Abstract: A process for producing a waxy product comprises hydrotreating a feedstock comprising a Fischer-Tropsch wax and a petroleum-based waxy distillate, to produce a range of hydrogenated products, and recovering a waxy product from the range of hydrogenated products.
Type:
Grant
Filed:
December 1, 1998
Date of Patent:
November 13, 2001
Assignee:
Schumann Sasol (South Africa) (Proprietary) Limited
Inventors:
Ferdinand Richter, Adrie Van Zyl Visser, Godlieb Gerhardus Swiegers
Abstract: The present invention concerns the use of a catalyst comprising an extruded essentially alumina-based support, constituted by a plurality of juxtaposed agglomerates and partially in the form of packs of flakes and partially in the form of needles, and optionally comprising at least one catalytic metal or a compound of a catalytic metal from group VIB and/or at least one catalytic metal or compound of a catalytic metal from group VIII, further comprising at least one dopant selected from the group formed by boron, phosphorous, silicon (or a silica different from that which can be found in the support) and halogens, in an ebullating bed process and for hydrorefining and hydroconverting hydrocarbon feeds.
Abstract: The improved process and apparatus of the present invention for extracting high purity aromatics from gasoline using a glycol solvent based extraction process decrease liquid-vapor flashing, reduce reflux flow rate, and use heat of enthalpy produces at one point as a source of energy used at another point, decreasing energy consumption while significantly increasing purity and amount of product obtained.
Abstract: A hydrodenitrogenation catalyst is prepared by decomposing a nickel (ammonium) molybdotungstate precursor and sulfiding, either pre-use or in situ, the decomposition product.
Type:
Grant
Filed:
March 3, 2000
Date of Patent:
October 9, 2001
Assignee:
Exxon Research and Engineering Company
Inventors:
Stuart L Soled, Sabato Miseo, Roman Krycak, Hilda Vroman, Teh C. Ho, Kenneth L. Riley
Abstract: A process for upgrading a hydrocarbon oil is provided which comprises introducing the oil and an aromatic extraction solvent containing 0.1 to 10 vol % water into an extraction zone for contact of the oil and solvent therein whereby an extract solution is formed; and injecting water into the extraction zone at a point below that at which the extraction solvent is introduced. The injected water is injected substantially countercurrent to the extraction solvent at a velocity of about 0.5 to 3 ft/sec in an amount ranging from about 0.1 to about 10 LV% based on the amount of extract solution being processed.
Type:
Grant
Filed:
December 10, 1999
Date of Patent:
September 25, 2001
Assignee:
Exxon Research and Engineering Company
Inventors:
Keith K. Aldous, Joseph P. Boyle, Michael B. Davis
Abstract: A feed stream is first processed in a hydrotreating reaction zone and then the effluent is separated into three fractions in an augmented first high pressure separator. Controlled portions of the middle and heavy boiling point range hydrocarbon fractions from this separator are recycled through a low conversion hydrocracking zone, while the remaining portions of these two fractions are passed into a second high pressure separator for recovery. The recycled hydrocarbons flow into a hydrocracking zone and the effluent of this zone flows into the hydrotreating reaction zone.
Type:
Grant
Filed:
October 21, 1999
Date of Patent:
September 25, 2001
Assignee:
UOP LLC
Inventors:
Vasant P. Thakkar, Christopher J. Anderle
Abstract: A feed stream is first processed in a hydrotreating reaction zone and then the effluent is separated into three fractions in an augmented first high pressure separator. Controlled portions of the middle and heavy hydrocarbon fractions are passed into a high severity hydrocracking zone, while the remaining portions of these two fractions are passed into a second high pressure separator for recovery. The effluent of the hydrocracking zone is also fed to the second high pressure separator.
Type:
Grant
Filed:
October 21, 1999
Date of Patent:
September 25, 2001
Assignee:
UOP LLC
Inventors:
Vasant P. Thakkar, Christopher J. Anderle, Hemant B. Gala
Abstract: A hydrotreating process using a catalyst prepared by a process wherein the volatile content of a metal-impregnated support is reduced in the presence of a sulfur containing compound without reaching calcining temperatures.
