Abstract: The present invention provides a crosslinkable composition being capable of providing a molded article and a sealing material for an oxygen sensor which have excellent long-term heat resistance and satisfactory compression set. Also there is provided a molded article and a sealing material for an oxygen sensor which have excellent long-term heat resistance and satisfactory compression set. The crosslinkable composition comprises (A) a compound having at least one specific crosslinkable reaction group and (B) a nonperfluoro fluorine-containing elastomer being crosslinkable with the compound (A).
Abstract: The present invention provides a process for producing a block copolymer in high productivity, by anionic polymerization by use of a lithium initiator, and also to provide the block copolymer and a hydrogenated product thereof, the block copolymer having a conjugated diene block portion with a high vinyl bond content and a vinyl aromatic block portion with a narrow molecular weight distribution and exhibiting a narrow molecular weight distribution and high strength. A conjugated diene monomer and a vinyl aromatic monomer by use of a lithium initiator, are block copolymerized by making a tertiary amine compound and (2) sodium alkoxide coexist, wherein (2)/(1) (a molar ratio)=from 0.01 or more to less than 0.1.
Abstract: A process for producing an adsorbent where a metal oxide is reacted with an alkoxy silane to produce an epoxy-functionalized metal oxide. This product is reacted with an amino-substituted propionic acid and a nitro-substituted fluorenone, and this product is grafted to the epoxy-functionalized metal oxide. This grafted product is the adsorbent, which may be contacted with a hydrocarbon mixture having at least one sulfur containing compound in order to remove this sulfur containing compound. Also disclosed is a process for adding polymerization groups to an adsorbent.
Type:
Grant
Filed:
June 6, 2008
Date of Patent:
March 20, 2012
Assignee:
Chevron U.S.A. Inc.
Inventors:
Xiaolin Wei, Scott Michael Husson, Marcus V. Dutra e Mello, Daniel Chinn
Abstract: Phenolic resin binder systems for sand molds, used in metal casting, which improve the quality of thermally reclaimed sand, are described. The substantial or complete elimination of calcium compounds (e.g., calcium stearate and calcium hydroxide, conventionally employed as a mold lubricant and a resin curing catalyst, respectively) allows the thermally reclaimed sand to be reused over multiple thermal reclamation cycles without the adverse effects previously encountered.
Abstract: The invention provides an ink composition including (i) a sensitizing dye having a polymerizable group as a substituent, (ii) a polymerization initiator and (iii) a polymerizable compound having an ethylenically unsaturated bond. The invention also provides an inkjet recording method and a polymerizable compound useful as a sensitizing dye. The sensitizing dye (i) is represented by Formula (I) or (II) below. In the formulae, X represents O, S, NRa, or NRb, n1 and n2 each represent 0 or 1, Ra, Rb, and R1 to R18 each represent a hydrogen atom or a monovalent substituent, and one polymerizable group is present in the molecule.
Abstract: A process for preventing or reducing polymer agglomeration and/or accumulation on or around the gas distribution grid in an olefin polymerization, fluidized-bed reactor. The process involves introducing one or more scouring balls into the reactor above the gas distribution grid, and carrying out olefin polymerization in the presence of the scouring balls. Also disclosed is a process for polymerizing olefins in a fluidized-bed reactor with reduced polymer agglomeration and/or accumulation on the gas distribution grid.
Abstract: An antioxidant combined with UHMWPE prior to subjecting the UHMWPE to crosslinking irradiation. In one exemplary embodiment, the antioxidant is tocopherol. After the antioxidant is combined with the UHMWPE, the resulting blend may be formed into slabs, bar stock, and/or incorporated into a substrate, such as a metal, for example. The resulting product may then be subjected to crosslinking irradiation. In one exemplary embodiment, the UHMWPE blend is preheated prior to subjecting the same to crosslinking irradiation. Once irradiated, the UHMWPE blended product may be machined, packaged, and sterilized in accordance with conventional techniques.
Type:
Grant
Filed:
October 14, 2009
Date of Patent:
March 6, 2012
Assignee:
Zimmer, Inc.
Inventors:
Alicia Rufner, John Knight, Toni Rowe, Dirk Pletcher, Ray Gsell, Werner Schneider, Hallie E. Brinkerhuff
Abstract: A method for preventing or reducing agglomeration and/or accumulation on or around the gas distribution grid in a fluidized-bed vessel. The method involves introducing one or more scouring balls into the vessel above the gas distribution grid, and carrying out a fluidized-bed process in the presence of the scouring balls.
Abstract: The invention describes curable liquid acryloyl group containing compositions, which are produced by reacting monofunctional vinyl compounds and multifunctional acrylic esters with ?-dicarbonyl group containing compounds having two activated hydrogen atoms in its methylene position. These material can be polymerized or crosslinked by free radical polymerization, UV (ultraviolet) or electron-beam radiation. The curable liquid compositions are suitable for producing curable coatings, printing inks, adhesives, or molding compositions.
