Abstract: Articles, compositions, and methods involving ionically conductive compounds are provided. In some embodiments, the ionically conductive compounds are useful for electrochemical cells. The disclosed ionically conductive compounds may be incorporated into an electrochemical cell (e.g., a lithium-sulfur electrochemical cell, a lithium-ion electrochemical cell, an intercalated-cathode based electrochemical cell) as, for example, a protective layer for an electrode, a solid electrolyte layer, and/or any other appropriate component within the electrochemical cell. In certain embodiments, electrode structures and/or methods for making electrode structures including a layer comprising an ionically conductive compound described herein are provided.
Type:
Grant
Filed:
December 22, 2021
Date of Patent:
October 29, 2024
Assignees:
Sion Power Corporation, BASF SE
Inventors:
Holger Schneider, Hui Du, Klaus Leitner, Johan ter Maat, Pascal Hartmann, Joern Kulisch, Marina Safont-Sempere, Tracy Earl Kelley, Chariclea Scordilis-Kelley
Abstract: An electrode catalyst is configured such that non-noble metal particles, noble metal particles or nitride-doped noble metal particles are supported on a carbon support, wherein the carbon support has a 2D planar crystal structure or a 3D polyhedral crystal structure and is doped with nitrogen, thereby exhibiting increased catalytic activity.
Type:
Grant
Filed:
December 28, 2020
Date of Patent:
October 22, 2024
Assignees:
HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION, DAEGU GYEONGBUK INSTITUTE OF SCIENCE AND TECHNOLOGY
Inventors:
Eun Jik Lee, Jee Youn Hwang, Ji Hoon Jang, Ha Young Lee, Jong Sung Yu
Abstract: Molten lithium-sulfur and lithium-selenium electrochemical cells are disclosed. A solid electrolyte separates a molten lithium metal or molten lithium metal alloy 106 from a molten sulfur or molten selenium. The molten lithium-sulfur and lithium-selenium cells have low over potential, no side reaction, and no dendrite growth. These cells have high Coulombic efficiency and energy efficiency and thus provide new chemistries to construct high-energy, high-power, long-lifetime, low-cost and safe energy storage systems.
Abstract: Disclosed is a liquid electrolyte for use in lithium-ion, lithium-metal, and lithium-sulfur batteries, in which the liquid electrolyte comprises at least one organic nonlinear carbonate, at least one lithium salt, and at least one cyclic sulfoxide, and in which the liquid electrolyte does not comprise a combination of propylene carbonate, tetrahydrothiophene-1-oxide, and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). Also disclosed is a lithium secondary battery comprising an anode, a cathode, a separator, and the liquid electrolyte for use in lithium-ion, lithium-metal, and lithium-sulfur batteries.
Abstract: The present invention relates to an apparatus, detachably mountable to the external surface of an aircraft. More specifically, the present invention relates to a fully self-contained apparatus comprising an electrical device, such as a Directed Energy Weapon (DEW), and a corresponding thermal management system and power supply.
Abstract: Provided is a precursor of a positive electrode active material containing, in a reduced amount, impurities which do not contribute to a charge/discharge reaction but rather corrode a firing furnace and peripheral equipment and thus having excellent battery characteristics and safety, and production method thereof. A method for producing a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries having a hollow structure or porous structure includes obtaining the precursor by washing nickel-manganese composite hydroxide particles having a particular composition ratio and a pore structure in which pores are present within the particles with an aqueous carbonate solution having a carbonate concentration of 0.1 mol/L or more.
Abstract: Mesoporous carbon has a connecting structure in which primary particles made of carbon particles having primary pores with a primary pore diameter of less than 20 nm are connected. In the mesoporous carbon, the pore capacity of secondary pores with secondary pore diameters within a range of 20 nm to 100 nm, which is measured by a mercury intrusion method, is 0.42 cm3/g or more and 1.34 cm3/g or less. In addition, the mesoporous carbon has a linearity of 2.2 or more and 2.6 or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores in the mesoporous carbon. Furthermore, a catalyst layer includes the electrode catalyst for the fuel cell and a catalyst layer ionomer.
