Abstract: The present invention provides a continuous preparation method of cyclododecatriene including: preparing a reaction composition by mixing butadiene, a main catalyst, and a co-catalyst with a toluene solvent; and allowing the reaction composition to react at a reaction pressure higher than a vapor pressure of the butadiene, and a cyclododecatriene composition prepared by the continuous preparation method.

Abstract: A method for removing contaminants from a gas stream including contacting a gas stream comprising hydrocarbons and sulfur contaminants with a modified nanocomposite adsorbent. Also provided are compositions and processes for forming compositions of a modified nanocomposite adsorbent composition for removing sulfur contaminants from a hydrocarbon stream. Additionally, provided is system for removing sulfur impurities from a gaseous hydrocarbon stream, where the system includes a plurality of adsorbent vessels arranged in series, where the adsorbent vessels include an emulsion of a modified nanocomposite adsorbent composition.

Abstract: A membrane gas separator with a built-in valve along with a method of open and closing the membrane gas separator are disclosed herein. The membrane separator contains an inlet chamber, hollow selective fibres, an outlet chamber, a central core element and a flushing space. The membrane separator contains a built-in combined valve in the outlet chamber and a the central space and a check valve at an inlet manifold. The built-in valve contains a throttling section to ensure a reduced backflow of a final product from the outlet manifold to the inner space of hollow fibres, and the sealing section to stop the flow of the flushing medium from the outlet chamber to the flushing space when no inlet medium flows through the separator. The method of opening of the membrane separator includes opening of the sealing section and subsequent opening and deactivation of the throttling section.

Abstract: The systems and methods disclosed herein provide for the efficient separation of gas from fluid comprising liquid. In particular, gas separator systems and methods for use in bioreactor systems and operations are disclosed herein providing an efficient means to remove gaseous waste products, unreacted gaseous substrates, and or inert gas from broth of the biological fermentation of carbon substrates using a microorganism biocatalyst.

Abstract: An olefin production method is provided involves a step of catalytically cracking a raw material containing at least a polyolefin and an organochlorine compound in the presence of a zeolite catalyst having a sodium atom content of less than 0.1% by mass. This method improves olefin yield.

Abstract: A filter and a method for removing aldehyde-type VOCs from indoor air are disclosed. The filter includes a casing acting as a container. The container comprises two air-permeable opposite walls through which a volume of said indoor air flows and houses one or more natural polyphenols and a catalytic agent. The filter acts as an absorption filter, reacting irreversibly with the aldehyde-type VOCs of the indoor air. The natural polyphenols are powdered polyphenols selected from resveratrol (3,4?,5-trihydroxystilbene), resorcinol (1,3-benzenediol), pyrogallol (1,2,3-benzenetriol), phloroglucinol (1,3,5-benzenetriol) and hydroquinone (1,4-benzenediol), or combinations thereof. The catalytic agent is a solid sulfonic acid. A mixture of the natural polyphenols and said catalytic agent are present, in the container, as compacted block elements. An air-purifying/decontaminating device comprising the filter is also disclosed.

Abstract: A method for preparing hydrogen gas includes a decomposition step, a first adsorption step, a second adsorption step, a first regeneration step, a third heat-exchange step, and a second regeneration step.

Abstract: Water removal from humidified air and other water-laden gases may be complicated due to the need for large and expensive capital equipment or use of powder-form desiccants that may lead to pressure drops, poor throughput and energy-intensive recovery of water. Reversible water-absorbing constructs may alleviate these difficulties and comprise: a phase change polymer exhibiting a reversible hydrophilic-hydrophobic phase transition, and at least one additional material in contact with the phase change polymer, such as a water-sorptive material. The phase change polymer and the at least one additional material are formed as a plurality of filaments. Filaments formed from the phase change polymer may be generated through an electrospinning process, which may be arranged in various higher level constructs, such as in fibers, fabrics and non-woven filament mats capable of absorbing water from humidified air or other water-laden gases.

Abstract: A process for producing propylene involves dehydration of isopropanol. The dehydration process includes a step of subjecting a starting material containing isopropanol to a dehydration reaction in the presence of a dehydration catalyst comprising alumina to produce a product containing propylene. The starting material has a water content of 0.1 to 10.0 wt % (relative to 100 wt % of the total mass of the starting material), and the product has a total content of C2 unsaturated impurities and C3-C4 unsaturated impurities of 80 ppm or less (relative to 100 wt % of the total mass of the product).

Abstract: A carbon capture system can include a plurality of CO2 thermal swing adsorption (TSA) beds. The plurality of CO2 TSA beds can include at least a first TSA bed, a second TSA bed, and a third TSA bed configured to capture CO2 within a capture temperature range and to regenerate the captured CO2 at a regeneration temperature range above the capture temperature range. The carbon capture system can include a plurality of valves and associated flow paths configured to allow switching operational modes of each of the first, second, and third TSA beds.

Abstract: The present invention relates to a process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams of chemical products comprising ethylene, propylene, isobutene, 1-butene, 2-butene, 1,2-butadiene, 1,3-butadiene, benzene, styrene, toluene, ethylbenzene and xylenes; wherein in step (d): ? the coil outlet temperature is ?800 and ?870° C., preferably ?805 and ?835° C.

