Abstract: Compounds of the formula I ##STR1## in which R.sup.1 to R.sup.8 independently of one another are H and at least one of R.sup.1 and R.sup.8 is a substituent belonging to the group --F, --Si(C.sub.1 -C.sub.4 alkyl).sub.3 or --COOR.sup.10 ; or each pair of adjacent radicals of R.sup.1 to R.sup.8 is --CO--O--CO--; or at least one of R.sup.1 to R.sup.8 is C.sub.1 -C.sub.20 alkyl-(X).sub.p --, C.sub.2 -C.sub.20 alkenyl-(X).sub.p --, C.sub.2 -C.sub.20 -alkynyl-(X).sub.p --, C.sub.3 -C.sub.8 cycloalkyl-(X).sub.p --, (C.sub.1 -C.sub.12 alkyl-C.sub.3 -C.sub.8 cycloalkyl-(X).sub.p --, C.sub.3 -C.sub.8 -cycloalkyl-CH.sub.2 --(X).sub.p --, C.sub.1 -C.sub.12 alkyl-C.sub.3 -C.sub.8 cycloalkyl-CH.sub.2 --(X).sub.p --, C.sub.6 -C.sub.10 aryl-X--, C.sub.7 -C.sub.20 alkaryl-X--, C.sub.7 -C.sub.12 aralkyl-(X).sub.p -- or C.sub.8 -C.sub.20 -alkaralkyl-(X).sub.p -- or --Y-- (C.sub.m H.sub.2m --O)--.sub.n R.sup.10 each of which is unsubstituted or substituted by --F, --OH, --CN, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.
Type:
Grant
Filed:
January 11, 1993
Date of Patent:
August 16, 1994
Assignee:
Ciba-Geigy Corporation
Inventors:
Marcus Baumann, Carl W. Mayer, Wolfgang Wernet, Walter Fischer
Abstract: Fungicidal compositions for the protection of turfgrass against crown and root rot are disclosed. The compositions comprise, as the active material, a mixture of (a) a monoester salt of a phosphorous acid (preferably aluminum ethyl phosphite), and (b) an ethylene bisdithiocarbamate contact fungicide (preferably manganese-zinc ethylene bisdithiocarbamate). Preferred compositions comprise one part by weight of the monosester salt to two parts by weight of the ethylene bisdithiocarbamate.
Abstract: 3,5-Diaminobenzotrifluoride is prepared by reaction of 4-chloro-3,5-dinitrobenzotrifluoride with sodium formate in acetic acid, in the presence of sodium acetate and palladium on charcoal.
Type:
Grant
Filed:
December 10, 1990
Date of Patent:
August 9, 1994
Assignee:
Occidental Chemical Corporation
Inventors:
Ramesh Krishnamurti, Mahendra K. Dosi, Henry C. Lin
Abstract: A process for reducing the amount of the ethoxylated amine byproducts MEAGE, DEAGE and TEAGE formed in a process for making ethanolamines from the reaction of ethylene oxide and ammonia, comprising feeding carbon dioxide or a material which will evolve carbon dioxide to a reactor for conducting such process.
Abstract: Amine derivatives having the general formula (I): ##STR1## wherein X is selected from the group consisting of ##STR2## wherein Q is oxygen, sulfur or nitrogen atom, and ##STR3## wherein Q is as above; Y is selected from the group consisting of ##STR4## R.sup.1 is hydrogen atom or an alkyl group; R.sup.2 is hydrogen atom or an alkyl group; R.sup.3 is hydrogen atom, a halogen atom or an alkyl group; R.sup.4 hydrogen atom, an alkyl group, a cycloalkyl group, a halogenated alkyl group or a halogen atom; R.sup.5 is hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, nitro group or hydroxy group; R.sup.5 is attached to an arbitrary position of X, and R.sup.3 or R.sup.4 is attached to an arbitrary position of Y.The amine derivatives (I) are useful as fungicides.
