Patents Examined by Rip A. Lee
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Patent number: 11718693Abstract: The present invention provides an ethylene/alpha-olefin copolymer having narrow molecular weight distribution together with a low density and an ultra low molecular weight, having minimized number of unsaturated functional groups, and having uniform crystallinity, thereby showing excellent physical properties, and a method for preparing the same.Type: GrantFiled: May 3, 2019Date of Patent: August 8, 2023Inventors: Rae Keun Gwak, Seung Hwan Jung, Jin Sam Gong, Jung Ho Jun, Choong Hoon Lee, Eun Jung Lee, Hyun Jin Ju, In Sung Park, Sang Eun Park
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Patent number: 11718635Abstract: The present disclosure related to iron-containing compounds including a 2,6-diiminoaryl ligand and one or more substituted hydrocarbyl substituents. Catalysts, catalyst systems, and processes of the present disclosure can provide polyolefins with high or low molecular weight, low comonomer content, narrow polydispersity indices, and broad orthogonal composition distribution. The present disclosure provides new and improved iron-containing catalysts with enhanced solubility in hydrophobic (nonpolar) solvents.Type: GrantFiled: December 11, 2020Date of Patent: August 8, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Matthew W. Holtcamp, Robert L. Halbach, Subramaniam Kuppuswamy, Matthew S. Bedoya
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Patent number: 11712678Abstract: The present invention relates to a method for preparing superabsorbent polymer. The method for preparing superabsorbent polymer according to the present invention enables providing superabsorbent polymer having excellent absorption ratio, absorption speed and permeability.Type: GrantFiled: December 26, 2017Date of Patent: August 1, 2023Inventors: Dong Hyun Kim, Tae Bin Ahn, Jun Wye Lee, Chang Sun Han
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Patent number: 11708429Abstract: Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems.Type: GrantFiled: July 29, 2019Date of Patent: July 25, 2023Assignee: Dow Global Technologies LLCInventor: Bryan D. Stubbert
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Patent number: 11708431Abstract: The invention relates to a polymer composition comprising a polyethylene and a crosslinking agent, wherein the polymer composition contains a total amount of vinyl groups which is B vinyl groups per 1000 carbon atoms, and B1?B, wherein B1 is 0.88, when measured prior to crosslinking according to method ASTM D624898; and wherein the crosslinking agent is present in an amount which Z wt %, based on the total amount (100 wt %) of the polymer composition, and Z?Z2, wherein Z2 is 0.60, an article being e.g. a cable, e.g. a power cable, and processes for producing a polymer composition and an article; useful in different end applications, such as wire and cable (W&C) applications.Type: GrantFiled: December 18, 2018Date of Patent: July 25, 2023Assignee: BOREALIS AGInventors: Villgot Englund, Virginie Eriksson, Daniel Nilsson, Annika Smedberg
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Patent number: 11708434Abstract: This disclosure describes polymerization processes and processes for quenching polymerization reactions using reactive particulates, such as amorphous silica, as quenching agents, typically in solution or bulk polymerization processes.Type: GrantFiled: May 24, 2021Date of Patent: July 25, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jay L. Reimers, Yifeng Hong, John R. Hagadorn
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Patent number: 11702535Abstract: Provided herein are polymer compositions comprising a polymer and polymer processing aid (PPA) comprising a blend of at least two of: (i) a polyethylene glycol; (ii) a surfactant comprising a sorbitan ester or a polysorbate; and (iii) a metal salt of a fatty acid. The polymer can be a C2-C6 olefin homopolymer or a copolymer of two or more C2-C20 ?-olefins, and the polymer composition can take the form of polymer pellets; a polymer melt; reactor-grade polymer granules and/or polymer slurries; or other form of polymer composition containing the PPA and optionally one or more other additives. The polymer composition is preferably free or substantially free of fluorine, including fluoropolymer-based PPAs.Type: GrantFiled: September 23, 2022Date of Patent: July 18, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Nino Ruocco, Michael A. Leaf, Danny Van Hoyweghen
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Patent number: 11702489Abstract: A method capable of stably performing continuous production of a propylene polymer with high productivity while reducing generation of agglomerates is described. In the method, a monomer(s) containing propylene is/are (co)polymerized in a presence of an olefin polymerization catalyst with a polymerization system containing two or more gas phase polymerization reactors or a polymerization system containing a liquid phase polymerization reactor(s) and a gas phase polymerization reactor(s) such that that the total number of liquid phase polymerization reactor(s) and gas phase polymerization reactor(s) is three or more. In at least one gas phase polymerization reactor, an average retention time ?G [hour] in the gas phase polymerization, an average particle diameter Dpi [?m] of fed powder, and a total amount Co [wt %] of an ethylene-derived structural unit and C4-C12 ?-olefin-derived structural units in a polymer in discharged powder are in a predetermined relationship.Type: GrantFiled: February 8, 2021Date of Patent: July 18, 2023Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Takayuki Mitani
