Abstract: An alkylation process wherein isoparaffin hydrocarbons are alkylated with olefin hydrocarbons in the presence of an alkylation catalyst comprising H.sub.2 SO.sub.4 to yield alkylated hydrocarbons suitable for use in motor fuels. Such process includes an isoparaffin pretreatment step wherein isoparaffin charge is contacted with spent alkylation catalyst to remove contaminants from the isoparaffin which are reactive with sulfuric acid under alkylation conditions.

Abstract: Mineral oils containing minor or residual amounts of sulfur-containing impurities are upgraded by contact thereof with a cobalt oxide-supported sorbent under sulfur-sorbing conditions. The sorbent is regenerated by a set of sequential treatment steps.

Abstract: Residual oils which are thermally cracked with entrained hot solids in a low residence time riser must be hydrodesulfurized so that sulfur oxide emissions in the flue gas of the solids regenerator are maintained within environmentally acceptable limits. Of a full range residual oil thermal cracking feedstock, the lower boiling distillate feed components are capable of providing a higher ethylene yield with a lower dispersant steam requirement as compared to the high boiling residual feed components. In accordance with the present invention, the high boiling residual components of a thermal cracker feed residual oil are selectively removed during hydrodesulfurization to provide a non-aliquot distillate-residual oil hydrodesulfurization product in which the ratio of lower boiling distillate oil to high boiling residual oil is enhanced.

Abstract: In a conventional reactor into which at one end portion there are fed olefin, isoparaffin and HF acid, or other catalysts, and from which an alkylate containing product is passed to a phase separator or settling zone, there is added to the reactor to a downstream portion therein, beyond the original point of entry of the first olefin feed a second portion of olefin feed together with hydrocarbon phase recycled from the phase separator or settling zone.

Abstract: Isomerizable hydrocarbons including paraffins, cycloparaffins, olefins and alkyl aromatics are isomerized by contacting the hydrocarbon at isomerization conditions with a catalytic composite comprising a platinum group metal on an alpha-alumina monohydrate support wherein said support is prepared by admixing an alpha-alumina monohydrate with an aqueous ammoniacal solution having a pH of at least about 7.5 to form a stable suspension and commingling said suspension with a salt of a strong acid to form an extrudable paste or dough. Upon extrusion, the extrudate is dried and calcined to form said alumina support.

Abstract: When residual oil is cracked to gasoline in the presence of a fluidized zeolite catalyst the oil is first catalytically hydrodesulfurized so that sulfur oxide emissions from the catalyst regenerator are held to environmentally acceptable levels. The hydrodesulfurized residual oil is flash vaporized at the elevated temperature at the inlet of the cracking riser and most of the residual oil feedstock passes into the vapor state and is cracked to valuable products. However, a portion of the 1050.degree. F.+ (566.degree. C.+) residual material cannot be flash vaporized at the riser temperature and instead deposits upon the catalyst and is coked. Data are presented which show that as the proportion of the 1050.degree. F.+ (566.degree. C.+) components in a cracking feedstock decreases, the amount of these high boiling components in each barrel of cracker feedstock which are flash vaporized can actually increase. A multistage hydrodesulfurization operation is provided in which the proportion of 1050.degree. F.

Abstract: An improved coal deashing process wherein a feed mixture comprising soluble coal products, insoluble coal products, and deashing solvent at a first temperature level is separated in a first separation zone into a first light fraction and a first heavy fraction comprising the insoluble coal products and some of the deashing solvent through admixing predetermined quantities of an additive with the feed mixture prior to separation to provide an improved yield of recoverable soluble coal products. Alternatively, the additive is admixed with the first light fraction prior to subsequent separations to provide an improved yield of recoverable soluble coal products.

Abstract: A process for improving the yield of soluble coal products separated from a residuum feed in a coal deashing process. In operation, an additive comprising (i) at least a portion of a distillate fraction preferably recovered from the coal liquefaction products from which the residuum feed is derived, (ii) a portion of recycled heavy soluble coal products, (iii) a portion of recycled light soluble coal products, or (iv) admixtures thereof is introduced in predetermined quantities into the residuum feed prior to entry into a separation zone maintained at elevated temperature and pressure to effect an improved separation of the soluble coal products from the insoluble coal products within the residuum feed.

Abstract: The bottom effluent from an isostripper of an HF alkylation system is combined with the bottom effluent consisting essentially of isopentanes and heavier hydrocarbons from a debutanizer column such as to produce an alkylate product stream under the provision that the mixing of the two streams is achieved in response to a signal representing the vapor pressure of the mixed streams.

Abstract: In the catalytic hydrotreating of pyrolysis gasoline, the major portion of dienes present in the hydrotreated product concentrate in the C.sub.5 fraction. The C.sub.5 fraction is separated from a first portion of the hydrotreated effluent and a portion of said separated C.sub.5 fraction is combined with a second portion of the hydrotreated effluent as a combined recycle stream to the hydrotreating reaction. By combining a portion of the separated C.sub.5 fraction with the recycle hydrotreated effluent, the net C.sub.5 product recovered from the process has a diene value which is lower than that which would be obtained without the C.sub.5 recycle.

