Abstract: The present invention relates to new inorganic pigments and to a process for preparing same. More particularly, it relates to new yellowish-green pigments consisting of titanium compounds. These pigments consist of the crystalline phases rutile TiO.sub.2, perovskite CaCO.sub.3 and trigonal CoTiO.sub.3. They contain 2 to 12% by weight of cobalt and 4 to 20% by weight of calcium based on total TiO.sub.2 and they have a dominant wave length .lambda..sub.D comprised between 530 and 560 m.mu..
Type:
Grant
Filed:
July 18, 1977
Date of Patent:
June 27, 1978
Assignee:
Montedison S.p.A.
Inventors:
Luigi Balducci, Dino Sarti, Fausto Gerelli
Abstract: Process for producing aqueous slurries of chloride process anatase titanium dioxide pigment by adding to the slurry from 0.03 to 0.45% by weight of sodium aluminate or aluminum trichloride, calculated as Al.sub.2 O.sub.3 and based on the weight of the titanium dioxide pigment. The resulting slurries retain relatively low viscosity for at least one day.
Abstract: A polycrystalline, fibrous rutile TiO.sub.2 pigmentary material having good optical properties and retention in paper, and exceptionally high tinting strength in latex paint systems is prepared by treating a substantially sulfate-free hydrous TiO.sub.2, prior to calcination, with a mineralizing complex comprising alkali metal and alkaline earth metal salts, a compound of boron and a rutile promoter sol, and calcining the treated hydrous TiO.sub.2 at temperatures in the ranges of from 812.degree.-865.degree. C. followed by washing to remove the calcium ions, milling, hydroclassification and drying; or optionally by a postcalcination treatment for imparting optimum pigmentary properties.
Abstract: Finely divided, fluosilicate-treated silica, such as silica flatting agent for use in coating formulations, is prepared by blending in a dry, finely divided state, silica and divalent metal fluosilicate, notably magnesium fluosilicate. In a preferred embodiment, dry pellets of amorphous, precipitated silica and dry magnesium fluosilicate are milled together to produce the fluosilicate-treated flatting agent. In another embodiment, an aqueous solution of magnesium fluosilicate is applied to silica pellets which are then milled.
Abstract: To prevent the escape of water into the porous aggregate of light-weight concrete at the time of pumping, the individual particles of the additive, which, with cement slurry, forms a gel-like protective layer, which is scarcely permeable to water, for a period of time, and which facilitates a bond between the aggregate and the cement. The protective layer can be produced by spraying a solution, in particular an aqueous solution of the additive into the aggregate particles, which are heated to a temperature above the boiling point of the solvent, and by evaporating the solvent.
Type:
Grant
Filed:
November 25, 1974
Date of Patent:
June 20, 1978
Assignee:
Chemotechnik Gesellschaft fur Baustoffchemie mbH & Co.
Abstract: Process for converting premilled quinacridone to pigmentary form by contacting the premilled quinacridone with an aqueous alkaline medium in the presence of at least one surfactant. The process eliminates the need for salt in the premilling operation and eliminates the use of organic liquids in the premilling or aftertreatment of the premilled quinacridone.
Abstract: An alumina refractory material and its method of preparation are disclosed. The material includes a volatilized silica binder wherein the volatilized silica binder is added to the batch as a thoroughly dispersed, acidified, aqueous slurry. Graphite and silicon carbide may also be included to control erosion by molten metal. Green strength binders are also usually included.
Abstract: In a two-stage process for producing black iron oxide pigments wherein an iron salt solution is alkalized in a first stage to precipitate about 55 to 70% of the iron, the solution is oxidized to convert the precipitate to goethite, the solution is further alkalized in a second stage to precipitate the balance of the iron, the precipitated iron II hydroxide is allowed to react with goethite to form magnetite, the improvement which comprises effecting the second stage in the presence of an inorganic ionic compound of at least one metal selected from the group consisting of copper, nickel, aluminum, chromium, titanium, zirconium and vanadium in about 0.05 to 5% calculated as metal based on the weight of the final pigment. The resulting pigment is of high color intensity, narrow grain distribution range and pronounced magnetite structure.
Type:
Grant
Filed:
April 8, 1976
Date of Patent:
May 23, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Jakob Rademachers, Franz Hund, Ingo Pflugmacher, Gerhard Winter
Abstract: Organic pigments which provide an opaque color impression in binders and exhibit adequate flow properties in binders are obtained from pigments which provide a transparent color impression in binders in a simple way in that an azeotrope-forming agent which is appropriate for the liquid adhering to the pigment is added to the moist pigment obtained after the preparation, and the azeotropic mixture and any excess solvent which may be present are then distilled off.
Type:
Grant
Filed:
May 10, 1976
Date of Patent:
May 16, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Horst Brandt, Reinhold Hornle, Karlheinz Wolf, Hans-Heinz Molls
Abstract: A pigment composition comprising pigment and at least 5% by weight based on the weight of composition of a complex formed from one or more non ionic polyether surfactants based on ethylene oxide and a polymeric carboxylic acid having a molecular weight of at least 1500.
Type:
Grant
Filed:
October 21, 1975
Date of Patent:
May 16, 1978
Assignee:
Ciba-Geigy Corporation
Inventors:
John Bryce Blackburn, Arnold William Field
Abstract: A copper phthalocyanine pigment composition consisting essentially of 100 parts by weight of copper phthalocyanine and 0.5 - 30 parts by weight of a copper phthalocyanine derivative having the following formula ##STR1## WHEREIN Cu--Pc-- is the residue of copper phthalocyanine, m and n are each an integer of 1 - 4, and R.sub.1 and R.sub.2 are each a substituted or non-substituted alkyl group or a heterocyclic group containing the nitrogen atom appearing in the formula.
