Abstract: A Pd-supporting Zr-based composite oxide wherein by having a Zr-containing composite oxide support and Pd supported thereon and by showing, upon XAFS (X-ray absorption fine structure) analysis, a maximum peak in a Pd bond distance range of 2.500-3.500 ?, the maximum peak being located in a position of 3.050-3.110 ?.
Abstract: A method of producing a kesterite material of CZTS, CZTSe or CZTSSe type, including the steps of: a) preparing an acidic solution by dissolving copper and zinc salts in water in desired molar ratio, b) preparing a basic solution by dissolving an alkali metal stannate together with an alkali metal carbonate or an alkali metal hydrogen carbonate or an alkali metal hydroxide or a combination thereof, and optionally with an alkali metal selenate or an alkali metal selenite or a mixture thereof, c) carrying out a precipitation reaction by mixing the acidic and the basic solution, d) drying the precipitate thereby providing a precursor for the kesterite material, and e) sulfurizing the precursor of step d to provide the kesterite material. Also, a precursor for a kesterite material of CZTS, CZTSe or CZTSSe type.
Type:
Grant
Filed:
September 1, 2017
Date of Patent:
August 10, 2021
Assignee:
HALDOR TOPSØE A/S
Inventors:
Niels Christian Schjødt, Søren Dahl, Jesper Nerlov
Abstract: Fabricating a layer including lithium lanthanum zirconate (Li7La3Zr2O12) layer includes forming a slurry including lanthanum zirconate (La2Zr2O7) nanocrystals, a lithium precursor, and a lanthanum precursor in stoichiometric amounts to yield a dispersion including lithium, lanthanum, and zirconium. In some cases, the dispersion includes lithium, lanthanum, and zirconium in a molar ratio of 7:3:2. In certain cases, the slurry includes excess lithium. The slurry is dispensed onto a substrate and dried. The dried slurry is calcined to yield the layer including lithium lanthanum zirconate.
Type:
Grant
Filed:
April 30, 2019
Date of Patent:
August 10, 2021
Assignee:
Arizona Board of Regents on behalf of Arizona State University
Abstract: Described is an adsorbent, a vacuum heat insulating material having the same and a refrigerator, which are capable of adsorbing a target material in a reduced pressure environment. A refrigerator includes an outer casing forming an exterior, an inner casing provided inside the outer casing and forming a storage chamber and a vacuum heat insulating material positioned between the outer casing and the inner casing, and including an adsorbent that adsorbs a heat transfer medium. The adsorbent includes a first adsorption component provided to adsorb oxygen, and including a transition metal oxide having an oxygen deficiency structure, and a second adsorption component provided to adsorb moisture.
Abstract: A high-performance permanent magnet is provided. A permanent magnet expressed by a composition formula: RpFeqMrCutCo100-p-q-r-t-. The magnet comprises a metal structure including a cell phase having a Th2Zn17 crystal phase, and a Cu-rich phase provided to divide the cell phase and having a Cu concentration higher than that of the Th2Zn17 crystal phase. An Fe concentration of the Th2Zn17 crystal phase is not less than 30 atomic % nor more than 45 atomic %. An average length of the Cu-rich phase is not less than 30 nm nor more than 250 nm.
Type:
Grant
Filed:
August 30, 2017
Date of Patent:
August 3, 2021
Assignee:
KABUSHIKI KAISHA TOSHIBA
Inventors:
Yosuke Horiuchi, Shinya Sakurada, Naoyuki Sanada
Abstract: A lime hydrator integrated into a flue gas desulfurization system or other industrial system is provided that provides an in-situ variable rate of cured hydrated lime production for a variable supply rate of the in-situ produced cured hydrated lime for use within a flue gas stream as a moistened hydrated lime for a reduction of acid gas present in a flue gas stream. Also provided is a method of using a lime hydrator integrated into a flue gas desulfurization system or other industrial system to provide in-situ a variable production rate of cured hydrated lime for a variable supply rate of the in-situ produced cured hydrated lime for use within a flue gas stream as a moistened hydrated lime for a reduction of acid gas present in a flue gas stream.
Type:
Grant
Filed:
July 4, 2017
Date of Patent:
July 13, 2021
Assignee:
GENERAL ELECTRIC TECHNOLOGY GMBH
Inventors:
Wuyin Wang, Per Hakan Fredrik Landmer, Evald Johansson, Lars-Erik Johansson
Abstract: The invention provides a low alpha dose barium sulfate particle having a silica content of 0.6% by weight or less, an average particle diameter of 1 ?m or less, a sulfur content of 10 ppm or less, and an alpha dose of 0.07 cph/cm2 or less.
