwon Kim, Donggyun Kang
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Patent number: 12104010Abstract: A polymer composition for use in an electric circuit protection device is provided. The polymer composition comprises a polymer matrix that includes a thermotropic liquid crystalline polymer. The polymer composition exhibits an in-plane thermal conductivity of about 3.5 W/m-K or more as determined in accordance with ASTM E1461-13 and a melt viscosity of from about 1 to about 100 Pa-s as determined in accordance with ISO Test No. 11443:2014 at a temperature 15° C. higher than the melting temperature.Type: GrantFiled: January 14, 2022Date of Patent: October 1, 2024Assignee: Ticona LLCInventor: Young Shin Kim
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Patent number: 12098242Abstract: Disclosed is an eco-friendly biodegradable polyester resin composition, including: a polyester resin including a diol, an aromatic dicarboxylic acid and an aliphatic dicarboxylic acid, wherein an alternating ratio of the polyester resin is 0.3 to 0.7, wherein the alternating ratio is a ratio of a diol, bonded between the aromatic dicarboxylic acid and the aliphatic dicarboxylic acid, among the diol. The diol may include 1,4-butanediol; the aromatic dicarboxylic acid may include terephthalic acid or dimethyl terephthalate; and the aliphatic dicarboxylic acid may include adipic acid. When the biodegradable polyester resin composition is dried at 80° C., placed in a stainless steel mold, and compressed at 210° C. under a pressure of 10 MPa for 3 minutes to produce a polyester sheet having a thickness of 300 ?m, the sheet has a tensile strange range from 40 MPa to 60 MPa, an elongation at break range from 800% to 1100%, and Young's modulus range from 20 MPa to 80 MPa.Type: GrantFiled: May 19, 2023Date of Patent: September 24, 2024Assignee: ECOVANCE CO. LTD.Inventors: Seong Dong Kim, Kyung Youn Kim, Hoon Kim, Jun Su Byeon, Eun Sun Joeng