Patents Examined by Margaret Page
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Patent number: 5493057Abstract: Chloroethylsulfonylbenzaldehydes of the formula ##STR1## where n is 1 or 2 and the ring A may be substituted with halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkysulfonyl, nitro or hydroxysulfonyl, are prepared.Type: GrantFiled: May 7, 1993Date of Patent: February 20, 1996Assignee: BASF AktiengesellschaftInventors: Claus Marschner, Manfred Patsch
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Patent number: 5304683Abstract: A process for converting at least one alkyl mercaptan to a dialkyl sulfide can be carried out by contacting the alkyl mercaptan, and optionally an alkene, with an alumina catalyst under conditions sufficient to substantially covert the alkyl mercaptan to dialkyl sulfide. For example, ethyl mercaptan can by advantageously fed at a rate of about 0.5 to about 10 parts by weight per part by weight of the catalyst per hour over the catalyst at elevated temperature and pressure to produce diethyl sulfide.Type: GrantFiled: July 2, 1992Date of Patent: April 19, 1994Assignee: Phillips Petroleum CompanyInventor: Willaim E. Sattich
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Patent number: 5302619Abstract: Aromatic compounds are disclosed of the formula: ##STR1## wherein R.sup.1 is a C.sub.3 -C.sub.8 alkyl group, a C.sub.3 -C.sub.8 alkoxy group, an alkoxyalkyl group having 3 to 8 carbon atoms, a C.sub.3 -C.sub.8 alkenyl group, a C.sub.3 -C.sub.8 alkenyloxy group, an alkenyloxyalkyl group having 3 to 8 carbon atoms, a C.sub.3 -C.sub.8 haloalkyl group, a C.sub.3 -C.sub.8 haloalkoxy group, a haloalkoxyalkyl group having 3 to 8 carbon atoms, a C.sub.3 -C.sub.8 haloalkenyl group, a C.sub.3 -C.sub.8 haloalkenyloxy group, a haloalkenyloxyalkyl group having 3 to 8 carbon atoms or a C.sub.3 -C.sub.8 alkynyloxy group; R.sup.2 is a halogen atom; R.sup.3 groups are the same or different and each is a hydrogen atom, a halogen atom or a methyl group; R.sup.4 is a hydrogen atom or a methyl group; R.sup.5 groups are the same or different and each is a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.1 -C.sub.4 alkoxy group, a C.sub.1 -C.sub.4 haloalkoxy group, a C.sub.Type: GrantFiled: February 28, 1992Date of Patent: April 12, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Akira Shuto, Noriyasu Sakamoto, Hirosi Kisida, Hiroaki Fujimoto, Kimitoshi Umeda, Noritada Matsuo
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Patent number: 5283369Abstract: A process for producing a novel catalyst wherein an amorphous alumina gel is formed at least on the surface of an aluminum-containing material, the gel is heated to form crystalline .alpha.- or .beta.-alumina trihydrate and the trihydrate is sulfided, the product of said process, and the method of producing mercaptans from alcohols or ethers and hydrogen sulfide at elevated temperature in the presence of said novel catalyst, are disclosed herein.Type: GrantFiled: March 24, 1992Date of Patent: February 1, 1994Assignee: Elf Atochem North America, Inc.Inventors: Roger T. Clark, James A. Elkins, Jr.
