Abstract: Process for removal of salts thermally non-regenerable in a temperature range from 0° C. to 200° C., from organic solvents in an aqueous solution by evaporation, the normal boiling point of organic solvents being higher than that of water, and by enriching the organic constituents existing in the solvent as well as the heat stable salts existing therein in a liquid phase forming by evaporation of water and a portion of the organic constituents of a first vessel, and discharging an evolving vaporous phase from the first vessel.
Abstract: There is provided a process, and a device, for the treatment of crude oil, component(s) of crude, or mixtures thereof, to convert components of said hydrocarbon liquid to products having boiling points that are lower than the boiling points of said components prior to treatment. The process comprises subjecting crude to be treated to ultrasound vibrations and to an electromagnetic field emitted by a an electromagnetic field generator; wherein the electromagnetic field emitted by said electromagnetic field generator comprises a component of electromagnetic field modulated by an electromagnetic field emitted from the crude to be treated on the exposure thereof to ultrasound vibrations.
Abstract: Alumina/NiO/ZnO and Alumina/ZnO are synthesized via a novel modified hydrothermal method and investigated for the desulfurization activities. Sulfur compounds such as thiophene, benzothiophene (BT) and dibenzothiophene (DBT) are tested for their removal from model diesel fuel. The prepared composite materials were examined by the means of N2-adsorption, X-ray diffraction and Fourier transform infrared spectroscopy.
Type:
Grant
Filed:
December 30, 2013
Date of Patent:
August 23, 2016
Assignees:
King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and Technology
Inventors:
Khalid R. Alhooshani, Abdullah A. Al Swat, Tawfik A. Saleh, Mohammad N. Siddiqui, Mohammed A. Gondal
Abstract: A process and apparatus for recovering cycle oil from FCC CSO is described. By feeding the additional cycle oil to a hydrocracking unit additional diesel, naphtha and petrochemical feedstock may be obtained. The additional cycle oil is obtained by vacuum separation of the CSO. The described process and apparatus can provide additional recovery for a refiner.
Type:
Grant
Filed:
April 9, 2014
Date of Patent:
August 23, 2016
Assignee:
UOP LLC
Inventors:
Jibreel A. Qafisheh, Jill A. Bonucci, Xin X. Zhu, Boyd E. Cabanaw
Abstract: A distillation system and process for separating a multi-component feed mixture in a distillation system comprising a first distillation column having a first fired reboiler, and at least a second distillation column having a second heat-exchange reboiler, comprising the steps of a) introducing the feed mixture to the first column, and separating into at least a first top and a first bottom product; b) taking part of the first bottom product for providing heat to the second reboiler as a utility stream; and c) feeding part of said utility stream after heat-exchange as main feed to the second column for further separation. This process allows significant energy savings, by reduction of the amount of external heat required for the fired reboiler and omission of a conventionally used heat-exchanger.
Abstract: A process for producing a gas oil fraction by hydrodesulfurizing a feedstock oil prepared by blending a straight-run gas oil and a light cycle oil, wherein the process is capable of maintaining the activity of the desulfurization catalyst over a long period, and is capable of producing a low-sulfur gas oil fraction having a low sulfur content and excellent color index. The process for producing a low-sulfur gas oil fraction includes hydrodesulfurizing a feedstock oil to a sulfur content of not more than 10 ppm by mass, wherein the feedstock oil is prepared by blending a straight-run gas oil with a light cycle oil having a 10 volume % distillation temperature of less than 220° C. and a 90 volume % distillation temperature of less than 325° C., such that the blend proportion of the light cycle oil is not more than 30% by volume. Further, a low-sulfur gas oil is obtained by blending the low-sulfur gas oil fraction with a kerosene fraction.
Abstract: A gas-liquid catalyzed reaction is performed by introducing at least a portion of the reactive gas into the catalyst as a cross-flow or radial-flow stream. Introducing at least a portion of the reactive gas as a radial flow stream allows the reactive gas to travel through the catalyst bed along a shorter path length. This reduces the pressure drop for the radial flow portion of the gas. The reactive gas can be introduced into the catalyst bed at various heights relative to the height of the catalyst bed.
