Patents Examined by Sam Silverberg
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Patent number: 5738947Abstract: Disclosed is a corrosion-resistant film for protecting the surfaces of Ag, which comprises an Ag--Mg alloy having an Mg content of from 1 to 10 atomic % and which is applied to an Ag substrate. Also disclosed is a corrosion-resistant composite structure composed of an Ag substrate and a protective film of an Ag--Mg alloy with an Mg content of from 1 to 10 atomic % formed on the surface of the Ag substrate. The corrosion-resistant film protects an Ag with a silver-white gloss from being blackened by sulfide components, etc. The adhesiveness between the film and the Ag substrate is good. The composite structure has a high reflectivity and is useful as a reflective film for photo-magnetic recording media, optical recording media, reflectors, illuminators, etc. The surface of the corrosion-resisting film is oxidized to form an MgO layer on the film, and the film exhibits a high protecting effect.Type: GrantFiled: February 8, 1996Date of Patent: April 14, 1998Assignee: Mitsubishi Materials CorporationInventors: Kenichi Hijikata, Rie Mori
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Patent number: 5735971Abstract: Flawless nitrating layers are obtained during the nitro-carburizing of components made from steels which form passive layers in salt baths if these components are first pre-treated in an oxidizing salt melt at 300.degree. to 500.degree. C. prior to the nitro-carburizing process.Type: GrantFiled: November 28, 1995Date of Patent: April 7, 1998Assignee: Durferrit GmbH ThermotechnikInventors: Georg Wahl, Rainer Willing-Lepenies
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Patent number: 5736086Abstract: Disclosed is a process for forming a layered structure of metal sheet and polyester by heating the metal sheet, extrusion coating a thin layer of polyester on at least one side of the metal sheet, passing the coated sheet through nip rolls and optionally quenching the coated sheet to ensure the polyester coating(s) is in an amorphous state.Type: GrantFiled: March 29, 1996Date of Patent: April 7, 1998Assignee: Eastman Chemical CompanyInventors: Allan S. Jones, Richard L. McConnell, James W. Mercer, Jr.
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Patent number: 5735972Abstract: A black chromate-treatment solution for Zn-Ni alloy plated film comprises 1 to 100 g/l of hexavalent chromium, 1 to 100 g/l of hydrochloric acid residues and/or sulfuric acid residues, 1 to 100 g/l of nitric acid residues and 1 to 100 g/l of at least one metal selected from the group consisting of iron, nickel, cobalt and copper. The chromate-treatment solution permits the formation of a uniform black chromate conversion film on a Zn-Ni alloy plated film having an Ni content ranging from 8 to 20% by weight without using any silver ions in a substantial amount and the resulting black film is excellent in corrosion resistance.Type: GrantFiled: June 28, 1996Date of Patent: April 7, 1998Assignee: Dipsol Chemicals Co., Ltd.Inventors: Seiji Kishikawa, Takashi Yamamoto
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Patent number: 5733386Abstract: A highly corrosion-resistant, paint-adherent, and lubricating polymer-containing coating on a metal surface can be formed by contact with an aqueous solution (pH=2.0 to 6.5) that contains an acidic compound and polymer with the following formula (I): ##STR1## in which the X bonded to the phenyl ring in formula (I) represents a hydrogen atom, a hydroxyl group, a C.sub.1 to C.sub.5 alkyl group, a C.sub.1 to C.sub.5 hydroxyalkyl group, a C.sub.6 to C.sub.12 aryl group, a benzil group, a benzal group, an unsaturated hydrocarbon moiety condensed to the phenyl ring so as to form a naphthalene ring, or a group corresponding to formula (II): ##STR2## in which R.sup.1 and R.sup.2 in formula (II) each independently represent a hydrogen atom, a hydroxyl group, a C.sub.1 to C.sub.10 alkyl group, or a C.sub.1 to C.sub.10 hydroxyalkyl group; the Y.sup.1 and Y.sup.Type: GrantFiled: October 15, 1996Date of Patent: March 31, 1998Assignee: Henkel CorporationInventors: Masayuki Yoshida, Shigeo Tanaka, Kazutomo Miyafuji