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Patent number: 5266727Abstract: A process for purifying alkyl sulfides by absorption of the organosulfur impurities on an absorbent. The absorber is a copper salt deposited on a high surface area support. The purified alkyl sulfide is useful as an extractant for palladium.Type: GrantFiled: July 10, 1992Date of Patent: November 30, 1993Assignee: Chevron Research and Technology CompanyInventors: Harris E. Kluksdahl, Gary M. H. Lee
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Patent number: 5262441Abstract: An aromatic compound of the formula: ##STR1## wherein R.sup.1 is a C.sub.3 -C.sub.8 alkyl group, a C.sub.3 -C.sub.8 alkoxy group, an alkoxyalkyl group having 3 to 8 carbon atoms, a C.sub.3 -C.sub.8 alkenyl group, a C.sub.3 -C.sub.8 alkenyloxy group, an alkenyloxyalkyl group having 3 to 8 carbon atoms, a C.sub.3 -C.sub.8 haloalkyl group, a C.sub.3 -C.sub.8 alkoxy group, a haloalkoxyalkyl group having 3 to 8 carbon atoms, a C.sub.3 -C.sub.8 haloalkenyl group, a C.sub.3 -C.sub.8 haloalkenyloxy group, a haloalkenyloxyalkyl group having 3 to 8 carbon atoms or a C.sub.3 -C.sub.8 alkynyloxy group; R.sup.2 is a halogen atom; R.sup.3 is, the same or different, a hydrogen atom, a halogen atom or a methyl group; R.sup.4 is a hydrogen atom or a methyl group R.sup.5 is, the same or different, a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.1 -C.sub.4 alkoxy group, a C.sub.1 -C.sub.4 haloalkoxy group, a C.sub.1 -C.sub.4 alkylthio group, a C.sub.1 -C.sub.Type: GrantFiled: September 28, 1992Date of Patent: November 16, 1993Assignee: Sumitomo Chemical Company LimitedInventors: Akira Shuto, Noriyasu Sakamoto, Hirosi Kisida, Hiroaki Fujimoto, Kimitoshi Umeda, Noritada Matsuo
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Patent number: 5250574Abstract: An aromatic compound of the formula: ##STR1## wherein R.sup.1 is, the same or different, a halogen atom, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.1 -C.sub.3 alkoxy group or a C.sub.1 -C.sub.3 haloalkoxy group; R.sup.2 is a hydrogen atom or a methyl group; R.sup.3 is, the same or different, a halogen atom, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.1 -C.sub.2 alkoxy group or a C.sub.1 -C.sub.2 haloalkoxy group, or two adjacent R.sup.3 s may be combined together to represent a C.sub.1 -C.sub.2 alkylenedioxy group optionally bearing one or two substituents selected from halogen and methyl; p is an integer of 2 to 5; q is an integer of 0 to 5, which is useful for control of insect pests.Type: GrantFiled: October 25, 1991Date of Patent: October 5, 1993Assignee: Sumitomo Chemical Company LimitedInventors: Noriyasu Sakamoto, Akira Shuto, Hirosi Kisida, Hiroaki Fujimoto, Kimitoshi Umeda
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Patent number: 5241120Abstract: Process for the preparation of alkyl 3-chlorophenyl sulfones of the formula (I), in which R.sub.1 and R.sub.2 are straight-chain or branched alkyl (C.sub.1 -C.sub.4) groups, which can be identical or different, by reacting alkyl phenyl sulfones of the formula (II), in which R.sub.1 and R.sub.2 have the meanings given above, with chlorine in sulfuric acid or fuming sulfuric acid at temperatures of about 20 to about 180.degree. C.Type: GrantFiled: June 15, 1992Date of Patent: August 31, 1993Assignee: Hoechst AktiengesellschaftInventors: Gunther Sell, Gunther Semler
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Patent number: 5220041Abstract: Omega-alkanesulfonoxyalkanamides which are useful as alkylating agents are provided. Such alkylating agents are particularly useful for appending groups of the formula --Y--CONR.sup.8 R.sup.9 wherein Y is selected from the group consisting of unsubstituted or substituted trimethylene, tetramethylene, or pentamethylene; and R.sup.8 and R.sup.9 are hydrogen or various hydrocarbyl radicals onto electrophilic sulfur, oxygen or nitrogen moieties.Type: GrantFiled: January 21, 1992Date of Patent: June 15, 1993Assignee: Eastman Kodak CompanyInventor: Paul R. Buckland