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Patent number: 11697698Abstract: The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.Type: GrantFiled: March 7, 2019Date of Patent: July 11, 2023Assignees: THE UNIVERSITY OF TOKYO, SHOWA DENKO K.K., JAPAN POLYETHYLENE CORPORATIONInventors: Kyoko Nozaki, Shingo Ito, Junichi Kuroda, Yoshikuni Okumura, Shinya Hayashi, Minoru Kobayashi, Yuichiro Yasukawa
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Patent number: 11685798Abstract: In various embodiments, a polyethylene formulation has a density of greater than 0.940 g/cm3 when measured according to ASTM D792, and a high load melt index (I21) of 1.0 g/10 min to 10.0 g/10 min when measured according to ASTM D1238 at 190° C. and a 21.6 kg load. Moreover, the polyethylene formulation has a peak molecular weight (Mp(GPC)) of less than 50,000 g/mol, a number average molecular weight (Mn(GPC)) of less than 30,000 g/mol, and a weight fraction (w1) of molecular weight (MW) less than 10,000 g/mol of less than or equal to 10.5 wt %, as determined by Gel Permeation Chromatography (GPC). Articles made from the polyethylene formulation, such as articles made by blow molding processes are also provided.Type: GrantFiled: July 18, 2019Date of Patent: June 27, 2023Assignee: Dow Global Technologies LLCInventors: Peter S. Martin, Yijian Lin, Angela I. Padilla-Acevedo, Roger L. Kuhlman, Shadid Askar, Mridula Kapur, Todd A. Hogan, Joel D. Wieliczko, Chuan C. He
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Patent number: 11680120Abstract: Embodiments of a method for producing a multimodal ethylene-based polymer having a first, second, and third ethylene-based component, wherein the multimodal ethylene based polymer results when ethylene monomer, at least one C3-C12 comonomer, solvent, and optionally hydrogen pass through a first solution, and subsequently, a second solution polymerization reactor. The first solution polymerization reactor or the second solution polymerization reactor receives both a first catalyst and a second catalyst, and a third catalyst passes through either the first or second solution polymerization reactors where the first and second catalysts are not already present. Each ethylene-based component is a polymerized reaction product of ethylene monomer and C3-C12 comonomer catalyzed by one of the three catalysts.Type: GrantFiled: December 19, 2018Date of Patent: June 20, 2023Assignee: Dow Global Technologies LLCInventors: Alec Y. Wang, Johnathan E. DeLorbe, Joshua B. Gaubert, Sarat Munjal, Mehmet Demirors, Yijian Lin
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Patent number: 11680118Abstract: New C2C3 random copolymer composition, which shows improved sealing behaviour due to low sealing initiation temperature (SIT) and high hot tack force. In addition, the inventive composition shows an excellent sterilization behaviour, i.e. retention of low haze level after sterilization. The present invention is furthermore related to the manufacture of said copolymer composition and to its use.Type: GrantFiled: June 25, 2019Date of Patent: June 20, 2023Assignee: Borealis AGInventors: Jingbo Wang, Markus Gahleitner, Klaus Bernreitner, Pauli Leskinen, Cornelia Tranninger
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Patent number: 11680119Abstract: Embodiments of a method of producing a multimodal ethylene-based polymer comprising a first catalyst and a second catalyst in a first solution polymerization reactor and a third catalyst in a second solution polymerization reactor.Type: GrantFiled: December 19, 2018Date of Patent: June 20, 2023Assignee: Dow Global Technologies LLCInventors: Daniela Ferrari, Alec Y. Wang, Pradeep Jain, Yijian Lin
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Patent number: 11680160Abstract: Disclosed are a polyolefin resin composition and a production method using same. The polyolefin resin satisfies the following conditions: (1) melt index (MI2.16, 190° C., under a load of 2.16 kg) is 0.1 to 1.5 g/10 min; (2) density is 0.91 to 0.93 g/cc; (3) polydispersity Index (Mw (weight-average molecular weight)/Mn (number-average molecular weight)) is 3 to 7; (4) Mz (Z-average molecular weight)/Mw (weight-average molecular weight) is 2.3 to 4.5; and (5) COI(Comonomer Orthogonal Index) value calculated by Equation 1 in the specification is 5 to 12. In Equation 1, “SCB number at Mz” represents average number of branches derived from comonomers per 1000 carbon atoms at Z-average molecular weight (Mz), and “SCB number at Mn” represents average number of branches derived from comonomers per 1000 carbon atoms at number-average molecular weight (Mn) based on a molecular weight-comonomer distribution graph.Type: GrantFiled: April 2, 2019Date of Patent: June 20, 2023Assignee: DL CHEMICAL CO., LTD.Inventors: Jang Woo Lee, Byung Keel Sohn, Sah Mun Hong, Da Jung Kim, Hee Jun Lee, Sung Ho Choi, Su Hyun Park