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Patent number: 5730809Abstract: A passivate for tungsten alloy electroplates. The passivate includes an effective quantity of CrO.sub.3 in an aqueous bath having a pH of from about 3.5 to about 7.5.Type: GrantFiled: November 9, 1994Date of Patent: March 24, 1998Assignee: Enthone-OMI, Inc.Inventor: Robert Tremmel
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Patent number: 5728233Abstract: A highly uniform thin protective coating, with good appearance, anti-corrosion properties and adhesion properties, is provided by a surface treatment method wherein a surface treatment solution for aluminum and its alloys is prepared using a surface treatment composition for aluminum and its alloys comprising at least one type of phosphoric acid, condensed phosphoric acid or salt of these acids, at least one type of zirconium salt or titanium salt and effective fluoride, further comprising at least one type of phosphorous acid, hypophosphorous acid or salts of these acids, and this solution is brought in contact with the surface of an aluminum type metal.Type: GrantFiled: November 18, 1996Date of Patent: March 17, 1998Assignee: Nippon Paint Co., Ltd.Inventors: Satoshi Ikeda, Masayuki Kamimura
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Patent number: 5728234Abstract: A surface of aluminiferous metal is brought into contact at 30.degree. C. to 65.degree. C. for 5 to 60 seconds with a surface treatment bath with a pH of 2.0 to 6.5 that contains phosphate ion, condensed phosphate ion, and a water soluble polymer in the following weight proportions: 1-30: 0.1-10: 0.2-20. This is followed by a water rinse and drying by heating. The water soluble polymer has a chemical structure conforming with formula (I): ##STR1## in which (i) each of X.sup.1 and X.sup.2 represents a hydrogen atom, a C.sub.1 to C.sub.5 alkyl group, or a C.sub.1 to C.sub.5 hydroxyalkyl group; (ii) each of Y.sup.1 and Y.sup.2 represents a hydrogen atom or a moiety "Z" that conforms to formula (II) or (III): ##STR2## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 represents a C.sub.1 to C.sub.10 alkyl group or a C.sub.1 to C.sub.10 hydroxyalkyl group; (iii) the average value for the number of Z moieties substituted on each phenyl ring in the polymer molecule is from 0.2 to 1.Type: GrantFiled: October 15, 1996Date of Patent: March 17, 1998Assignee: Henkel CorporationInventors: Tomoyuki Aoki, Masayuki Yoshida
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Patent number: 5728236Abstract: A chemically derived product that rusts metal instantly upon contacting the surface of a metal and which can be easily and safely used by ornamental metal craftpersons. The chemically derived product is a liquid compound that contains the following constituents: (a) 93.0% by weight of water; (b) up to 5.0% by weight of a copper salt, the copper salt being selected from a copper salt group consisting of copper sulfate, copper nitrate, and copper chloride; and (c) a remaining amount consisting of an acid compound selected from an acid compound group consisting of sulfamic acid, oxalic acid, hydrochloric acid and nitric acid. The liquid compound can be particularly formulated for oxidizing steel or copper and may be produced having a predetermined coloring dye constituent selected from a color dye group consisting of copper, auburn, or gold, if oxidizing steel, or a color dye selected from a color dye group consisting of patina, aqua blue, or green, if oxidizing copper.Type: GrantFiled: October 24, 1995Date of Patent: March 17, 1998Assignee: Chem-ProInventor: Patrick A. Rundhaug
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Patent number: 5728235Abstract: An aqueous solution of manganese phosphate and phosphoric acid, preferably with little or no content of any material conventionally recognized as an accelerator or of any divalent metal ions other than manganese and iron, forms a good quality paint undercoating phosphate conversion coating on metal substrates, particularly on steel and galvanized steel substrates, when contacted by spraying or immersion with the substrates at a temperature of 54.degree.-65.degree. C. for a time of 0.5-5 minutes.Type: GrantFiled: November 12, 1996Date of Patent: March 17, 1998Assignee: Henkel CorporationInventors: Mervet S. Boulos, David C. Montrose, Michael Petschel
