Patents Examined by Helen F. Lee
  • Patent number: 5306805
    Abstract: This invention relates to a simplified process for the preparation of polyarylene sulphides with improved product quality from alkali metal sulphides and dihalogenated aromatic compounds, in which the alkali metal sulphides are prepared and reacted in situ.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: April 26, 1994
    Assignee: Bayer AG
    Inventors: Wolfgang Arlt, Wolfgang Alewelt, Karl-Heinrich Meyer, Manfred Schmidt, Erhard Tresper, Wolfgang Eisermann
  • Patent number: 5306773
    Abstract: A resin composition moldable at room temperature comprising a thermosetting unsaturated polyester resin, a mixture of thermoplastic polymers of vinyl acetate and an epoxy compound having at least one 1,2-epoxy group per molecule, a dialkyl-p-toluidine accelerator, a low temperature free radical peroxide initiator such as a blend of cumene hydroperoxide and acetyl acetone peroxide, and an alkali metal or transition metal compound capable of reacting with the free radical initiator to initiate polymerization of the unsaturated polyester resin.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: April 26, 1994
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Dean H. Wiseman, Masamichi Togo
  • Patent number: 5304629
    Abstract: Disclosed herein are a process for the preparation of a carboxylated arylene thioether oligomer, in which an alkali metal sulfide is caused to act on a poly(arylene thioether) so as to depolymerize the poly(arylene thioether), thereby preparing an alkali thiolate-containing oligomer, and a carboxylating agent is then caused to act on the alkali thiolate-containing oligomer, thereby forming the carboxylated arylene thioether oligomer, and a process for the production of an arylene thioether copolymer, wherein the carboxylated arylene thioether oligomer alone, which has been obtained in accordance with this preparation process, or a mixture of the carboxylated oligomer in an amount of at least 50 wt. % and another carboxylic compound in an amount less than 50 wt. % is reacted with an alkylenediol or an alkylenediol and a polyester or an alkylene diol and a lactone.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: April 19, 1994
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Hiroyuki Sato, Mitsuru Hoshino, Yuichika Kawakami
  • Patent number: 5304630
    Abstract: Disclosed herein are a process for the preparation of a carboxylated arylene thioether oligomer, in which an alkali metal sulfide is caused to act on a poly(arylene thioether) so as to depolymerize the poly(arylene thioether), thereby preparing an alkali thiolate-containing oligomer, and a carboxylating agent is then caused to act on the alkali thiolate-containing oligomer, thereby forming the carboxylated arylene thioether oligomer, and a process for the production of an arylene thioether copolymer, wherein the carboxylated arylene thioether oligomer alone, which has been obtained in accordance with this preparation process, or a mixture of the carboxylated oligomer in an amount of at least 50 wt. % and another carboxylic compound in an amount less than 50 wt. % is reacted with an alkylenediol or an alkylenediol and a polyester or an alkylene diol and a lactone.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: April 19, 1994
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Hiroyuki Sato, Mitsuru Hoshino, Yukichika Kawakami
  • Patent number: 5300575
    Abstract: The invention relates to dispersions of polythiophenes made up of structural units corresponding to the following formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another represent hydrogen or a C.sub.1-4 alkyl group or, together, form an optionally substituted C.sub.1-4 alkylene group,in the presence of polyanions, to the production of these dispersions and to their use for the antistatic treatment of plastic mouldings.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: April 5, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich Jonas, Werner Krafft
  • Patent number: 5298573
    Abstract: A process is provided for preparing poly(arylene sulfide sulfone)/poly(arylene sulfide ketone) block copolymers comprising: contacting poly(arylene sulfide sulfone) prepolymer, at least one dihalobenzophenone, a sulfur source, and a polar organic compound under polymerization conditions.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: March 29, 1994
    Assignee: Phillips Petroleum Company
    Inventor: Dwayne R. Senn
  • Patent number: 5298574
    Abstract: A process is provided for preparing poly(arylene sulfide ketone)/poly(arylene sulfide sulfone) block copolymers comprising: contacting poly(arylene sulfide ketone) prepolymer, at least one dihaloaromatic sulfone, a sulfur source, and a polar organic compound under polymerization conditions. The polymers thus produced exhibit crystalline properties and an increased glass transition temperature.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: March 29, 1994
    Assignee: Phillips Petroleum Company
    Inventor: Dwayne R. Senn
  • Patent number: 5296527
    Abstract: A high strength, thermally resistant, fire retardant, composition of matter is provided comprising (A) about 99.5 to about 75 weight percent of unmodified polymethylpentene where the weight percent of polymethylpentene is based on the total weight of A and B; and (B) about 0.5 to about 25 weight percent of polyphenylene sulfide where the weight percent of polyphenylene sulfide is based on the total weight of A, and B; (C) about 10 to about 67 weight percent of a reinforcer where the weight percent of the reinforcer is based on the total weight of A, B, C, and D; (D) optionally about 5 to about 45 weight percent of a flame retardant where the weight percent of the flame retardant is based on the total weight A, B, C and D.