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Patent number: 11680159Abstract: Microporous polymer films and methods of making same are disclosed. The microporous polymer film comprises: one or more polypropylene copolymer, said polypropylene copolymer comprising one or more polypropylene homopolymer chain segments and one or more ethylene-containing copolymer chain segments; wherein the microporous polymer film comprises: (i) polypropylene homopolymer chain segments in total amount of from 50-82 wt. %, based on the weight of the microporous polymer film; (ii) one or more ethylene-containing copolymer chain segments in total amount of from 18-50 wt. %, based on the weight of the microporous polymer film, wherein at least a portion of the ethylene-containing copolymer chain segments comprises polymerized units of ethylene in an amount of at least 45 wt. %, based on the weight of the ethylene-containing copolymer chain segments.Type: GrantFiled: September 16, 2020Date of Patent: June 20, 2023Assignee: DDP SPECIALTY ELECTRONIC MATERIALS US, LLCInventors: Wenyi Huang, Mark Alan Barger, Gary D. Parsons, Ioannis V. Bletsos
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Patent number: 11667731Abstract: Embodiments in accordance with the present invention encompass compositions comprising a long shelf stabilized organopalladium compound of formula (I) as described herein. The composition further contains a photoacid generator, a photosensitizer and one or more olefinic monomers as described herein. The shelf life of the compositions can further be extended by employing a stabilizer, such as for example, a hindered amine. The composition undergoes vinyl addition polymerization when it is exposed to a suitable actinic radiation to form a substantially transparent film or a three dimensional object. More specifically, the compositions of this invention are stable at room temperature for several days to several months and can also be stored at higher temperatures from about 40° C. to 60° C. for several days and undergo mass polymerization only when subjected to suitable actinic radiation.Type: GrantFiled: June 30, 2022Date of Patent: June 6, 2023Assignee: PROMERUS, LLCInventors: Shun Hayakawa, Guodong Deng, Larry F Rhodes
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Patent number: 11667776Abstract: The present disclosure provides a fiber and fabrics made therefrom. In an embodiment, a fiber is provided and includes an odor control composition. The odor control composition includes (A) from 85 wt % to 99.5 wt % of an olefin-based polymer and (B) from 15 wt % to 0.5 wt % of an odor suppressant. The odor suppressant includes: (i) an ionomer, (ii) particles of zinc oxide, and (iii) particles of copper oxide.Type: GrantFiled: August 26, 2019Date of Patent: June 6, 2023Assignee: Dow Global Technologies LLCInventors: Scott T. Matteucci, Jeffrey E. Bonekamp, Arkady L. Krasovskiy, Kefu Sun, Keran Lu, Ronald Wevers
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Patent number: 11661501Abstract: Bimodal high-density polyethylene polymer compositions with increased high melt strength and good processability. The compositions comprise a base resin having a density of about 945 kg/m3 to about 955 kg/m3, and an ethylene polymer (A) having a density of at least about 968 kg/m3, in an amount ranging from 45% to 55% by weight and an ethylene polymer (B) having a density lower than the density of polymer (A). The composition has a complex viscosity at a shear rate of 0.01 rad/s ranging from about 200 to 450 kPa·s and a complex viscosity at a shear rate of 100 rad/s ranging from about 1900 to 2500 Pa·s. Articles made from these compositions, such as pipes and fittings achieve long-term oxidative resistance and have a low wall thickness variability while maintaining high production output.Type: GrantFiled: September 28, 2020Date of Patent: May 30, 2023Assignee: INEOS OLEFINS & POLYMERS USA, A DIVISION OF INEOS USA LLCInventors: Joshua Allen Cottle, Mark Anthony Gessner, Robert Ernest Sander, Luc Dheur
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Patent number: 11655408Abstract: The present invention provides a composition comprising a) a phase change material; b) 1 to 10 wt % of a silica gelling additive; and c) a styrene co-polymer gelling additive; wherein the composition is in the form of a gel and wherein the weight ratio of b) silica gelling additive to c) styrene co-polymer gelling additive in the composition is in the range from 0.6 to 5:1. The invention also provides a method of making the composition and an article and a product comprising the composition. Finally, the invention provides the use of a combination of a silica gelling additive and a styrene co-polymer gelling additive to make a gel composition comprising a phase change material with one or more improved properties.Type: GrantFiled: September 18, 2018Date of Patent: May 23, 2023Assignee: CRODA INTERNATIONAL PLCInventors: Altug Altay, Marco Maria Auerbach
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Patent number: 11649305Abstract: A unimodal ethylene-co-1-hexene copolymer that, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by combination of melt elasticity and complex viscosity ratio (shear thinning)properties. A blown film consisting essentially of the unimodal ethylene-co-1-hexene copolymer. A method of synthesizing the unimodal ethylene-co-1-hexene copolymer. A method of making the blown film. A manufactured article comprising the unimodal ethylene-co-1-hexene copolymer.Type: GrantFiled: July 29, 2019Date of Patent: May 16, 2023Assignee: Univation Technologies, LLCInventors: Bo Liu, Yi Zhang, Ayush A. Bafna, François Alexandre, Robert N. Reib