Abstract: Provided are a forward osmosis membrane, a forward osmosis membrane module, and a manufacturing method thereof, wherein a forward osmosis membrane, which achieves an extremely favorable reduction in the reverse diffusion of salt compared to the prior art and has a predetermined water permeability, is developed thereby bringing about: practicality in that a liquid-like raw material solution used in actual concentration operations can be concentrated with suppressed diffusion of an induction solution even when used multiple times; and durability in that the performance of the membrane can be maintained within a predetermined range even when a raw material solution having an osmotic pressure is concentrated multiple times.

Abstract: A metal organic framework glass membrane and a preparation method thereof are provided. The preparation method includes a step of heating a crystalline metal organic framework material to the melting temperature at a rate of 1-15° C./min and then naturally cooling the crystalline metal organic framework material. The crystalline metal organic framework material contains a metal node and a ligand A. The metal node is a zinc ion and/or a cobalt ion and the ligand A is imidazole or phosphoric acid. The metal organic framework glass membrane has a wide range of membrane-forming conditions, and the material thereof can be melted without being decomposed within a control range to form a continuous glass layer with good repeatability.

Abstract: A method and apparatus for purifying air via a pre-purification unit (PPU) of an air separation unit (ASU) system can include passing air through a first adsorber of the PPU to purify the air for operation of the ASU system while it is at or below a first pre-selected operational capacity. In response to the operational capacity of the ASU system needing to be increased to a level above the first pre-selected operational capacity threshold, a second adsorber can be brought on-line in parallel with the first adsorber or in series with the first adsorber to provide improved purification capacity to account for the increased demand for purification capacity resulting from the increased operational capacity of the ASU system. This second adsorber can be different from the first adsorber (e.g. different in size, adsorption capacity for impurities within air, and/or configuration, etc.).

Abstract: Described are methods, devices, and systems useful for adsorbing organometallic vapor onto solid adsorbent material to remove the organometallic vapor from a gas mixture that contains the organometallic vapor and other vapor, particulate materials, or both.

Abstract: Systems and methods for processing a C3 and C4 hydrocarbon mixture have been disclosed. The C3 and C4 hydrocarbon mixture is separated to remove propane from C4 hydrocarbons. The resulting C4 hydrocarbons are then processed in an isomerization unit to produce additional isobutane. The isobutane of the isomerization unit effluent is dehydrogenated in a dehydrogenation unit to produce isobutene. The resulting isobutene is reacted with an alkanol to produce an alkyl tert-butyl ether.

Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that predominantly comprises isobutane. The feed stream is catalytically-activated in two separate reaction zones arranged in series in a manner that minimizes the production of C1-C3 light paraffins and is tolerant to the presence of typical catalyst poisons. The first reaction zone is selective for conversion of the feed stream to predominantly olefins and some aromatics. The second reaction zone is maintained at a lower temperature and a higher pressure and is selective for converting olefins to monocyclic aromatics which facilitates further feed stream olefination. Certain embodiments contact the activation effluent with an alkylation catalyst to provide enhanced yields of upgraded hydrocarbon products that meet specifications for a transportation fuel blend component.

Abstract: A process for extracting fuel products from waste rubber, comprising the steps of subjecting the waste rubber to pyrolysis to produce a pyrolysis vapour, subjecting the pyrolysis vapour to a condensation step to produce a pyrolytic oil having a boiling point range of 45-400° C. and a flash point below 25° C., and then subjecting the pyrolytic oil to a vacuum steam stripping step so as to recover a fraction having a flash point of at least 40° C. but no higher than 55° C., a boiling point range starting at 100° C. or higher, a density at 15° C. of less than 990 kg/m3, a total acid number TAN of up to 12, a styrene content of less than 7000 ppm, and an organic halogen (as Cl) content of less than 50 ppm.

Abstract: A modular, multi-crew life support system and a method of assembling the system involve a fan to draw in ambient air. The system includes one or more assemblies that produce conditioned air from the ambient air, and a housing to support an oxygen source. The system also includes a port configured as an inlet from the oxygen source to augment the conditioned air, and a duct to disperse a result of augmenting the conditioned air as output air to support two or more occupants of an enclosure.

Abstract: A problem to be solved by the present invention is to provide a new form of adsorbent suitable for a motor vehicle canister. An activated carbon fiber sheet satisfies one or two or more of conditions for indices, such as a specific surface area, a pore volume of pores having a given pore diameter, and a sheet density. An embodiment, for example, may have: a specific surface area ranging from 1400 to 2300 m2/g; a pore volume ranging from 0.20 to 0.70 cm3/g for pores having pore diameters of more than 0.7 nm and 2.0 nm or less; an abundance ratio R0.7/2.0, which is a ratio of a pore volume of micropores having pore diameters of 0.7 nm or less occupied in a pore volume of micropores having pore diameters of 2.0 nm or less, ranging from 5% to less than 25%, and a sheet density ranging from 0.030 to 0.200 g/cm3.