Patents Examined by Ralph H. Dean
  • Patent number: 5648427
    Abstract: A curable composition which comprises (A) an oxyalkylene polymer having a silicon-containing group(s) that has a hydroxy group(s) and/or a hydrolyzable group(s) bonded to the silicon atom(s), and can be crosslinked by forming siloxane bond, and (B) hollow microspheres of vinylidene chloride polymer whose true specific gravity is 1 g/cm.sup.3 or less.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: July 15, 1997
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisa
    Inventors: Masayuki Fujita, Hiroshi Wakabayashi
  • Patent number: 5643997
    Abstract: A polyethylenic resin composition comprising: at least one high density polyethylenic resin selected from (a) a high density polyethylenic resin (Resin A) and (b) a modified high density polyethylenic resin as derived by grafting on the Resin A a monomer of unsaturated carboxylic acid or its derivative (Resin B), at least one linear low density polyethylenic resin selected from (c) a linear low density polyethylenic resin (Resin C) and (d) a modified linear low density polyethylenic resin as derived by grafting on the Resin C the monomer as described in (b) above (Resin D), and (e) a linear very low density polyethylenic resin (Resin E) having a density (g/cm.sup.3) of at least 0.890, but less than 0.910, and a melting point of 110.degree. to 125.degree. C. This polyethylenic resin composition is excellent in fuel oil resistance, low temperature impact resistance, and heat resistance, and provides a material having affinity or adhesive properties to various resinous and metallic materials.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 1, 1997
    Assignee: Showa Denko K.K.
    Inventors: Masami Matsuoka, Hikaru Aoyagi
  • Patent number: 5644014
    Abstract: A coating composition is disclosed based on polycondensates of hydrolyzable compounds in particular of Si, Al, Ti and/or Zr, whereas at least part of the non-hydrolyzable groups linked to these elements contain in average 2 to 30 fluorine atoms linked to aliphatic carbon atoms. A process for producing such coating compositions is also disclosed. The corresponding cured (transparent) coatings are characterized in particular by a very good adherence to various types of substrates, in particular glass, besides an antiadhesive effect with respect to many different materials.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: July 1, 1997
    Assignee: Institut Fur Neue Materialien gemeinnutzige GmbH
    Inventors: Helmut Schmidt, Reiner Kasemann, Stefan Bruck
  • Patent number: 5641850
    Abstract: Liquid-crystalline polyorganosiloxanes containing methacryloxy and/or acryloxy groups are prepared by reaction of polyorganosiloxanes containing hydrogen atoms bonded directly to silicon atoms with alkenes and/or alkynes containing mesogenic groups in two steps, wherein the polyorganosiloxanes mentioned are reacted in a first step with alkene and/or alkyne containing mesogenic groups and are reacted in a second step with an alkene and/or alkyne containing at least one methacryloxy and/or acryloxy group and mesogenic groups.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: June 24, 1997
    Assignee: Consortium fur electrochemische Industrie GmbH
    Inventors: Juergen Stohrer, Franz-Heinrich Kreuzer, Hans-Joachim Luckas
  • Patent number: 5639803
    Abstract: This invention relates to a multi-step process for preparing a storage-stable dispersion of a biocide which comprises the steps of: (a) contacting a heat-swellable resin with a carrier to provide a liquid mixture of a resin and a carrier, (b) heating said liquid mixture to an elevated temperature to cause the resin to swell by virtue of carrier absorption into the resin to provide a swelled resin in said liquid mixture, and (c) adding a biocide to said swelled resin and mixing to provide a homogeneous, storage-stable liquid dispersion.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: June 17, 1997
    Assignee: Olin Corporation
    Inventors: Bruce Beardsley Anderson, Rahim Hani
  • Patent number: 5637642
    Abstract: This invention involved the discovery of novel polymers used as adhesives and a process for their preparation. The polymers were prepared by the nucleophilic substitution, at room temperature, of PVC with substituted alkyltrialkoxysilanes, which can be cured at room temperature to give adhesion of PVC to hydrophilic substrates. These polymers are particularly useful as adhesion promoters in ion-selective electrodes. The invention also involved the application of these adhesive primers to planar electrode substrates to give greatly improved performance in the response of ion-selective electrodes.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: June 10, 1997
    Assignee: Chiron Diagnostics Corporation
    Inventors: Mark W. Boden, Andy D. C. Chan, Susan M. Degnan, Stephen B. Ruiz
  • Patent number: 5637628