Abstract: There is provided a method of treatment of neurological disorders, such as epilepsy, stroke and cerebral ischaemia, which comprises the administration of a compound of Formula I: ##STR1## wherein, Ar.sub.1 and Ar.sub.2, which may be the same or different, independently represent phenyl or phenyl substituted by one or more of amino, nitro, halogen, hydroxy, C1 to 6 alkoxy, C1 to 6 alkyl or cyano;R.sub.1 represents hydrogen, C1 to 6 alkyl, C1 to 6 alkoxycarbonyl;R.sub.2 represents hydrogen or COCH.sub.2 NH.sub.2 ;R.sub.3 represents hydrogen or C1 to 6 alkyl;in addition, when R.sub.2 represents hydrogen either one or both of Ar.sub.1 and Ar.sub.2 may also represent 2-, 3- or 4-pyridinyl and R.sub.1 may also represent trihalomethyl;or a pharmaceutically acceptable salt thereof.Some of the compounds of formula I are novel, and these are also provided, together with pharmaceutical compositions containing the novel compounds.
Abstract: Color-containing alkanolamines or alkyleneamines, having color numbers of up to 100 PtCo or higher, can be treated with inorganic solid acidic catalysts. Inorganic support materials having bonded inorganic acid functionalities may be used as the inorganic solid acidic catalysts. In the presence of water, these inorganic solid acidic catalysts produce decolorized alkanolamines or alkyleneamines having color numbers of 20 PtCo or less. The process of decolorization can be carried out in batch or continuous mode processes thus providing low cost, high quality and high purity end products.
Type:
Grant
Filed:
June 28, 1993
Date of Patent:
July 19, 1994
Assignee:
Union Carbide Chemicals & Plastics Technology Corporation
Abstract: A process for preparing amines or imines which comprises contacting an alcohol, aldehyde, or ketone with an aminating agent in the presence of a catalyst under reaction conditions sufficient to form an amine or imine, wherein the catalyst comprises a homogeneous mixture of (a) 10-90 mole percent cobalt or an insoluble salt thereof, (b) 9-89 mole percent copper or an insoluble salt thereof, and (c) 1-20 mole percent of a metal or insoluble salt of a metal selected from the group consisting of a Lanthanum series metal, thorium, uranium, scandium, titanium, and yttrium is described. A process which employs zirconium as component (c) and which is supported on a carrier material, wherein the carrier material has been neutralized with a base, is also disclosed.
Abstract: Optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine can be obtained by catalytic hydrogenation of optionally substituted aniline, a catalyst being employed which contains ruthenium, palladium or a mixture of both metals, which are applied to a support of niobic acid or tantalic acid or a mixture of both. The catalyst contains the noble metal(s) in a total amount from 0.05 to 5% by weight, relative to the total weight of the catalyst. In the case of the use of both noble metals, their weight ratio to one another is 1:9-9:1.
Type:
Grant
Filed:
August 27, 1993
Date of Patent:
June 21, 1994
Assignee:
Bayer Aktiengesellschaft
Inventors:
Otto Immel, Gerhard Darsow, Helmut Waldmann, Gerd-Michael Petruck
Abstract: The invention provides a specific measure of iron stores in vivo using magnetic resonance imaging. T.sub.2 relaxation times in both lower-to-mid field strength magnetic resonance imaging instruments and a higher field strength instrument is evaluated. T.sub.2 obtained at the higher field strength instrument is subtracted from T.sub.2 obtained at the lower field strength instrument. This difference, T, is then correlated with a quantitative measure of the iron stores in vivo in the scanned tissue. A two-dimensional or multidimensional map of the scanned tissue is then constructed on the basis of T to visually identify different tissue types as being normal or abnormal, either through a visual determination based on gray scales or a numeric comparison based on quantitative measure. The introduction of artificial or nonbiological substances as opposed to natural ferritin, is permitted for further diagnostic use by application of this methodology.
Type:
Grant
Filed:
August 6, 1992
Date of Patent:
June 21, 1994
Assignee:
The Regents of the University of California
Abstract: Plant defoliating compositions comprising .delta.-aminolevulinic acid and one or more chlorophyll biosynthesis modulators; and methods of making and using same.