Type:
Grant
Filed:
June 25, 2013
Date of Patent:
August 16, 2016
Assignee:
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Abstract: A process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction using distillation and/or stripping treatment, a treatment with at least one inorganic base and a treatment with at least one organic base. This process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer-Tropsch plant for the production of hydrocarbons.
Type:
Grant
Filed:
December 16, 2009
Date of Patent:
August 2, 2016
Assignee:
ENI S.p.A.
Inventors:
Lino Carnelli, Roberta Miglio, Roberto Zennaro
Abstract: The present invention provides a geothermal based heat utilization system for just about preventing scaling of geothermal fluid in a heat exchanger, comprising a mixing unit upstream to a heat exchanger of said system and in which separated brine, steam condensate and non-condensable gas portions are mixed so as to just about reconstruct the geothermal fluid to just about equilibrium conditions such that dissolved solids are assured not to precipitate in the heat exchanger.
Abstract: Hydrocarbon-soluble molybdenum catalyst precursors include a plurality of molybdenum cations and a plurality of carboxylate anions having at least 8 carbon atoms. The carboxylate anions are alicyclic, aromatic, or branched, unsaturated and aliphatic, and can derived from carboxylic acids selected from 3-cyclopentylpropionic acid, cyclohexanebutyric acid, biphenyl-2-carboxylic acid, 4-heptylbenzoic acid, 5-phenylvaleric acid, geranic acid, 10-undecenoic acid, dodecanoic acid, and combinations thereof. The molybdenum salts have decomposition temperatures higher than 210° C. The catalyst precursors can form a hydroprocessing molybdenum sulfide catalyst in heavy oil feedstocks. Also disclosed are methods for making catalyst precursors and hydrocracking heavy oil using active catalysts.
Abstract: The present invention relates to the application of ionic liquids individually or in formulation to dry and desalt crudes oils having API gravities in the range of 8 to 20 (median, heavy and extra-heavy) when applied at concentrations ranging from 500 and up to 5000 ppm. The ionic liquids have a cation consisting of quaternary ammonium, wherein the substituents R, R1 and R2 are independent radicals represented by alkyl chains including 2 to 8 carbon atoms; and anion selected from the group consisting of ethylsulfate, methylsulfate and chloride.
Type:
Grant
Filed:
April 10, 2012
Date of Patent:
August 2, 2016
Assignee:
INSTITUTO MEXICANO DEL PETROLEO
Inventors:
Eugenio Alejandro Flores Oropeza, Laura Verónica Castro Sotelo, Alfonso López Ortega, José Gonzalo Hernández Cortez, Fernando Alvarez Ramírez, Flavio Salvador Vázquez Moreno, Arquímedes Estrada Martínez, Marcelo Lozada Y Cassou
Abstract: A startup method for a fractionator that is supplied with, and fractionally distills, a hydrocracked product obtained in a wax fraction hydrocracking step by hydrocracking a wax fraction contained within a Fischer-Tropsch synthetic oil, the method including a preheating step of preheating the fractionator using a hydrocarbon oil that includes at least a portion of the hydrocracked product and is liquid at a normal temperature and normal pressure.
Type:
Grant
Filed:
March 15, 2011
Date of Patent:
August 2, 2016
Assignees:
JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, JX NIPPON OIL & ENERGY CORPORATION, JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., NIPPON STEEL ENGINEERING CO., LTD.
Abstract: A process and apparatus for recovering cycle oil from FCC CSO is described. By feeding the additional cycle oil to a hydrocracking unit additional diesel, naphtha and petrochemical feedstock may be obtained. The additional cycle oil is obtained by vacuum separation of the CSO. The described process and apparatus can provide additional recovery for a refiner.