Abstract: In the catalytic hydrodesulfurization of residual oil the amount of hydrogen consumed per atom of sulfur removed is relatively low until the desulfurization becomes deep, whereupon the amount of hydrogen consumed per atom of sulfur removed becomes relatively high. The present invention provides a multistage process capable of producing products of low sulfur content while avoiding deep desulfurization of the heavy portion of the residual oil so that hydrogen consumption is diminished. The feed oil is fractionated to provide a residual fraction, a heavy distillate fraction and a light distillate fraction. The residual fraction and hydrogen are charged to an upstream hydrodesulfurization stage. A portion of the upstream stage residual oil effluent stream is split out of the process for use as refinery fuel and the remaining portion of the upstream stage effluent stream is charged to an intermediate hydrodesulfurization stage together with the heavy distillate feed fraction and hydrogen.

Abstract: The hydrogen consumption in the catalytic desulfurization of hydrocarbon oils is reduced by the incorporation in the catalyst of a small amount of arsenic.

Abstract: A process for the steam hydroconversion of light hydrocarbon feed stocks relatively deficient in hydrogen and high in sulfur, which process comprises passing the feed and steam into a steam hydroconversion zone over a dual-function catalyst comprising molybdenum on a high surface area alumina base or on an iron oxide-chromium oxide base, said catalyst having been reduced and sulfided prior to use. A portion of the hydrocarbon is steam reformed to produce hydrogen in the reaction zone which is then used in situ to hydrogenate the olefins and aromatics in the feed and also removes sulfur therefrom, all processes occurring in the same reaction zone.

Abstract: Hydrogen sulfide is removed from a three-phase mixture of crude oil, natural gas, and water as it issues as a stream from an oil well by first adding liquid sulfur dioxide to the stream without substantially changing its temperature or pressure and then turbulencing the stream to react most of the hydrogen sulfide therein with the sulfur dioxide. Water containing an additive capable of forming a salt with the remaining trace hydrogen sulfide is then added to the stream and then the desulfurized natural gas is separated out of the stream. Hot and sulfur-free crude oil is then injected into the stream to melt the sulfur therein and the stream is then gravitationally separated into sulfur, water, and pure sulfur-free crude oil, some of the last of which is heated and reintroduced into the stream upstream to heat same and melt the sulfur therein.

Abstract: This invention provides a method for reducing the level of thiophenic sulfur compounds in a heavy carbonaceous oil feed which involves contacting the oil feed with a C.sub.1 -C.sub.4 alkanol in the presence of a non-acidic zeolite catalyst.The reaction equilibrium in the process favors the displacement of thiophene sulfur atoms by oxygen atoms.

Abstract: In the hydrodesulfurization of residual oil the amount of hydrogen consumed per atom of sulfur removed is relatively low until the desulfurization becomes deep, whereupon the amount of hydrogen consumed per atom of sulfur removed becomes relatively high. The present invention provides a multistage catalytic hydrodesulfurization process capable of producing products of low sulfur level while avoiding deep desulfurization of the heavy portion of the residual oil so that hydrogen consumption is diminished. The feed oil and hydrogen are passed through an upstream hydrodesulfurization stage and the upstream stage effluent is flashed to separate a distillate oil fraction from a concentrated residual oil fraction. A portion of the concentrated residual oil fraction is diverted from the process for use as refinery fuel and the remaining portion of the flash residue and hydrogen are charged to an upstream stage together with the flash distillate.

Abstract: In the hydrodesulfurization of residual oil the amount of hydrogen consumed per atom of sulfur removed is relatively low until the desulfurization becomes deep, whereupon the amount of hydrogen consumed per atom of sulfur removed becomes relatively high. The present invention provides a multistage hydrodesulfurization process capable of producing products of low sulfur level while avoiding deep desulfurization of the heavy portion of the residual oil so that hydrogen consumption is diminished. The feed oil is fractionated to provide distillate and residual fractions. The residual fraction and hydrogen are charged to an upstream catalytic hydrodesulfurization stage. A portion of the upstream stage effluent stream is diverted from the process for use as refinery fuel and the remaining portion of the upstream stage effluent stream is charged to a downstream catalytic stage together with the feed distillate oil and hydrogen.

Abstract: Process for the extraction of diene or aromatic hydrocarbons from petroleum hydrocarbon fractions employing sulfonamides as solvents. Also described are new sulfonamides useful as solvents for the extraction process.

Abstract: An improved hydrocarbon hydrocracking process is disclosed wherein residual nitrogen-containing and/or polycyclic hydrocarbon impurities are extracted from bottoms of the resulting hydrocrackate by contacting the bottoms under liquid-liquid extracting conditions with a furfural solution of ferric chloride.

Abstract: There is disclosed a hydrotreating process for petroleum distillate which comprises contacting the distillate with catalyst particles of special shape characteristics in the presence of hydrogen at elevated temperature and pressure.