Abstract: In an ebullated bed process, a nominal 1000.degree. F.+ boiling point vacuum residuum is hydrotreated at a first temperature of 750.degree. F. to 875.degree. F. and total pressure of 1900 psig to 3000 psig. Hydrogen partial pressure is controlled by changing total reactor pressure in the range of 1700 psig to 2300 psig to achieve a selected yield of 650.degree. F.- boiling material.

Abstract: During delayed coking, channels are formed in the solid coke bed to facilitate cooling of the hot coke drum. A distributor device injects a fluid, preferably steam, directly into the coke drum during delayed coking. The fluid travels through the coke bed and forms a channel which eliminates an impervious zone in the mass of solid coke. The channel allows more efficient cooling of the drum and eliminates the problem of a "hot drum" which can occur during delayed coking.

Abstract: An improved process for producing an anisotropic pitch product suitable for carbon fiber manufacture. A metal alkylaryl sulfonate is combined with a carbonaceous feedstock substantially free of mesophase pitch, and the combination is heated for a period of time at an elevated temperature while passing a non-oxidative sparging gas such as nitrogen through the feedstock. The process is carried out for a sufficient period of time to produce an anisotropic pitch having from 50 to 100 percent by volume mesophase which is suitable for producing good quality carbon fibers.In one aspect of the invention, an oxidatively reactive gas is used as the sparging gas.

Abstract: A process for producing ultra clean distillate and naphtha products wherein a distillate boiling range stream which contains heteroatoms and aromatics to subjected to three stage processing. The first stage is conventional hydrotreating, wherein the resulting effluent is further hydrotreated, but with a noble metal zeolite catalyst which is typically used for hydrocracking. The effluent from this second stage, which is now substantially free of heteroatoms, is passed to a third stage. This third stage is a hydrocracking stage, the severity of which will determine if the ultimate product will be a distillate or a naphtha.

Abstract: A two stage catalytic reforming process. The first stage is comprised of two separate fixed-bed reforming units each comprised of one or more serially connected fixed-bed reforming zones. The second stage is comprised of one or more moving-bed reforming zones with continual catalyst regeneration. A hydrogen-rich gaseous stream is separated after each fixed-bed unit and a portion is recycled to the respective fixed-bed reforming zones.

Abstract: A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a moving-bed mode with the catalyst being continually regenerated, and the second stage is operated in a fixed-bed mode.

Abstract: A reforming system for reforming gasoline boiling range hydrocarbon streams, which system is comprised of two or more parallel fixed-bed reforming stages sharing a common moving-bed reforming stage.

Abstract: Method and apparatus are provided whereby the heat released from exothermic hydrodemetallization reactions is recovered in order to provide either a lower operating cost of a two-stage hydrotreating process or protection of process equipment against excessive operating temperatures.

Abstract: A method of removing sulfur components from a hydrocarbon stream which involves contacting a hydrocarbon stream including an initial amount of at least one sulfur species selected from the group consisting of mercaptans, organic sulfides, and disulfides with a catalyst capable of adsorbing the sulfur species in the absence of extraneously added hydrogen and under conditions suitable for removing the at least one sulfur species from the hydrocarbon stream by the catalyst to form a resultant hydrocarbon stream containing a reduced amount of the at least one sulfur species.

Abstract: Gum and sediment formation in liquid hydrocarbon mediums are inhibited by adding to the medium a branched or straight chain C.sub.1 -C.sub.8 aminoalcohol. The invention is particularly well-suited for use in hydrodesulfurizer processes wherein the hydrocarbon medium is typically a naphtha, diesel, kerosene, light gas and or residual fuel charge and the charge or medium is subjected to high temperature and pressure treatment in the presence of a catalyst. The invention also shows particular advantage in distillate fuels, such as in blended diesel fuels, both before and during heat treatment processing thereof.

Abstract: The present invention relates to a hydroprocessing process that employs a catalyst that has been regenerated by subjecting the catalyst to an initial partial decoking step, followed by impregnation with a Group IIA metal-containing component and then subjected to a final decoking step.

Abstract: The present invention relates to a process for catalytically dewaxing a hydrocarbon oil feedstock by contacting the feedstock with a combination of a catalyst comprising an intermediate pore size silicoaluminophosphate molecular sieve and a hydrogenation component and an intermediate pore size aluminosilicate zeolite catalyst.

Abstract: The use of lift gas for FCC risers is improved by the direct use of stripping vapors from a second stage of catalyst stripping as a lift gas. Reactor vapors recovered primarily from the stripping section of an FCC reactor/regenerator section provide an excellent source for lift gas material. These reactor vapors contain high concentrations of light paraffinic materials often with an equal weight percent amount of steam. The recovery of the stripping vapors independent from the product stream allows such gaseous mixtures to be readily used as lift gas. The lift gas material is obtained from a stripping section located subadjacent to a regenerator section so that it will have adequate pressure for use as a lift gas stream. The relatively high pressure of the lift gas stream eliminates processing requirements that would otherwise be necessary for the removal of particulate material and the compression of the gas to the pressure conditions at the bottom of the riser.

Abstract: A process and apparatus for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A coke combustor vessel, which may be partially or totally open to the dilute phase above the bubbling bed, is added to the existing regenerator vessel. Spent catalyst is discharged into the coke combustor, regenerated in a turbulent or fast fluidized bed, then discharged into the dilute phase region above the bubbling bed, either via a deflector or by simply overflowing the combustor. Regeneration of catalyst is completed in the bubbling dense bed, and/or an annular fast fluidized bed surrounding the coke combustor. Catalyst may be recycled from the dense bed to the coke combustor either by a flow line, or by adjusting relative heights of bubbling to fast fluidized bed.

Abstract: Potential problems associated with the formation of polynuclear aromatic compounds during hydrocracking of residual oils are eliminated by operating at high conversion rates with a high hydrogen concentration followed by a unique separation method. The feed to the final product recovery column is preferably highly vaporized before or within the column. All of the net bottoms stream of the product recovery column, which is equal to less than 5 vol. percent of the feed, is withdrawn from the process. Only PNA free distillate is recycled.

Abstract: An improved delayed coking process is described in which sludge and oxygen contact hot coke during the quench cycle at conditions which cause at least a portion of the organics contained in the sludge to oxidize. Preferably, a portion of the sludge is combusted and the heat generated is used to help remove, during the quench cycle, entrapped liquids contained in the coke bed and to enhance thermal conversion of hazardous materials contained in the sludge to less harmful materials.

Abstract: The cetane numbers of viscoreduced diesel fuels are significantly improved by intimately contacting same with an effective amount of hydrogen peroxide in the presence of a carboxylic acid, or with an effective amount of a percarboxylic acid either in the presence or absence of hydrogen peroxide; the final product diesel fuels are also effectively deodorized and decolorized.

Abstract: Catalytic reforming processes using boron-containing large-pore zeolites.

Abstract: The cetane numbers of directly distilled diesel fuels are significantly improved by intimately contacting same with an effective amount of hydrogen peroxide in the presence of a carboxylic acid, or with an effective amount of a percarboxylic acid either in the presence or absence of hydrogen peroxide.

Abstract: A hydrocarbon conversion process to yield product of improved properties is effected in the presence of a zeolite characterized by increased Secondary Pore Volume, decreased Lattice Constant, Secondary Pore Mode, Secondary Pore Diameter, increased Secondary Pore Volume, Surface Silicon to Aluminum Atom Ratio, and Acid Site Density.