    Abstract: A dental impression-taking silicone composition is provided, which comprises A) 100 parts by weight of an organopolysiloxane having at least two aliphatic unsaturated groups per molecule, B) 0.1 to 30 parts by weight of an organohydrogenpoly-siloxane having per molecule at least three hydrogen atoms directly bonded to a silicone atom, C) 10 to 500 ppm of a silicone-soluble platinum compound, as calculated on the basis of the total amount of A) and B), D) 5 to 500 parts by weight of an inorganic filler, and E) 1 to 200 parts by weight of a polyvinyl ether having a polymerization degree of 1,000 to 50,000. This composition provides a paste mixture having an increased strain in compression after curing and a reduced permanent deformation after curing and unlikely to run down during impression-taking. Upon cured, oil matter does not bleed out of the surface of the cured mixture.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: June 10, 1997
    Assignee: GC Corporation
    Inventors: Hiroshi Kamohara, Shunichi Futami
  • Patent number: 5637668
    Abstract: A process for manufacturing high molecular weight polysiloxane copolymers by interfacial polymerization. The polysiloxanes may contain phenylmethyl siloxane blocks and dimethyl siloxane blocks, alternately polymerized together to form an (A.sub.m B.sub.n).sub.x type copolymer. The interfacial polymerization process is fast, proceeds smoothly at room temperature, and is not reversible, i.e., no cyclic siloxane species are generated. The polysiloxanes can be formed as thermoplastic elastomers suitable for use as sealants, fillers, and films.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: June 10, 1997
    Assignees: Dow Corning Corporation, University of South Australia
    Inventors: Daniel Graiver, Arnold W. Lomas, Jani G. Matisons, Arthur Provatas
  • Patent number: 5635578
    Abstract: A primer composition containing (A) an organosilicon compound having a fluorine-containing organic group and having hydrogensilyl groups at both the terminals of the molecule and (B) a platinum group metal catalyst, and a method of modifying the surface of silicone rubber by using such a primer composition. This primer composition enables firm adhesion between a silicone rubber and a curable liquid fluorine rubber.
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: June 3, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Hitoshi Kinami, Yasushi Yamamoto
  • Patent number: 5633314
    Abstract: An aqueous aerosol coating composition, which includes a thermoplastic acrylic polymer solubilized in an aqueous solution of a monohydric alcohol. The coating composition may further be blended with a controlling amount of a water soluble or water reducible acrylic polymer for imparting a desired degree of gloss and alkali resistance to a coating made from the aqueous aerosol coating composition. The compositions of this invention provide for improved drying rates, hardness and alkali resistance over current aqueous systems.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: May 27, 1997
    Assignee: Rohm and Haas Company
    Inventor: Homayoun Jamasbi
  • Patent number: 5633332
    Abstract: Polymers can be obtained by free-radical polymerization of monomers in the presence of a dissolved polysiloxane. The free-radical-polymerizable monomers used are at least one compound of the formula I ##STR1## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen, COOH, C.sub.1 -C.sub.18 -alkyl, cyclohexyl, C.sub.1 -C.sub.4 -alkyl-cyclohexyl, C.sub.6 -C.sub.10 -bicycloalkyl, C.sub.6 -C.sub.18 -tricycloalkyl,R.sup.3 is hydrogen or methyl,R.sup.4 is hydrogen, (C.sub.1 -C.sub.20)-alkyl, 2-hydroxypropyl, glycidyl,--[CH.sub.2 CH.sub.2 --O].sub.n H, having n=1 to 5,--[CH.sub.2 ].sub.m --OH, having m=3 to 18, in particular m=3 to 8,--[CH.sub.2 ].sub.2 O--[CO--(CH.sub.2).sub.5 ].sub.x OH, where x=a number from 1 to 3, or--[CH.sub.2 CHOHCH.sub.2 ]--O--(CO)R,where R is a C.sub.1 to C.sub.18 -alkyl radical.The polysiloxane used is at least one aromatic polyarylene siloxane of the formula III ##STR2## where R.sup.9 and R.sup.10 are, independently of one another, a C.sub.1 -C.sub.12 -alkyl radical, a C.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: May 27, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Horst-Tore Land, Walter Schubert, Reinhardt Kalus
  • Patent number: 5631321
    Abstract: The present invention provides a sealing component for connector waterproofing having an excellent heat resistance, low-temperature resistance and oil resistance which can be economically produced in a reduced molding time. A novel sealing component for connector waterproofing is provided, which comprises a vulcanized composition comprising at least (a) 100 parts by weight of an organopolysiloxane represented by the following average composition formula (I), (b) from 5 to 500 parts by weight of a finely divided silica filler, (c) from 0.01 to 5 parts by weight of a dialkyl peroxide or peroxy ketal which has a half-life of 1 hour at a temperature of from 130.degree. C. to 150.degree. C., (d) from 0.1 to 5 parts by weight of a silicon compound having two or more Si--H bonds per molecule, and (e) from 0.01 to 2 parts by weight of an organic peroxide represented by the following general formula (II):R.sup.1.sub.m SiO.sub.(4-m)/2 (I)wherein R.sup.
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: May 20, 1997
    Assignees: Yazaki Corporation, Shin-Etsu Chemical Co., Ltd.