Type:
Grant
Filed:
April 9, 2014
Date of Patent:
July 26, 2016
Assignee:
UOP LLC
Inventors:
Jibreel A. Qafisheh, Jill A. Bonucci, Xin X. Zhu, Boyd E. Cabanaw
Abstract: The desalination system is a multi-stage flash desalination (MSF) system. Each stage has a P-shaped chamber having a flashing section extending vertically, a condensing section extending horizontally to overlay the flashing section of the next succeeding stage, and a demister (a device to separate liquid droplets entrained in vapor) separating the flashing section and the condensing section. One or more heat pipes extend between the condensing section of each stage and the flashing section of the next succeeding stage in order to transfer heat released by the condensing vapor in one section to the colder flashing section of the next succeeding chamber. The system includes a seawater-cooled condenser in the last stage to recover fresh water from the water vapor. The system may be modified by replacing or supplementing the condenser in the last stage with a thermal vapor compressor (TVC) to transfer vapor to the first stage.
Type:
Grant
Filed:
July 2, 2015
Date of Patent:
July 19, 2016
Assignee:
KING SAUD UNIVERSITY
Inventors:
Obida Mohamed Zeitoun, Hany Abdelrahman Alansary, Abdullah Othman Nuhait
Abstract: A process and apparatus for recovering cycle oil from FCC CSO is described. By feeding the additional cycle oil to a hydrocracking unit additional diesel, naphtha and petrochemical feedstock may be obtained. The additional cycle oil is obtained by vacuum separation of the CSO. The described process and apparatus can provide additional recovery for a refiner.
Type:
Grant
Filed:
April 9, 2014
Date of Patent:
July 19, 2016
Assignee:
UOP LLC
Inventors:
Jibreel A. Qafisheh, Boyd E. Cabanaw, Xin X. Zhu
Abstract: A method of improving the uniformity of the contacting of a heavy oil feed with FCC cracking catalyst in the feed zone of an FCC cracking riser in which the heavy oil feed is injected into the catalyst in the riser by means of feed injectors located around the riser, the method comprising minimizing the differences in the temperature profile in the oil/catalyst mixture across the feed zone by varying the oil feed rate to the injectors.
Type:
Grant
Filed:
April 11, 2013
Date of Patent:
July 19, 2016
Assignee:
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventors:
Bing Du, Alvin U. Chen, Christopher G. Smalley, Kentaro Kobayashi, Masaaki Sugita
Abstract: Methods are provided for producing multiple lubricating oil basestocks from a feedstock. Prior to dewaxing, various fractions of the feedstock are exposed to hydrocracking conditions of different severity to produce a higher overall yield of basestocks. The hydrocracking conditions of different severity can represent exposing fractions of a feedstock to different processing conditions, exposing fractions of a feedstock to different amounts of hydrocracking catalyst, or a combination thereof.
Type:
Grant
Filed:
July 12, 2012
Date of Patent:
July 19, 2016
Assignee:
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventors:
Eric D. Joseck, Michael Brian Carroll, David Mentzer, Teck-Mui Hoo, Michel Daage, Ajit Bhaskar Dandekar
Abstract: An electric actuator is provided for operating an unheading valve of a coke drum. The electric actuator includes a driving element comprising a planetary roller screw for actuating the unheading valve. By using a planetary roller screw, rather than hydraulics for the driving element, the electric actuator of the present invention can be used in place of hydraulic actuators while still providing sufficient power and reliability for use with an unheading valves of a coke drum.
Abstract: The present invention concerns a plate for distributing a polyphase mixture in a reactor operating in trickle bed mode constituted by at least one gas phase and at least one liquid phase, the plate (10) being located above a bed of catalytic particles, comprising a plurality of chimneys (3), characterized in that a portion of the chimneys of the plate located near to the wall of the chamber of the reactor, those termed the peripheral chimneys, have an upper portion which is inclined at an angle with respect to the vertical. The invention also concerns the use of the plate in a reactor with a view to carrying out hydrotreatment, hydrogenation or oxidation reactions.