Abstract: Lubricant oils of low pour point and improved oxidation stability are produced by catalytically dewaxing a lube feedstock over a zeolite dewaxing catalyst such as ZSM-5 in the hydrogen or decationized form. The use of these catalysts enables products of excellent oxidative stability to be obtained and reduces the catalyst aging rate in the first and subsequent dewaxing cycles to values below 5° F./day. The duration of the dewaxing cycles may be extended, particularly in the second and subsequent cycles after hydrogen reactivation.
Abstract: Process for converting a hydrocarbon fraction that is obtained from atmospheric distillation of a crude, comprising a vacuum distillation stage (a) of said feedstock that makes it possible to obtain a vacuum distillate and a vacuum residue; a stage b) for treating at least a portion of the vacuum distillate in the presence of hydrogen; a stage c) for treating at least a portion of the vacuum residue in the presence of hydrogen, whereby said stages b) and c) are each carried out in at least one separate triphase reactor that contains at least one ebullated-bed hydrotreatment catalyst that operates with an upward flow of liquid and gas; a stage d) in which at least a portion of the product that is obtained in stage b) is sent to an atmospheric distillation zone from which a light fraction and a heavier liquid fraction are recovered; a stage e) in which at least a portion of the product that is obtained in stage c) is sent to an atmospheric distillation zone from which a light fraction and a heavier liquid fract
Abstract: Process for converting a hydrocarbon fraction that is obtained from atmospheric distillation of a crude, comprising a vacuum distillation stage (a) of said feedstock that makes it possible to obtain a vacuum distillate and a vacuum residue; a stage b) for treating at least a portion of the vacuum distillate in the presence of hydrogen in at least one reactor that contains at least one fixed-bed hydrotreatment catalyst under conditions that make it possible to obtain a liquid effluent with a low sulfur content; a stage c) for treating at least a portion of the vacuum residue in the presence of hydrogen in at least one triphase reactor that contains at least one ebullated-bed hydrotreatment catalyst; a stage d) in which at least a portion of the product that is obtained in stage b) is sent to an atmospheric distillation zone from which a light fraction and a heavier liquid fraction are recovered; a stage e) in which at least a portion of the product that is obtained in stage c) is sent to an atmospheric distill
Abstract: Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+fraction to hydro-treating, and combining the 700° F.+portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.
Type:
Grant
Filed:
December 16, 1999
Date of Patent:
August 14, 2001
Assignee:
Exxon Research and Engineering Company
Inventors:
Robert Jay Wittenbrink, Richard Frank Bauman, Paul Joseph Berlowitz, Bruce Randall Cook
Abstract: A method of controlling asphaltene precipitation in a fluid comprising the addition of a precipitation inhibitor to the fluid containing the asphaltene.
Type:
Grant
Filed:
September 29, 1999
Date of Patent:
August 7, 2001
Assignee:
Imperial College of Science, Technology & Medicine
Abstract: An asphalt blend composition containing an asphalt component and a bottoms fraction from a used motor vaporization process of the above process, and a pavement composition comprising aggregate and the asphalt blend composition. The process comprises directly contacting used lubricating oil with a heated vapor, e.g., steam, under conditions which at least partially decompose the organo-metallic component and provide a desired volume of pumpable bottoms containing organo-metallic compound decomposition products and an overhead comprising gases and distillatable hydrocarbons, with no substantial carryover of metals into the overhead. The process may be carried out under conditions which minimize decomposition of high molecular weight additives such as VI improvers.
Type:
Grant
Filed:
April 11, 2000
Date of Patent:
August 7, 2001
Assignee:
Marathon Ashland Petroleum LLC
Inventors:
Howard F Moore, Donald P Malone, Patricia K Doolin, David J Zalewski
Abstract: Processes for providing improved methane removal and hydrogen reuse in reactors, particularly in refineries and petrochemical plants. The improved methane removal is achieved by selective purging, by passing gases in the reactor recycle loop across membranes selective in favor of methane over hydrogen, and capable of exhibiting a methane/hydrogen selectivity of at least about 2.5 under the process conditions.