    Inventors: Kiyotaka Okazaki, Masahiro Kanda
  • Patent number: 5631338
    Abstract: The present invention provides a process for preparing bisphenol A with a high conversion and selectivity by reacting phenol with acetone in the presence of both a polyorganosiloxane having a mercapto group-containing hydrocarbon group and an acid. It is preferable that the polyorganosiloxane having a mercapto group-containing hydrocarbon group and the acid is a polyorganosiloxane having both a mercapto group-containing hydrocarbon group and a sulfonic acid group.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: May 20, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kaoru Inoue, Tuneyuki Ohkubo, Takashi Terajima
  • Patent number: 5629388
    Abstract: A process for producing a polydiorganosiloxane based graft copolymer is provided. The process involves producing an emulsion of crosslinked polydiorganosiloxane by admixing dihydroxyfunctional polydiorganosiloxane, an emulsifying agent, and water; polymerizing the polydiorganosiloxane in the presence of an acid catalyst, a cross linking agent and a grafting agent to form silicone rubber particles having functional sites, and graft polymerizing a vinyl functional monomer onto the resulting silicone particles. The process provides several advantages in a rubber particle size control thereby resulting in better control of the properties of the resulting graft copolymer.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: May 13, 1997
    Assignee: General Electric Company
    Inventors: Kenneth G. Himelrick, Kevin R. Kidder, Vijaya K. Kuruganti, Hrong-Roang Sheu
  • Patent number: 5627241
    Abstract: A method of making an organopolysiloxane sheet or tube polymer involves contacting a sheet or tube silicate with an organo-H-chlorosilane to form an organosiloxane sheet or tube polymer with pendent .tbd.Si--H groups. Subsequently, the organosiloxane sheet or tube polymer with pendent .tbd.Si--H groups is contacted with an alkenyl group containing compound in the presence of a hydrosilation catalyst. The catalyst is used in an amount effective to catalyze a hydrosilation reaction between the alkenyl group on the alkenyl group containing compound and the hydride functionality on the organosiloxane sheet or tube polymer with pendent .tbd.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 6, 1997
    Assignees: Dow Corning Corporation, Case Western University
    Inventors: Chenggang Chen, Dimitris E. Katsoulis, Malcolm E. Kenney
  • Patent number: 5625024
    Abstract: The present invention relates to novel polysiloxane-polyether-based copolymers which contain T units and comprise randomly linked organopolysiloxane units and linear polyether units, to a method for their preparation and their use.
    Type: Grant
    Filed: March 23, 1995
    Date of Patent: April 29, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Sabine Schlitte, Hubertus Eversheim, Gebhard Wagner, Karl-Heinz K asler, Jan Mazanek, Hans-Ulrich Meier-Westhues
  • Patent number: 5625011
    Abstract: The invention relates to molecular composites including a rigid reinforcing thermoplastic polymer dispersed on a molecular scale in a flexible organosiloxane/thermoplastic polymer copolymer, to a process for the preparation of the said composites and to a material with a surface enriched in siloxane, obtained from the said molecular siloxane composites, and to the uses of said composites and of the said material, in particular for aerospace construction.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: April 29, 1997
    Assignee: Agence Spatiale Europeenne
    Inventor: Sanjay Palsule
  • Patent number: 5625025
    Abstract: The present invention relates to a silicone composition comprising a mixture of (A) an amino-functional diorganopolysiloxane oil free of phenol groups and having at least 1 amino group per molecule and (B) a diorganopolysiloxane oil free of amino groups and having at least 1 phenol group per molecule. The silicone composition has a viscosity of from 10 to 100,000 mm.sup.2 /s at 25.degree. C. and an average phenol equivalent weight of 10,000 to 5,000,000. The silicone compositions of the present invention are highly heat-resistant, exhibit excellent release properties, and superior lubrication properties.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: April 29, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hiroki Ishikawa, Tsutomu Naganawa, Isao Ona
  • Patent number: 5624985
    Abstract: A novel method for putting silicone onto polycarbonate is disclosed comprising preparing a mixture of a silicone, a polycarbonate and a solvent, heating the mixture to reflux and recovering the solid powdery residue.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: April 29, 1997
    Assignee: General Electric Company
    Inventors: Michael A. Lucarelli, William J. Raleigh, Kimberlie A. Schryer
  • Patent number: 5621042
    Abstract: Coating compositions are described. They contain, as a film-forming component, a fluoropolymer with a silane-coupling agent containing at least one free isocyanate group. The fluoropolymer may also have been modified with a reaction product of a polysiloxane or fluorine compound containing a reactive organic functional group with an organic polyisocyanate, which reaction product contains at least one free isocyanate group.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: April 15, 1997
    Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Colour & Chemicals Mfg, Co., Ltd.
    Inventors: Kazuyuki Hanada, Setsuo Hirose, Katsumi Kuriyama