Abstract: Process for converting crude quinacridone to pigmentary form by milling crude quinacridone in the presence of from 5% to 50% by weight of aluminum sulfate, based on the weight of the crude quinacridone. The resulting quinacridone exhibits high masstone transparency in coating compositions.
Abstract: Pigments are disclosed comprising zinc sulfide as a host containing in solid solution at least a sufficient amount of a metal sulfide additive or dopant to alter the color of the zinc sulfide. The dopant may comprise one or more certain metal sulfides but normally is present as a unitary sulfide, such as lithium sulfide, or preferably as a multiple sulfide, such as lithium indium sulfide and copper indium sulfide. Optionally, a binary metal compound dopant can include a metal oxide. The pigments may be prepared by encapsulating the host and dopant metal sulfides in vacuum to prevent introduction of oxides and then heating to an equilibrium temperature.
Abstract: A temperature-stable inorganic yellow pigment of the composition Fe.sub.2 TiO.sub.5 .multidot. x TiO.sub.2, where x is from 0 to about 15, with a particle diameter of less than about 1 micron is produced by forming an aqueous suspension of at least one finely divided iron compound selected from the group consisting of iron oxide, iron oxide hydroxide, iron hydroxide and iron carbonate and at least one finely divided titanium compound selected from the group consisting of titanium dioxide and titanium dioxide oxide hydrate, the iron and titanium compounds being present in accordance with the stoichiometric composition Fe.sub.2 TiO.sub.5 .multidot. x TiO.sub.2 where x is from 0 to about 15, removing the aqueous phase from the mixed suspension, and calcining the residue at a temperature from about 600.degree. C to 1100.degree. C.
Type:
Grant
Filed:
August 14, 1974
Date of Patent:
April 18, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Franz Hund, Wilhelm Holznagel, Henning Erfurth, Friedrich Kindervater, Willi Hennings
Abstract: An Fe.sub.3 O.sub.4 iron oxide black pigment having incorporated therein up to about 50 mole percent of .gamma.-Fe.sub.2 O.sub.3 plus Me Fe.sub.2 O.sub.4 (wherein Me is at least one of magnesium, manganese, cobalt, nickel, aluminum, chromium, titanium, copper, zinc and cadmium) having a specific surface according to BET of greater than about 12 m.sup.2 /g, up to about 10% by weight of a substantially insoluble inorganic compound as coating and a stability to oxidation with air under standardized conditions of greater than about 130.degree. C. Advantageously the coating comprises at least one of zinc hydroxide, zinc phosphate, zinc phosphite, aluminum phosphate and silica, being precipitated onto the suspended pigment from a solution. The resulting pigments are of improved resistance to oxidation, rendering them especially useful for pigmenting inorganic and organic dispersions and for use on magnetogram supports.
Type:
Grant
Filed:
May 16, 1977
Date of Patent:
April 4, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Bernd Stephan, Franz Hund, Wilhelm Holznagel
Abstract: A process includes hydrating between about 10.degree. and 100.degree. C, one of the synthesized anhydrous calcium aluminates prepared specially or stemming from the manufacture of hydraulic binders or of anhydrous calcium silicates, groundup to an average degree of fineness, with a quantity of water of such an order of magnitude that a paste is formed, having dry extracts between about 5 and 70% by weight; subjecting at least the large particles to a vigorous agitation during the hydration to form a suspension, drying the formed suspension to a dry powder and collecting the obtained dry powder.
Abstract: This invention provides a high bulking clay consisting essentially of selectively flocculated ultra fine particles of clay coated with a member from the group consisting of polyfunctional amines and long chain amines.
Abstract: Sulfur containing organosilicon compounds having the formula:Z - Alk - S.sub.n - Alk - Zin which Z is: ##STR1## where R.sub.1 is alkyl of 1 to 4 carbon atoms, cyclohexyl or phenyl and R.sub.2 is alkoxy of 1 to 8 carbon atoms, cycloalkoxy of 5 to 8 carbon atoms or alkylmercapto of 1 to 8 carbon atoms, alk of a divalent aliphatic hydrocarbon or unsaturated aliphatic hydrocarbon or a cyclic hydrocarbon containing 1 to 18 carbon atoms and n is a whole number from 2 to 6 are used as reinforcing additives in rubber mixtures containing a silica or silicate filler, and in a given case carbon black; the organosilane is coated on the surface of the silica or silicate filler particles.
Type:
Grant
Filed:
May 26, 1976
Date of Patent:
February 28, 1978
Assignee:
Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
Inventors:
Friedrich Thurn, Kurt Burmester, Johannes Pochert, Siegfried Wolff
Abstract: A high bulk clay product and method of making the same are provided in which kaolinite is selectively flocculated to produce an ultra fine particle fraction in the presence of fine mica below 150 mesh in size and the resulting flocculant is collected and dried.
Type:
Grant
Filed:
December 27, 1976
Date of Patent:
February 28, 1978
Assignee:
Yara Engineering Corporation
Inventors:
Wayne M. Bundy, Joseph P. Berberich, David Sastre
Abstract: A process for the preparation of carbon black-containing pigments consists essentially of precipitation of a carbon black-containing metal hydroxide or bismuth oxychloride layer on substrate particles in an aqueous suspension containing carbon black particles of particle size of below 1 mn. and washing, drying and optionally calcining the products. Flaky substrates, e.g., mica flakes coated with TiO.sub.2, are preferably employed. Carbon black-containing pigments obtained have carbon black particles incorporated in a metal hydroxide, metal oxide or bismuth oxychloride layer precipitated on the substrate in the presence of the carbon black.
Type:
Grant
Filed:
December 10, 1976
Date of Patent:
February 28, 1978
Assignee:
Merck Patent Gesellschaft mit beschrankter Haftung