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Patent number: 5725683Abstract: A process for making an aluminum alloy lighting sheet product having a reflective surface protected by a UV-stable polymer coating. An aluminum alloy sheet is chemically brightened in an aqueous acidic solution, conversion coated, and then coated with a UV-stable polymer. Alternatively, an aluminum alloy sheet is chemically etched in an aqueous alkaline solution, conversion coated, and then coated with a UV-stable polymer. Preferably, the UV-stable polymer contains about 0.5-10 wt. % amorphous silica particles. In another embodiment, an aluminum alloy sheet surface is cleaned, chemically conversion coated and then coated with a coating composition containing a UV-stable polymer and 0.5-10 wt. % of about 0.5-5 microns.Type: GrantFiled: March 28, 1996Date of Patent: March 10, 1998Assignee: Aluminum Company of AmericaInventors: Daniel L. Serafin, Paul B. Schultz, Albert L. Askin, Paula Hinds, David A. Linde, Robert E. Bombalski
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Patent number: 5721303Abstract: Various organosulfur gold compounds and their use for the production of gold decorations are known. The invention relates to new organosulfur gold compounds, to a process for their production and to their use for the production of preparations for producing a gold decoration on firing-resistant substrates. The gold compounds according to the invention are obtainable from monogold (I) dimercaptosuccinic acid and compounds of similar structure by dissolution thereof in water in the presence of a base and precipitation by acidification and, if desired, repetition of the dissolving and precipitating steps. The gold compounds according to the invention are characterized by a gold content of 60 to 90% by weight, an atomic ratio of greater than 0.7 to 4. Preferred gold compounds are soluble in water and are suitable as a constituent of organic/aqueous and exclusively aqueous bright and burnished gold preparations for the decoration of glass, porcelain and ceramic.Type: GrantFiled: January 28, 1997Date of Patent: February 24, 1998Assignee: Cerdec Aktiengesellschaft Keramische FarbenInventors: Andreas Schulz, Marco Hofler
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Patent number: 5714016Abstract: A gear for wheel speed detection or sensor ring has a low cost and an excellent corrosion resistance. The sensor ring is mainly made of sintered stainless steel. A surface layer of the sensor ring contains at least 5 atomic % and not more than 25 atomic % of phosphorus, at least 30 atomic % and not more than 70 atomic % of oxygen, and at least 5 atomic % and not more than 50 atomic % of iron, and at least partially consists of an amorphous phase. The surface layer is formed by dipping a sintered stainless steel product in oil at a temperature of 15.degree. to 70.degree. C. containing phosphoric acid groups.Type: GrantFiled: May 25, 1994Date of Patent: February 3, 1998Assignee: Sumitomo Electric Industries, Ltd.Inventors: Hiroshi Ueda, Naoki Inui, Yoshinobu Takeda
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Patent number: 5711820Abstract: The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in as liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic.Type: GrantFiled: February 16, 1996Date of Patent: January 27, 1998Assignee: Allied Signal, Inc.Inventors: Henry M. Smith, George W. Bohnert, Ronald B. Olson, Thomas E. Hand
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Patent number: 5707465Abstract: A low temperature aluminum alloy or aluminum corrosion resistant coating has, as essential ingredients, water, 0% hexavalent chromium, an alkali metal permanganate providing at least 760 ppm permanganate, alkali metal or aluminum halide providing at least 100 ppm of halide, and a pH of from about 1.0 to about 4.0.Type: GrantFiled: October 24, 1996Date of Patent: January 13, 1998Assignee: Sanchem, Inc.Inventor: John W. Bibber
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Patent number: 5704994Abstract: A shaped object with a roughened surface is immersed in an aqueous solution of a metal salt and/or a solution of an organic metal. After the shaped object is dried, it is heated to form a metal-diffused layer in the shaped object and a ceramic surface layer on the shaped object. The ceramic surface layer has a large hardness, and is prevented from peeling off.Type: GrantFiled: October 27, 1995Date of Patent: January 6, 1998Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Mitsuo Kuwabara, Mitsuhiro Funaki, Kazuhito Hiraga, Tetsuya Ohishi