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Patent number: 5210257Abstract: Novel aryl ethers, containing both a carboxylic acid and a sulfonic acid functionality; and a process for making them are described. These difunctional aryl compounds comprise:i) a carboxylic acid group or its derivative,ii) a first aromatic group bonded to the carboxylic acid or its derivative,iii) a second aromatic group linked to the first aromatic group by a non-electron-withdrawing moiety,iv) a third aromatic group linked to the second aromatic group by a non-electron-withdrawing moiety, andv) a sulfonyl group or its derivative bonded to the third aromatic group.Type: GrantFiled: April 12, 1991Date of Patent: May 11, 1993Assignee: The Dow Chemical CompanyInventor: William J. Harris
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Patent number: 5206439Abstract: Product from the reaction of mercaptan with sulfur in the presence of a basic catalyst is treated by contacting with an alcohol-based solution containing an oxidizing agent and an inorganic basic catalyst followed by the recovery of a purified polysulfide product.Type: GrantFiled: January 27, 1992Date of Patent: April 27, 1993Assignee: Phillips Petroleum CompanyInventor: James E. Shaw
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Patent number: 5196604Abstract: Polymers comprising fluorine-containing poly(ether sulfones) and monomers comprising aromatic fluorine-containing sulfones used in the preparation of these polymers.Type: GrantFiled: November 4, 1991Date of Patent: March 23, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew E. Feiring, Samuel D. Arthur
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Patent number: 5189223Abstract: The present invention provides a process for preparing 4,4'-dihydroxydiphenylsulfone which comprises subjecting a phenol and a sulfonating agent to dehydration reaction in the presence of mesitylene as a reaction medium while the produced 4,4'-dihydroxydiphenylsulfone is suspended in the mesitylene, and a process for preparing 4,4'-dihydroxydiphenylsulfone, characterized in that after the foregoing dehydration reaction, the 4,4'-dihydroxydiphenysulfone obtained as suspended in the mesitylene and/or retained in a liquid-free solid form is subjected to reaction for isomerization of 2,4'-dihydroxydiphenylsulfone produced as a by-product into 4,4'-dihydroxydiphenylsulfone with heating at a temperature of not lower than that for isomerization of 2,4'-dihydroxydiphenylsulfone into 4,4'-dihydroxydiphenylsulfone.Type: GrantFiled: May 1, 1991Date of Patent: February 23, 1993Assignee: Konishi Chemical Ind. Co., Ltd.Inventors: Eiji Ogata, Nobuyuki Nate
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Patent number: 5189224Abstract: The present invention provides a method for preparing a 4-alkylsulfonyl-2-chloro-m-xylene useful as an intermediate for agricultural chemicals, and an intermediate for the production thereof. The method of the present invention is to produce (E) from (C) by way of novel intermediates (D-1) and (D-2).Type: GrantFiled: October 9, 1991Date of Patent: February 23, 1993Assignee: Nissan Chemical Industries Ltd.Inventors: Masatoshi Baba, Eiichi Oya
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Patent number: 5185472Abstract: Novel mixtures of bicyclic ethers of the formulas ##STR1## wherein R represents an alkyl group of from one to four carbon atoms, said mixture having at least a 1.1:1 ratio of Ia to Ib, a process for their manufacture and their use as odoranis and novel intermediates for their preparation are described.Type: GrantFiled: February 28, 1991Date of Patent: February 9, 1993Assignee: Givaudan CorporationInventors: Georg Frater, Harald Schmidt
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Patent number: 5177245Abstract: Provided is a process for preparing optionally-substituted cyclohexenylhydroquinones starting from cyclohexanone.Type: GrantFiled: November 25, 1991Date of Patent: January 5, 1993Assignee: Eastman Kodak CompanyInventors: Dewey W. Fuller, Jr., Gether Irick, Jr.
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Patent number: 5175371Abstract: An improved process for preparing either optically pure enantiomer of the bark beetle pheromones ipsenol and ipsdienol is provided. The process is also applicable to the condensation of aldehydes of widely varying properties to the corresponding chiral alcohol.Type: GrantFiled: March 16, 1992Date of Patent: December 29, 1992Assignee: Aldrich Chemical Company, Inc.Inventor: Herbert C. Brown