Type:
Grant
Filed:
May 21, 1999
Date of Patent:
July 24, 2001
Assignee:
Membrane Tehnology and Research, Inc.
Inventors:
Richard W. Baker, Kaaeid A. Lokhandwala, Zhenjie He, Ingo Pinnau
Abstract: A coke drum head is hinged to a coke drum body using a compound joint such as a trammel pivot, and the head is moved between open and closed positions using an actuator. In moving between open and closed positions, the head traces out a non-circular path which reduces the required headroom relative to a head using a standard pivot.
Type:
Grant
Filed:
November 30, 1994
Date of Patent:
July 24, 2001
Assignee:
Fluor Corporation
Inventors:
Leslie Peter Antalffy, Robert Benoit, Gerald Bryant, Michael B. Knowles, David W. Malek, Samuel Allen Martin
Abstract: This invention relates to the refining of petroleum products, and more particularly to an integrated hydroprocessing scheme involving a hydrocracking stage and subsequent dewaxing stage. Materials boiling in the middle distillate or lube oil range may be dewaxed. The bottoms streams (and optionally, other streams) of each stage are maintained separately from one another, during processing. Dewaxing may occur using either hydroisomerization catalysts or shape-selective catalysts or both in series. One embodiment employs a baffle in the flash zone of a fractionator to separate bottoms streams from each other. Alternatively, the effluent from the hydrocracking stage may be processed separately from the effluent from the dewaxing stage. The bottoms fraction from the dewaxing stage may be recycled back to the hydrocracking stage for further processing or used as lube base stock.
Type:
Grant
Filed:
September 24, 1998
Date of Patent:
July 17, 2001
Assignee:
Mobil Oil Corporation
Inventors:
Arthur R. Gentry, Kenneth W. Goebel, Timothy L. Hilbert, Michael G. Hunter, David A. Pappal, Randall D. Partridge
Abstract: The invention provides a process for converting a hydrocarbon feed in which said feed is treated in a distillation zone producing an overhead vapour distillate and a bottom effluent, associated with an at least partially external reaction zone comprising at least one catalytic bed, in which at least one reaction for converting at least a portion of at least one hydrocarbon is carried out in the presence of a catalyst and a gas stream comprising hydrogen, the feed for the reaction zone being drawn off at the height of at least one draw-off level and representing at least a portion of the liquid flowing in the distillation zone, at least part of the effluent from the reaction zone being re-introduced into the distillation zone at the height of at least one re-introduction level, so as to ensure continuity of the distillation, said process being characterized in that a liquid distillate is withdrawn from the distillation zone at the height of at least one withdrawal level, said level being located below the vapo
Abstract: The present invention is a process for decreasing the acidity of a starting acidic crude oil by contacting an acidic crude with an effective excess of ammonia dissolved in said crude to form an ammonia-continuous oil discontinuous phase at a temperature and conditions sufficient to form the corresponding amide of the naphthenic acids. The process is useful in the processing of acidic crudes.
Type:
Grant
Filed:
September 21, 1999
Date of Patent:
July 10, 2001
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, David William Savage, William Neergaard Olmstead, Winston Karl Robbins, David Craig Dalrymple, Bruce Henry Ballinger
Abstract: Disclosed is a rubber process oil in which the content of polycyclic aromatics (PCAs) as determined by the IP 346 method is less than 3% by mass and which is rich In aromatic hydrocarbons, and a method for producing the same. The aniline point of the rubber process oil is 80° C. or less, and the % CA value as determined by ring analysis according to the Kurtz method is from 20 to 50%. The rubber process oil is produced by using extraction of lube oil fraction with a solvent having a selective affinity for aromatics. The extraction conditions are determined so that the extraction yield is regulated to a predetermined requirement defined by the PCAs content of the lube oil fraction. Alternatively, the extract is cooled to further separate into the extract and the raffinate, and the second raffinate is used for the rubber process oil.