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: March 22, 1994
    Assignee: Phillips Petroleum Company
    Inventor: Edwin Boudreaux, Jr.
  • Patent number: 5296538
    Abstract: There is provided a thermoplastic resin composition, the composition comprising1 to 99% by weight of polyarylenesulfide-type resin (I),99 to 1% by weight of at least one resin (II) selected from the group consisting of polycarbonate-type resins, polyphenyleneether-type resins, and ABS-type resins, and0.1 to 100 parts by weight, on the basis of 100 parts by weight of the aforesaid resins (I)+(II), of a graft copolymer (III) as compatibilizer having a specific multi-phase structure.The thermoplastic resin composition containing the compatibilizer (III) of the present invention has a feature of each of the blended resins of a polyarylenesulfide-type resin (I) and at least one resin (II) selected from the group consisting of polycarbonate-type resins, polyphenyleneether-type resins and ABS-type resins, such as good impact and heat resistance, moldability, and appearance of molded articles.
    Type: Grant
    Filed: March 25, 1992
    Date of Patent: March 22, 1994
    Assignees: Nippon Petrochemicals Co., Ltd., Nippon Oil Fats Co., Ltd.
    Inventors: Yuichi Orikasa, Suehiro Sakazume
  • Patent number: 5296556
    Abstract: An improved thermoset adhesive composition comprising a thermoplastic, substantially amine-terminated polyamide resin, an epoxy resin, and a diluent, and methods for the preparation thereof.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: March 22, 1994
    Assignee: Union Camp Corporation
    Inventor: Charles R. Frihart
  • Patent number: 5294660
    Abstract: The present invention provides a polyphenylene sulfide film which consists essentially of a resin composition containing polyphenylene sulfide as major constituent, in which fine particles with an average particle size of 0.05-3 .mu.m are dispersed, the fine particles having a single particle index of not less than 0.5. The polyphenylene sulfide film of the present invention is excellent in not only the slipping property but also the number of electrical insulation defects are extremely small, so that the film of the present invention is useful for the dielectric film of film capacitor with stable initial characteristics. Further, since the film of the present invention is excellent in the slipping property and surface smoothness, so that it is useful as a base film for magnetic recording media with excellent magnetic conversion characteristics and excellent drop out characteristics.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: March 15, 1994
    Assignee: Toray Industries, Inc.
    Inventors: Yukichi Deguchi, Yukio Noguchi, Masaaki Sudo, Kiyohiko Ito
  • Patent number: 5292789
    Abstract: A polyphenylene sulfide/polyphenylene ether composition is provided, which has excellent dimensional stability and impact resistance, as well as good heat resistance, rigidity and surface appearance. The composition also includes certain polyamide resins, hydrogenated conjugated diene/aromatic monovinyl block copolymers, modified polyolefins, compatibilizer agents, and inorganic fillers.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: March 8, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Hiromi Ishida, Hidekazu Kabaya
  • Patent number: 5290881
    Abstract: The properties of polyphenylene ether-polyarylene sulphide mixtures are improved by the addition of an agent as it is known for the improvement of the properties of polyphenylene ether-polyamide mixtures.
