Patents Examined by Thomas R. Neville
  • Patent number: 5429916
    Abstract: A silver halide color photographic photosensitive material comprises a reflective support having thereon at least one photosensitive silver halide emulsion layer. The reflective support comprises a base paper and two or more water-proof resin layers laminated on one surface of the base paper at the side to be coated with the photosensitive emulsion. The water-proof resin layers have different contents of a white pigment. The base paper has pH of from 5 to 9. The silver halide emulsion layer contains silver halide emulsion having a silver chloride content of 95% by moles or higher and being sensitized with selenium, tellurium, or gold.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: July 4, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoto Ohshima
  • Patent number: 5427891
    Abstract: Disclosed is a silver halide photographic material comprising:at least one silver halide emulsion layer;a hydrazine derivative; andat least one hydroquinone derivative represented by general formula (LI) or (LII): ##STR1## wherein G represents hydrogen atom or an alkyl group having 1 to 17 carbon atoms;n represents an integer of 1 to 5; andR.sub.1 to R.sub.10 each represent a hydrogen atom, an alkyl group, an aryl group, a hydroxyl group, an alkoxy group, an aryloxy group, a halogen atom, a primary, secondary or tertiary amino group, a carbonamido group, a sulfonamido group, a carbamoyl group, a sulfamoyl group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group, a carboxyl group or a sulfo group.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Hirano, Nobutaka Ohki, Nobuaki Inoue, Tetsuo Yamaguchi
  • Patent number: 5426019
    Abstract: Yellowing, dye fade and thermal pinking of a processed color photographic element is improved by incorporating into the photographic element a non-color forming, oil-soluble, monomeric or oligomeric organic compound having a glass transition temperature between 0.degree. and 150.degree. C. Preferred organic compounds include rosin derivatives, natural resins and oil-soluble sucrose esters, etc. In a particularly preferred embodiment, the above-noted properties are improved by incorporating into the photographic element an oil-soluble rosin derivative, such as abietic acid.
    Type: Grant
    Filed: December 30, 1993
    Date of Patent: June 20, 1995
    Assignee: Eastman Kodak Company
    Inventor: Krishnan Chari
  • Patent number: 5424178
    Abstract: A silver halide photographic material is disclosed, comprising at least one silver halide emulsion layer on a support and a backing layer on the surface of the support opposite to the emulsion layer, wherein said silver halide emulsion layer comprises tabular grains having an aspect ratio of not less than 3 in a proportion of not less than 50% as calculated in the terms of projected area of the silver halide grains contained in the emulsion layer and the surface on the backing layer side has a Beck smoothness of not more than 150 seconds.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: June 13, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hirohiko Tsuzuki
  • Patent number: 5424169
    Abstract: There is disclosed a silver halide photographic light-sensitive material for plate making giving a hard gradation and having less variation in photographic performance due to fatigue of the developing solution. The silver halide photographic light-sensitive material has at least one silver halide emulsion layer and contains at least one of hydrazine compound represented by Formula (I) in the above emulsion layer or in another hydrophilic colloid layer. The light-sensitive material also contains at least one hydrazine compound represented by Formula (II) in the above emulsion layer or another hydrophilic colloid layers. ##STR1## The variables in these formulas are defined in the specification.
    Type: Grant
    Filed: October 5, 1993
    Date of Patent: June 13, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Kazunobu Katoh, Kazumi Nii, Takashi Hoshimiya, Hisashi Okamura
  • Patent number: 5422224
    Abstract: A photographic material comprises a support and at least one photosensitive layer which comprises a non-chemically sensitized silver halide emulsion containing at least 80 mol % silver chloride based upon the total amount of silver halide in the emulsion. The photosensitive layer or another hydrophilic colloid layer comprises a hydrazine derivative represented by the following General Formula (I): ##STR1## In this formula A.sub.1 and A.sub.2 both represent hydrogen atoms, or one represents a hydrogen atom and the other represents a sulfinic acid group or an acyl group; R.sup.1 represents an aliphatic group, an aromatic group or a heterocyclic group, and R.sup.1 may or may not be substituted; G represents --CO--, --SO.sub.2 --, --SO--, --COCO--, thiocarbonyl, iminomethylene or --P(O)(R.sup.4) group; R.sup.2 represents a substituted or unsubstituted alkyl group, aryl group, heterocyclic group, amino group, alkoxy group or aryloxy group; at least one of R.sup.1 and R.sup.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: June 6, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 5422220
    Abstract: A photostimulable phosphor of which the emission intensity at the stimulation wavelength of 550 nm is higher than the emission intensity at the stimulation wavelength of 600 nm, characterized in that said phosphor is a divalent europium activated barium fluorobromide containing as codopant samarium, and wherein the terminology barium fluorobromide stands for an empirical formula wherein (1) a minor part of the barium (less than 50 atom %) is replaced optionally by at least one metal selected from the group consisting of a monovalent alkali metal, a divalent alkaline earth metal other than barium, and a trivalent metal selected from the group consisting of Al, Ga, In, Tl, Sb, Bi, Y, and a rare earth metal selected from the group consisting of Ce, Pr, Nd, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, (2) a minor part (less than 50 atom %) of the bromine is replaced by chlorine, and/or iodine, and (3) wherein fluorine is present stoichiometrically in a larger atom % than bromine taken alone or bromine combined with chlorin
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: June 6, 1995
    Assignee: Agfa-Gevaert N.V.