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Patent number: 5700523Abstract: A method for treating a metal surface involves contacting the metal surface with an aqueous silicate solution, contacting the silicate-coated metal surface with an aqueous organo-functional silane solution, and then contacting the silane-coated metal surface with a chrome-free pretreatment. Preferably, the bath containing the aqueous silicate solution also includes a cleaning agent for cleaning the metal surface. Alternatively, the metal surface may be cleaned in a separate step before the metal surface is contacted with the aqueous silicate solution and, optionally, the metal surface is rinsed with water after the metal surface is cleaned and before the metal surface is contacted with the aqueous silicate solution. The silicate-coated metal surface may be rinsed with water before it is contacted with an aqueous organo-functional silane solution. In addition, the silane-coated metal surface may be rinsed with water before it is contacted with a chrome-free pretreatment.Type: GrantFiled: June 3, 1996Date of Patent: December 23, 1997Assignee: Bulk Chemicals, Inc.Inventors: Anthony P. Petrole, Jose B. Rivera
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Patent number: 5700334Abstract: The rapid, low-temperature formation of a bright blue surface on hot-dip zinc/aluminum alloy-plated steel sheet that contains 0.1 to 60 weight % aluminum in the alloy, or on other surfaces of similar chemical composition, using conventional surface-treatment equipment, is achieved by treating the surface with a treatment bath that has a pH of 3.5 to 6.0 and that contains molybdenum compound at 0.2 to 3.0 weight % as molybdenum and simple or complex fluoride at 0.1 to 2.0 weight % as fluorine.Type: GrantFiled: November 28, 1995Date of Patent: December 23, 1997Assignee: Henkel CorporationInventors: Hitoshi Ishii, Takao Ogino
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Patent number: 5695571Abstract: The defluxing agent for flux residue after soldering contains an acid (preferably an organic acid, and particularly an acid stronger than abietic acid; for example, acrylic acid, acetic acid, propionic acid, benzoic acid) and an organic solvent (for example, xylene, benzyl acetate, methyl .alpha.-hydroxyisobutyrate, cyclohexanone, methyl .beta.-methoxyisobutyrate), and if necessary it further contains a monohydric alcohol, a surfactant and a corrosion inhibitor. Rinsing is preferably performed after the cleaning, using a solvent which is miscible with the defluxing agent, in order to completely remove the acid. There is also disclosed a cleaning apparatus which may be generally used for this and other cleaning.Type: GrantFiled: June 1, 1994Date of Patent: December 9, 1997Assignee: Fujitsu LimitedInventors: Keiji Watanabe, Masayuki Ochiai, Yasuo Yamagishi, Ei Yano, Nobuo Igusa, Isamu Takachi
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Patent number: 5693153Abstract: Surface preparation methods and materials that provide corrosion protection for aluminum and its alloys without the use of chromate and that protects aluminum surfaces against corrosion nearly as well as a chromate conversion coating. In accordance with the present methods, aluminum parts are degreased in a general purpose cleaner and rinsed in hot tap water. The parts are then cleaned using alkaline cleaner and then rinsed in cold tap water. The parts are then deoxidized using one of two alternative steps. The parts may be deoxidized using a 20-25 volume percent Smut-Go NC solution at room temperature for 15-25 minutes. The parts may alternatively be deoxidized using a solution of 10% HNO.sub.3 and 3% NaBrO.sub.4 dissolved in water at room temperature for 15-25 minutes. The deoxidized aluminum parts are then rinsed in cold tap water. The parts are then immersed in boiling deionized water and then sealed using a 1% LiNO.sub.3, 10% Al(NO.sub.3).sub.3 and 10% aluminum silicate solution.Type: GrantFiled: November 21, 1996Date of Patent: December 2, 1997Assignee: He Holdings, Inc.,Inventor: Jordan L Rosengard