Abstract: Provided is a method for producing a zinc ferrite catalyst, the method comprising: preparing a zinc precursor solution; preparing a ferrite precursor solution; obtaining a first precipitate by bringing the zinc precursor solution into contact with an alkaline solution; obtaining a second precipitate by adding the ferrite precursor solution to the first precipitate; and drying and firing the second precipitate after filtering the second precipitate.
Type:
Grant
Filed:
December 19, 2018
Date of Patent:
June 22, 2021
Assignee:
LG CHEM, LTD.
Inventors:
Jun Kyu Han, Dong Hyun Ko, Kyong Yong Cha, Sang Jin Han, Sunhwan Hwang, Seongmin Kim
Abstract: Contemplated systems and methods for removing polysulfides and hydrogen sulfide from liquid sulfur of a Claus plant include (a) physically separated steps of catalytic decomposition of polysulfides and gas stripping, or (b) use of the stripping gas as the continuous phase in a packed column with decomposition catalyst to so avoid catalyst attrition.
Abstract: The invention concerns a method for accentuating the orientation of the grains of a continuous steel sheet (1), in particular for producing electrical sheet steel, said method involving, during the movement of the steel sheet (1) in the longitudinal direction of same, a longitudinal stretching of the steel sheet (1) in a stretch region (1d) in which the steel sheet (1) moves at a temperature of between approximately 750° C. and approximately 900° C. The invention also concerns a device for implementing said method in which the stretching is carried out by two tensioning blocks (41, 42) comprising traction rollers arranged to move and guide the steel sheet (1). The invention further concerns a facility for producing electrical sheet steel comprising a line comprising a rolling mill and on which said method and said device are implemented downstream from the rolling mill.
Abstract: Apparatus and methods for oxidizing an ammonia desulfurization solution. The apparatus may include an oxidation air system. The apparatus may include an oxidation tank. The apparatus may include in the tank, a gas-liquid dispersion enhancer. The enhancer may include a sieve plate layer that includes a sieve plate. The sieve plate layer may be one of a plurality of sieve plate layers. The plurality may include two or three sieve plate layers. The apparatus may include an oxidation enhancing device mated to the tank. The oxidation enhancing device may include an acoustic wave generating device. The oxidation enhancing device includes an ultrasonic wave generating device. The ultrasonic generating device may be configured to provide a sound intensity in the range 12 to 40 Watts/Liter. The ultrasonic generating device may be configured to provide to a liquid sound intensity in the range 12 to 40 Watts/Liter.
Type:
Grant
Filed:
June 13, 2018
Date of Patent:
June 8, 2021
Assignee:
Jiangnan Environmental Protection Group Inc.
Abstract: A splatter shield system for an additive manufacturing machine includes one or more splatter shields configured to cover at least a portion of a build area during energy application such that the at least one splatter shield is positioned between an energy source of an additive manufacturing machine and the build area during energy application. The one or more splatter shields are transparent to an energy source (e.g., a laser) of the additive manufacturing system such that energy application occurs through the splatter shield.
Type:
Grant
Filed:
November 21, 2017
Date of Patent:
June 8, 2021
Assignee:
Hamilton Sundstrand Corporation
Inventors:
Sergey Mironets, Alexander Madinger, Diana Giulietti, Dmitri Novikov
Abstract: Materials are disclosed for the safe sequestration and removal of hazardous contaminants from a surface. The materials can be sprayed, rolled, painted, brushed or dip coated onto any surface and allowed to dry and/or cure at room temperature or drying/curing can be accelerated by the application of heat to form a coating that entraps the contaminant therein. The coating and the entrapped contaminant can then peeled from the surface and safely disposed of to minimize hazardous waste. The coating includes a colorimetric additive that is specific to the contaminant, the coating and the contaminant producing a visual indication of contamination.
Type:
Grant
Filed:
May 31, 2017
Date of Patent:
June 1, 2021
Assignee:
INNOSENSE LLC
Inventors:
Uma Sampathkumaran, Kevin H. Yu, Raymond Winter
Abstract: A method for producing a double sulfate of potassium and magnesium by dry mechanical attrition of potassium sulfate and magnesium sulfate hexahydrate, comprising obtaining potassium sulfate by sulfatation of potash to bisulfate of potassium and disproportionation of the bisulfate of potassium to potassium sulfate in a water-methanol solution, and obtaining magnesium sulfate hexahydrate by sonic-assisted partial sulfatation of calcined serpentinic silicate.