    Type: Grant
    Filed: May 3, 1989
    Date of Patent: March 1, 1994
    Assignee: General Electric Company
    Inventor: Marinus E. J. Dekkers
  • Patent number: 5288893
    Abstract: This invention provides novel organosulfonimidates and a method for preparing both the present sulfonimidates and those disclosed in the prior art. Some of the sufonimidates can be condensed under relatively mild conditions to form polyorganooxothiazenes.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: February 22, 1994
    Assignee: Dow Corning Corporation
    Inventor: Aroop K. Roy
  • Patent number: 5288844
    Abstract: Disclosed herein is a high-refractive index plastic optical material comprising a copolymer obtained by subjecting a mixture composed of a component A consisting of a dithiol compound represented by the formula I: ##STR1## wherein n stands for an integer of 1-3, and a component B consisting of divinylbenzene, said mixture containing both components in such a manner that the proportion of the component A to the component B is 0.25-3.5 in terms of weight ratio, to addition polymerization and having a refractive index of at least 1.63 and an Abbe's number of at least 27. The optical material has excellent optical properties that the refractive index is high and the dispersion is low, and moreover possesses good physical properties.
    Type: Grant
    Filed: July 2, 1992
    Date of Patent: February 22, 1994
    Inventor: Teruo Sakagami
  • Patent number: 5288815
    Abstract: Disclosed herein are a poly(arylene thioether-ketone) copolymer comprising (A) at least one poly(arylene thioether-ketone) segment having predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other and (B) at least one poly(arylene thioether) segment having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) segment (B) to the total amount of the poly(arylene thioether-ketone) segment (A) ranging from 0.05 to 5 by weight, (b) the number-average polymerization degree of the poly(arylene thioether) segment (B) being higher than 1 but lower than 10, and (c) said copolymer having a melt viscosity of 2-100,000 poises as measured at 350.degree. C. and a shear rate of 1,200/sec as well as a production process of the poly(arylene thioether-ketone) copolymer.
    Type: Grant
    Filed: April 18, 1991
    Date of Patent: February 22, 1994
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Yoshiyuki Inaguma, Yasuhiro Suzuki
  • Patent number: 5288848
    Abstract: The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established at defined values and low corrosion.These polyarylene sulphides are obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and, if appropriate, polyhalogenoaromatics, with the addition of particular monohalogenoaromatics as chain stoppers.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: February 22, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karsten Idel, Wolfgang Ebert, Ludwig Bottenbruch, Dieter Freitag, Rolf-Volker Meyer
  • Patent number: 5286809
    Abstract: This invention relates to thermoplastic moulding compounds based on polyamides and/or polyesters and special functionally modified polyarylene sulphides and optionally conventional additives and to their preparation and their use.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: February 15, 1994
    Assignee: Bayer AG
    Inventors: Hans-Detlef Heinz, Burkhard Kohler
  • Patent number: 5286817
    Abstract: A process is provided for preparing poly(arylene sulfide)/poly(arylene sulfide sulfone) block copolymer comprising: contacting poly(arylene sulfide) prepolymer, a dihaloaromatic sulfone, a sulfur source, and a polar organic compound under polymerization conditions, wherein said prepolymer is prepared by contacting a dihaloaromatic compound, a phenolic compound, a polar organic compound, and a sulfur source under polymerization conditions.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: February 15, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Dwayne R. Senn, Carlton E. Ash
  • Patent number: 5286814
    Abstract: A heat-resistant stretched film is obtained by stretching a resin composition comprising 100 parts by weight of a poly(arylene sulfide) of a substantially linear structure and 5 to less than 100 parts by weight of a melt-stable poly(arylene thioether-ketone). The poly(arylene sulfide) has a melt viscosity of at least 1,000 poises as measured at 310.degree. C. and a shear rate of 200 sec.sup.-1. The poly(arylene thioether-ketone) has predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- groups are bonded in the para position to each other through the benzene ring, and has the following physical properties (a)-(c):(a) a melting point, Tm being 310.degree.-380.degree. C.;(b) a melt crystallization temperature, Tmc (420.degree. C./10 min) being at least 210.degree. C. and a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) being at least 10 J/g; and(c) a reduced viscosity being 0.3-2 dl/g at 25.degree. C. and a polymer concentration of 0.
    Type: Grant
    Filed: April 26, 1991
    Date of Patent: February 15, 1994
    Assignee: Kureha Kagaku Kogyo K. K.
    Inventors: Toshiya Mizuno, Yoshikichi Teramoto, Takeshi Saito, Juichi Wakabayashi, Yoshikatsu Satake, Ken Kashiwadate, Takayuki Katto