Type:
Grant
Filed:
March 28, 2022
Date of Patent:
September 10, 2024
Assignee:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Naoki Hasegawa, Kazuhisa Yano, Tomohiro Takeshita, Rui Imoto, Kumiko Nomura, Noriyuki Kitao, Yunan Wang, Yuuki Kasama
Abstract: Provided is a gas adsorption sheet for a secondary battery, which contains gas adsorbent particles excellent in gas adsorption property, and allows the gas adsorption performance of the gas adsorbent particles to be sufficiently exhibited. According to one embodiment of the present invention, there is provided a gas adsorption sheet for a secondary battery, including: a heat-resistant base material; and a gas adsorption layer arranged on at least one surface of the heat-resistant base material, wherein the gas adsorption layer contains: a binder resin; and gas adsorbent particles each of which is formed of an inorganic porous material having pores, and is capable of adsorbing a gas.
Abstract: A method for producing a lithium-containing oxide comprising one or more metal elements, which can be used as an active material for an electrode, for example a positive electrode for a lithium battery, the method comprising the following successive steps: a) a step of bringing at least one coordination polymer into contact with a lithium source, the coordination polymer comprising the other metal element(s) interconnected by organic ligands; b) a step of calcining the mixture resulting from step a).
Type:
Grant
Filed:
June 18, 2019
Date of Patent:
September 3, 2024
Assignee:
COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ÉNERGIES ALTERNATIVES
Abstract: Systems and methods are provided for a slurry for coating an electrode structure. In one example, a method may include dispersing, by mixing at one or both of a high shear and a low shear, a solid ionically conductive polymer material in at least a first portion of a solvent to form a suspension, then dispersing, by mixing at the one or both of the high shear and the low shear, one or more additives in the suspension, and then mixing, at the one or both of the high shear and the low shear, a second portion of the solvent with the suspension to form a slurry. As such, the slurry including the solid ionically conductive polymer material may be applied as a coating in a solid-state battery cell, which may reduce resistance to Li-ion transport and improve mechanical stability relative to a conventional solid-state battery cell.
Type:
Grant
Filed:
July 1, 2020
Date of Patent:
August 13, 2024
Assignee:
A123 SYSTEMS LLC
Inventors:
Wesley Hoffert, Adriana A. Rojas, David M. Laughman, Lucienne Buannic, Derek C. Johnson, Brian Sisk, Brian Chiou, Thomas Gillooly
Abstract: A device for diagnosing a valve failure of a fuel cell system is capable of accurately and quickly determining whether an integrated valve in a fuel cell system is operated abnormally, and preventing problems caused by the operation abnormality of the integrated valve.
Abstract: A method for reducing the carbon corrosion in a fuel cell stack of a fuel cell system includes the steps of detecting a corrosion value which is representative of the extent of the carbon corrosion probably occurring in the fuel cell stack during an inactive phase of the fuel cell stack, and initiating a protective measure for reducing the carbon corrosion in the fuel cell stack on the basis of the corrosion value.
Type:
Grant
Filed:
October 29, 2019
Date of Patent:
July 23, 2024
Assignee:
Bayerische Motoren Werke Aktiengesellschaft
Abstract: A free-standing electrode film may comprise an electrode active material and a composite binder comprising polytetrafluoroethylene (PTFE) and polyvinylpyrrolidone (PVP). An electrode for an energy storage device may comprise a current collector and a film on the current collector, the film including an electrode active material and a composite binder comprising PTFE and PVP. A method of manufacturing a free-standing electrode film may comprise preparing a mixture including an electrode active material and a composite binder, the composite binder comprising PTFE and one or more additional binders selected from the group consisting of PVP, polyvinylidene fluoride (PVDF), polyethylene oxide (PEO), and carboxymethylcellulose (CMC). The method may further comprise adding a solvent to the mixture, subjecting the mixture to a shear force, and, after the solvent has been added and the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.
Type:
Grant
Filed:
November 13, 2020
Date of Patent:
July 16, 2024
Assignee:
LICAP TECHNOLOGIES, INC.
Inventors:
Bibek Tiwari, Linda Zhong, Bae Hyun Kim, Hyeunhwan An
Abstract: The invention relates to a method for the precipitation of a solid material, where the method comprises: providing an aqueous metal ion solution, said metal ion solution comprising TiOSO4 and metal ions of a metal M, where M is one or more of the elements: Mg, Co, Cu, Ni, Mn, Fe; providing an aqueous carbonate solution; and mixing said aqueous metal ion solution and said aqueous carbonate solution thereby providing a solid material comprising titanium and a metal carbonate comprising said metal(s) M, where the titanium is homogeneously distributed within the solid material. The invention also relates to a solid material, a method of preparing a positive electrode material for a secondary battery from the solid material and the use of the solid material as a precursor for the preparation of a positive electrode material for a secondary battery.