    Inventors: Paul Leblans, Albert D. Adriaensens, Melvin Tecotzky, Jan A. Van den Bogaert
  • Patent number: 5422234
    Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polymer having epoxy functionality, strongly bonds the overcoat layer to the imaging layer.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: June 6, 1995
    Assignee: Eastman Kodak Company
    Inventors: Charles L. Bauer, Wayne A. Bowman
  • Patent number: 5422235
    Abstract: In a photographic paper production method, a photographic paper support is coated with one or more photographic silver halide emulsion layers and one or more other hydrophilic colloid layers, at least one of the layers including a hardener. The coated support is then dried and conditioned to a temperature of from 24.degree. C. to 33.degree. C. The photographic and other layers on the support are conditioned to an equilibrium relative humidity of from 55% to 70%. The coated support is then stored at the conditioned temperature until the photographic and other layers have achieved a predetermined hardness. The new photographic paper production method reduces the post-production storage time required for photographic paper to achieve an acceptable level of abrasion resistance.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: June 6, 1995
    Assignee: Eastman Kodak Company
    Inventors: John W. Chapman, Andrew F. Sierakowski, Robyn A. Whittle
  • Patent number: 5422232
    Abstract: Disclosed herein is a silver halide color photographic light-sensitive material comprising at least three silver halide emulsion layers having different color sensitivities and formed on a reflective support. The support comprises a substrate and a composition layer laminated on at least the surface of the substrate on which the emulsion layers are coated, and made of a thermoplastic resin containing polyester as a main component and a white pigment mixed and dispersed in the resin. The polyester is a polyester synthesized by the polycondensation of a dicarboxylic acid and a diol. The silver halide contained in the material is silver chlorobromide having silver chloride content of 95 mol % or more, or silver chloride. The ratio of the coated amount of all hydrophilic colloid used in the material to the coated amount of silver contained in all silver halide used in the material ranges from 5.0 to 30.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: June 6, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiro Asami, Naoto Ooshima
  • Patent number: 5420000
    Abstract: Described is a radiation sensitive imaging film containing a heat fixable radiation sensitive element, e.g., a diacetylene, of the formula: R--C.tbd.C--C.tbd.C--R', where R and R' are, e.g., both --CH.sub.2 --O--CONH--(CH.sub.2).sub.5 CH.sub.3. After exposure to X-radiation during diagnostic or X-ray therapy, the resulting image can be permanently dry fixed by a short heating step and then stored for a long period. Processes for making the film, new binder-convertor systems, and a device incorporating the film are described as well as other imaging, diagnostic and therapeutic methods utilizing the film in high energy radiation applications in the health care field.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: May 30, 1995
    Assignee: JP Laboratories, Inc.
    Inventors: Gordhanbhai N. Patel, Yao-Ming Cheng, Subhash H. Patel
  • Patent number: 5419997
    Abstract: A method for processing a silver halide photographic material is disclosed and the photographic material has a support thereon, comprising at least one silver halide emulsion layer and containing a hydrazine compound represented by following formula (I) in the above emulsion layer or the other hydrophilic colloid layers, which comprises processing the silver halide photographic material after exposure in a developing solution containing:(1) 0.2 to 0.75 mole/liter of a dihydroxybenzene developing agent,(2) 0.001 to 0.06 mole/liter of a 1-phenyl-3-pyrazolidone or p-aminophenol auxiliary developing agent,(3) 0.3 to 1.2 mole/liter of a free sulfite ion, and(4) a compound represented by following formula (II), and having a concentration ratio of a compound represented by formula (II) to a dihydroxy developing agent of 0.03 to 0.12 and pH of 9.0 to 11.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: May 30, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mitsunori Hirano
  • Patent number: 5418120
    Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polyalkoxysilane, strongly bonds the overcoat layer to the imaging layer.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Kodak Company
    Inventors: Charles L. Bauer, Wayne A. Bowman
  • Patent number: 5415978
    Abstract: An image is formed in a color photosensitive material through scanning exposure by using at least one semiconductor laser excited solid laser including a semiconductor laser, a non-linear optical element and means for controlling the temperature thereof as a light source for producing a laser beam. The laser beam is modulated by an external modulator in accordance with the image to be formed. Among the combinations of photosensitive layers and laser beams, at least two laser beam light sources are such that a laser beam has a wavelength falling within .+-.20 nm from the maximum wavelength in the spectral sensitivity distribution of the corresponding photosensitive layer. Each photosensitive layer has a spectral sensitivity distribution with a peak width of up to 40 nm.