Type:
Grant
Filed:
July 17, 1992
Date of Patent:
June 14, 1994
Assignee:
The Board of Trustees of The University of Illinois
Abstract: Fungicidal compounds having the formula (I): ##STR1## in which any two of K, L and M are nitrogen and the other is CH; and X is an optionally substituted 3- to 6-membered heterocyclic ring containing at least one trivalent nitrogen atom by which it is attached to the central pyrimidine ring.
Type:
Grant
Filed:
October 6, 1992
Date of Patent:
May 24, 1994
Assignee:
Imperial Chemical Industries PLC
Inventors:
John M. Clough, Christopher R. A. Godfrey, Ian T. Streeting, David P. Bacon
Abstract: A continuous process for making N,N-dimethylacrylamide (NNDMA) is disclosed which uses a commodity chemical, namely vinyl chloride (VCl), which is amidated with dimethylamine (DMA) and carbon monoxide in the presence of a supported palladium(O) triorganophosphine catalyst used under conditions where the ratio of P/Pd is critical. The continous process unexpectedly provides the catalyst with long life because the reaction can be carried out in a moving bed of catalyst in the presence of enough acetonitrile solvent to prevent deposition of DMA.HCl, formed during the reaction, in the pores of the catalyst support.
Abstract: A method of controlling odors from a hydrocarbon-containing sludge including the steps of mixing a quaternary ammonium compound with water, adding a surface-active agent to the mixture of the quaternary ammonium compound and water, and dispersing the mixture into the hydrocarbon-containing sludge. A masking agent may be introduced to the mixture of the water, the quaternary ammonium compound, and the surface-active agent. A pH control agent is added to this mixture, along with a quantity of a polyglycol ether. The quaternary ammonium compound is benzalkonium chloride. The surface-active agent is butyl cellosolve. The masking agent is limonene. The step of dispersing the mixture includes spraying the mixture onto the hydrocarbon-containing sludge.
Type:
Grant
Filed:
February 8, 1993
Date of Patent:
May 3, 1994
Inventors:
Ronald W. Bowman, Robert R. Caycraft, L. C. Gramms, E. P. Caballero
Abstract: Aromatic amines which are substituted by C.sub.1 -C.sub.4 -alkoxy in the p-position are prepared by catalytic hydrogenation of the underlying aromatic nitro compounds in a reaction medium comprising sulphuric acid and a C.sub.1 -C.sub.4 -alcohol by a Bamberger type rearrangement at elevated temperature, advantageously by carrying out the catalytic hydrogenation under elevated pressure.
Type:
Grant
Filed:
July 10, 1991
Date of Patent:
April 19, 1994
Assignee:
Bayer Aktiengesellschaft
Inventors:
Heinz Landscheidt, Alexander Klausener, Heinz U. Blank
Abstract: Disclosed is a method for preparation of alkylamines which comprises reacting ammonia and a monounsaturated olefin in the presence of a catalyst selected from the group consisting of:a. Acid modified montmorillonite clays;b. Heterogeneous catalysts comprising a fluorine-containing compound on an inert support; andc. Heteropoly acids on an inert support.
Abstract: Compounds of the formula: ##STR1## wherein X is hydrogen, halo, trihalomethyl, alkyl, nitro, or cyano; X.sup.1 is hydrogen, halo, or trihalomethyl; X.sup.2 is trihalomethyl or halo; Y is O, S, NH or NR.sup.1 ; R.sup.1 and R.sup.2 are the same or different radicals selected from hydrogen, alkyl, or mononuclear aralkyl; n is 1 to 5, and Z is carboxy, amino, mono- and dialkyl amino and when Z is carboxy; the agronomically acceptable salts, esters, thioesters and amides thereof, and compositions containing these compounds exhibit herbicidal activity.
Abstract: A purification process of crude methacrylamide by recrystallization from an aqueous methacrylamide solution, comprising the steps of conducting crystallization by adjusting the hydrogen ion concentration of the aqueous methacrylamide solution to pH 8 or more, separating a methacrylamide crystal, adjusting 5% by weight or more of resulting mother liquor to pH 5 or less, separating precipitated insoluble matter, and reusing thus-treated mother liquor, is provided.The high quality methacrylamide crystal thus obtained is excellent in Hazen number, purity and transparency of a methanol solution and suitable for uses such as windshield glasses.