Abstract: Methods for removing reduced sulfur compounds, such as hydrogen sulfide, from fluids employing a ferric iron salt that exhibits unusually high solubility in aqueous, alkaline solutions and has strong affinity for capture and oxidation of reduced sulfur compounds. Alkaline aqueous ferric iron salt and solutions thereof useful for removing reduced sulfur compounds from fluids and various methods of production of such salts and solutions. In addition, methods of regenerating the alkaline aqueous ferric iron salt solutions after capture of hydrogen sulfide or other reduced sulfur compounds, generally by exposure to oxygen in air. The alkali metal carbonate salt preferably comprises potassium carbonate and/or potassium bicarbonate. The alkaline aqueous ferric iron salt solutions generally comprise ferric ions, potassium ions, carbonate ions, and bicarbonate ions, optionally with one or more organic additives.
Abstract: A catalyst bed comprising a ceramic or metallic foam comprising one or more NOx reduction catalysts is described. A method for reducing the concentration of NOx in a dust containing gas stream comprising: a) passing a first gas stream containing NOx into a contacting zone; b) contacting the first gas stream with a ceramic or metallic foam catalyst bed having one or more flow paths through the catalyst bed wherein the ceramic or metallic foam comprises a NOx reduction catalyst to produce a second gas stream with a reduced NOx concentration; and c) passing the second gas stream out of the contacting zone wherein the first gas stream has a dust concentration of at least 5 mg/Nm3 and the pressure drop of the foam catalyst bed increases by 300% or less relative to the initial pressure drop of the foam catalyst bed due to dust accumulation, measured under the same conditions is also described.
Type:
Grant
Filed:
December 20, 2016
Date of Patent:
June 1, 2021
Assignee:
SHELL OIL COMPANY
Inventors:
Wassim Klink, Guido Seng, Wenzhong Zhang, Andreas Klemt, Paul Benjerman Himelfarb
Abstract: The invention relates to a catalyst comprising a small-pore zeolite that contains iron and copper and has a maximum ring size of eight tetrahedral atoms, characterized in that the channel width of the small-pore zeolite amounts to >3.8 ? (0.38 nm) in at least one dimension.
Type:
Grant
Filed:
May 2, 2017
Date of Patent:
May 25, 2021
Assignee:
UMICORE AG & CO. KG
Inventors:
Fei Wen, Nicola Soeger, Jürgen Gieshoff
Abstract: The present invention describes a fluid which is suitable for the decontamination of heat engines which can carry out both, at the same time, the catalytic reduction of oxides of nitrogen (NOx) contained in exhaust gases and assist in the regeneration of the particulate filter (PF). The invention also describes several embodiments of said fluid.
Type:
Grant
Filed:
October 20, 2016
Date of Patent:
May 25, 2021
Assignee:
IFP ENERGIES NOUVELLES
Inventors:
Serge Gonzalez, Jacques Vallet, David Pasquier
Abstract: The present invention relates to a process for producing mixed oxide catalysts on the basis of molybdenum and bismuth oxides in which the precursor compounds of the components of mixed oxide catalysts provided in the form of a solution and/or suspension are subjected to a spray-drying with a specific temperature regime and the spray particles obtained in this way are then calcined to yield a catalytic active mass, and to the mixed oxide catalysts obtainable by this process and to the use of these catalysts in the partial oxidation of olefins, in particular in the partial gas phase oxidation of propene to acrolein and acrylic acid. The spray drying of the precursor compounds containing solution or suspension is performed in concurrent with a gas stream having a specific entrance temperature. Alternatively, when the main gas stream has a higher entrance temperature, an additional colder gas stream can be fed in downstream.
Type:
Grant
Filed:
July 19, 2016
Date of Patent:
May 18, 2021
Assignee:
Evonik Operations GmbH
Inventors:
Achim Fischer, Axel Mescher, Harald Jakob
Abstract: A method of reducing NOx in tail gas obtained during startup of a plant for preparing nitric acid may involve heating the tail gas from a starting temperature T0, through a threshold temperature TG, to an operating temperature TB at which steady-state operation of the plant can occur (T0<TG<TB). NOx-containing tail gas may be passed through a storage medium and at least partially stored while the temperature of the tail gas is lower than the threshold temperature TG. The NOx may be released, preferably when the temperature of the tail gas has attained the threshold temperature TG. The NOx may be combined with a reducing agent in the presence of an SCR catalyst after the temperature of the tail gas has exceeded the threshold temperature TG, but not before, resulting in catalytic reduction of at least a portion of the NOx.
Type:
Grant
Filed:
June 1, 2015
Date of Patent:
April 27, 2021
Assignees:
thyssenkrupp Industrial Solutions AG, thyssenkrupp AG