    Type: Grant
    Filed: January 13, 1994
    Date of Patent: May 16, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiro Asami, Nobuharu Nozaki, Yoji Okazaki
  • Patent number: 5415975
    Abstract: A silver halide photographic emulsion comprising a hydrophilic colloid binder, negative-acting silver halide grains, a hydrazine, and a contrast-promoting amount of a compound selected from the group consisting of 3-indazolinones, 4(3H)-pyrimidones, urazoles, 2-pyrazolin-5-ones, and 3-pyrazolin-5-ones.
    Type: Grant
    Filed: May 24, 1994
    Date of Patent: May 16, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Richard C. Cotner
  • Patent number: 5415980
    Abstract: A method of forming a photographic image comprising imagewise exposing a silver halide color photographic material comprising a support having thereon a cyan color image forming layer, a magenta color image forming layer and an yellow color image forming layer, wherein the cyan color image forming layer in the photographic material contains silver halide emulsion grains having a silver chloride content of 95 mol % or more and containing substantially no silver iodide and contains a color sensitizing dye of the following general formula (I), ##STR1## wherein the terms are as defined in the specification and color developing the exposed material with a color developer, wherein the color developer has a chloride ion content of from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/liter and a bromide ion content of from 1.5.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/liter.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: May 16, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoto Ohshima
  • Patent number: 5415973
    Abstract: A super-high contrast silver halide photographic material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the emulsion layer or at least one other hydrophilic colloid layer contains at least one hydrazine derivative, at least one redox compound capable of releasing a development inhibitor by oxidation and at least one compound represented by formula (I):Q--SM (I)wherein Q represents a heterocyclic group containing at least one hydrophilic group bonded thereto directly or indirectly; and M represents a hydrogen atom, an alkali metal, a quaternary ammonium group or a quaternary phosphonium group. The material is suitable for photomechanical processes, giving sharp and super-high contrast line images and dot images with little black pepper therein. Enlargement or reduction of images is easy with the material.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: May 16, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Nobuaki Inoue
  • Patent number: 5415987
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support having thereon a silver halide emulsion layer and a hydrophilic colloid layer provided at the farthest position from the surface of the support on which the emulsion layer is provided. In the light-sensitive material, the silver halide emulsion layer contains tabular silver halide grains each having an aspect ratio of not less than 3; and the hydrophilic colloid layer contains a polymer latex comprising a polymer which comprises a repeating unit derived from a monomer having a solubility in water of not higher than 0.025 % in weight at 25.degree. C.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: May 16, 1995
    Assignee: Konica Corporation
    Inventor: Kazuya Tsukada
  • Patent number: 5413901
    Abstract: A radiographic film package for non-destructive testing purposes has been developed, comprising a radiographic film sheet which is composed of a film support coated at both sides with one or more silver halide emulsion layer(s) and one or more non-light-sensitive protective antistress coating(s) thereover, and a wrapper around said film sheet which is light-opaque and air-tight, and which comprises a heat-sealable thermoplastic layer at the inner side of the wrapper, a transparent polymer layer at the outer side of the wrapper and a layer of aluminum located between said transparent polymer layer and said heat-sealable thermoplastic layer, and wherein at least one antistatic layer coating is provided between the said thermoplastic layer of said wrapper and the emulsion layers of said film sheet.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: May 9, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Raymond Florens, Hubert Vandenabeele, Paul Wouters
  • Patent number: 5411844
    Abstract: A coating composition for applying a layer to a photographic element and the resulting photographic element comprising gelatin, water and from 0.3 to 1 gm/100 gms of the composition of a surfactant mixture of 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt or di-fluoroalkylsulfosuccinate, sodium salt, from 35 to 75 percent by weight of a nonylphenoxy polyglycidyl alcohol, and from 3 to 14 percent by weight of perfluoro-octyl sulfonamido, N-hydrogen, N-propylene trimethylammonium iodide based on the total weight of the surfactant mixture; when a dioctyl sulfosuccinate, sodium salt is used, the minimum amount thereof is 0.15 gm/100 gm of coating composition.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael W. Orem