Type:
Grant
Filed:
August 15, 2018
Date of Patent:
July 2, 2024
Assignee:
TOPSOE BATTERY MATERIALS A/S
Inventors:
Søren Dahl, Jon Fold Von Bülow, Rainer Küngas, Anni Stahl, Peter Axmann, Gisela Arnold, Claudia Pfeifer, Wolfgang Weirather
Abstract: An electrolyte composition includes at least a sodium salt dissolved in at least one solvent and a combination of additives. The solvent is any of ethylene carbonate, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, propylene carbonate, ethyl acetate, ethyl propionate, methyl propionate, 4-fluorotoluene, 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropyl ether, di-fluoro ethylene carbonate, ethyl difluoroacetate, or mixtures of the foregoing. The combination of additives includes at least sodium difluoro(oxalato)borate (NaODFB) and tris(trimethylsilyl)phosphite (TMSPi).
Type:
Grant
Filed:
June 18, 2019
Date of Patent:
June 25, 2024
Assignees:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, COLLEGE DE FRANCE, SORBONNE UNIVERSITÉ
Abstract: In a fuel cell system, for example HTPEM fuel cells. a valve system is employed by selectively guiding exhaust gas from the burner either to the reformer for heating the reformer, especially during normal operation, or to by-pass the reformer in startup situations in order to heat the fuel cell stack before starting heating the reformer. Optionally, a compact burner/reformer unit is provided.
Abstract: According to the present disclosure, it is possible to appropriately prevent a shortage of a nonaqueous electrolyte solution in an electrode body and keep battery performance of a nonaqueous electrolyte secondary battery at a favorable state. A nonaqueous electrolyte secondary battery disclosed herein includes an electrode body and a nonaqueous electrolyte solution. The electrode body includes an electrolyte solution passage that is a flow passage through which the nonaqueous electrolyte solution flows between the inside and the outside of the electrode body.
Abstract: A method for the production of an electrode for a fuel cell is provided that comprises providing a multitude of catalyst particles carried on at least one electrically conductive particle carrier, and depositing one or more atomic or molecular layers of an ionomer from the gas phase on the catalyst particles and/or the at least one particle carrier, thereby forming a proton-conducting ionomer coating. Furthermore, an electrode for a fuel cell is also provided.
Type:
Grant
Filed:
December 5, 2019
Date of Patent:
June 11, 2024
Assignees:
Volkswagen AG, Audi AG
Inventors:
Thomas Schladt, Lasse Schmidt, Tanja Graf, Gerold Hübner, Jonathan Edward Müller
Abstract: The present disclosure relates to an electrode for an all solid-state battery and a method for manufacturing the same. The electrode comprises an electrode active material layer, wherein the gaps between the electrode active material particles forming the electrode active material layer are filled with a mixture of a polymeric solid electrolyte, oxidation-/reduction-improving additive and a conductive material. The method for manufacturing the electrode comprises a solvent annealing process, and the dissociation degree and transportability of the oxidation-/reduction-improving additive are increased through the solvent annealing process, thereby improving the life characteristics of a battery.
Type:
Grant
Filed:
May 3, 2019
Date of Patent:
June 4, 2024
Assignee:
LG Energy Solution, Ltd.
Inventors:
Jung-Pil Lee, Ji-Hee Ahn, Sung-Joong Kang, Jae-Hyun Lee
Abstract: A separator including a porous polymer substrate and an inorganic coating layer formed on at least one surface of the porous polymer substrate. The inorganic coating layer includes inorganic particles and a binder resin. The binder resin includes a first binder resin and a second binder resin. The first binder resin comprises a polyvinylidene fluoride (PVdF)-based polymer and the second binder resin comprises an acrylic polymer. The acrylic polymer has an acid value of 1 or less and a glass transition temperature, Tg, of 90° C. to 130° C. In addition, the inorganic coating layer has a high content of binder resin at the top layer portion to provide excellent adhesion between the separator and an electrode.
Type:
Grant
Filed:
September 27, 2019
Date of Patent:
May 21, 2024
Assignee:
LG ENERGY SOLUTION, LTD.
Inventors:
Young-Bok Kim, Dong-Wook Sung, So-Mi Jeong