Type:
Grant
Filed:
December 19, 2003
Date of Patent:
February 21, 2012
Assignee:
Sun Chemical Corporation
Inventors:
Artur Lachowicz, Kai-Uwe Gaudl, Steven H. Nahm, Gerwald F. Grahe
Abstract: The present invention relates to a phenolic hydroxy group-containing rubber-modified polyamide resin which has, in the molecule, a phenolic hydroxy group-containing aromatic polyamide segment having a structure represented by the following formula (A) (wherein, m and n are average values and Ar represents a divalent aromatic group) and a butadiene (co)polymer segment selected from the following formula (B-1) or (B-2), —(CH2—CH?CH—CH2)X—??(B-1) —(CH2—CH?CH—CH2)Y—(CH2—CH(CN))Z—??(B-2) (wherein, each of x, y and z is an average value and 0.01?z/(y+z)?0.13, x represents a positive number of 5 to 200, and also y+z is a positive number of 10 to 200), and a resin composition containing said resin, in particular an epoxy resin composition; a cured product of said epoxy resin composition is excellent in flexibility, heat resistance and electrical properties especially at high temperature and high humidity.
Abstract: Disclosed are an ink composition comprising at least a colorant (a) and a polymer (b) having a heterocyclic moiety forming a colorant, an image forming method including applying the ink composition to a recording medium by printing and curing the ink composition, and a printed article produced by curing the ink composition.
Abstract: It is an object of the present invention to provide a method for easily and economically producing an expansion-molded polypropylene-based resin article stably with a high porosity, that has continuous voids and that can be used as materials such as a sound absorbing material and a draining material. More specifically, the present invention relates to a method for producing an expansion-molded polypropylene-based resin article, in which a mold is filled with expanded polypropylene-based resin particles, and the expanded particles are heated and fused using water vapor, and then cooled, wherein expanded polypropylene-based resin particles are used in which a polypropylene-based resin having a melt index (MI) of not less than 0.1 g/10 minutes and not more than 9 g/10 minutes is used as a base resin, a cell size is not more than 150 ?m, two melting peaks are present on a DSC curve obtained by differential scanning calorimetry, and ?/(?+?) is not less than 0.35 and not more than 0.
Abstract: A method for varying the transport properties of a film cast from a polymer having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. The method includes casting the polymer using a solvent mixture having two or more solvents selected from the group consisting of polar solvents and non-polar solvents.
Type:
Grant
Filed:
July 1, 2011
Date of Patent:
December 27, 2011
Assignee:
Kraton Polymers U.S. LLC
Inventors:
Carl Lesley Willis, Dale Lee Handlin, Jr., Scott Russell Trenor, Brian Douglas Mather
Abstract: The present invention provides a pre-expanded particulate polyolefin-based resin capable of easily attaining satisfactory secondary expandability, satisfactory surface appearance, and satisfactory dimensional stability even when it is intended to obtain an in-mold expansion molded article having a thin-wall shape. The present invention provides a pre-expanded particulate polypropylene-based resin including a polypropylene-based resin X as a base resin, where the resin X includes a resin mixture of at least a polypropylene-based resin A having a melting point of 140° C. or lower and a polypropylene-based resin B having a melting point of 145° C. or higher, and the resin mixture is modified by an organic peroxide so as to have a melt index of 5 g/10 min or more and less than 20 g/10 min.
Abstract: Hot melt adhesives are provided that have improved heat resistance. The adhesives comprise a metallocene polyolefin, an amorphous ?-olefin polymer, a tackifier and a functional polyolefin. The functional polyolefin is used in an amount sufficient to increase the heat resistance. A preferred functional polyolefin is a maleated polyolefin such as maleated polypropylene. A preferred tackifier is a hydrogenated hydrocarbon tackifier.
Abstract: A blown film that comprises polypropylene that has a melt flow rate of 1.8 to 14.0 g/10 min. and a melting point of at least 115° C. The blown film has a haze of less than 10% and a gloss of greater than 70%. The blown film may be co-extruded with a medium density polyethylene or 15 wt % of an impact copolymer. A clarifier may also be incorporated. The blown film that comprises polypropylene is produced on a standard air cooled blown film line.
Type:
Grant
Filed:
December 14, 2007
Date of Patent:
December 13, 2011
Assignee:
Fina Technology, Inc.
Inventors:
Rodolfo Mier, Mark Miller, Raleigh McBride
Abstract: The present invention has an object to provide an amphoteric polymer having high anti-soil redeposition ability and solubility with surfactants, and a process for producing the same. The amphoteric polymer includes: a structure unit (a) derived from a cationic group-containing monomer (A); and a structure unit (b) derived from a carboxyl group-containing monomer (B). The structure unit (a) is present at a level of 1 to 99% by mass based on 100% by mass of all structure units derived from all monomers in the amphoteric polymer, and the structure unit (b) is present at a level of 1 to 99% by mass based on 100% by mass of all the structure units derived from all the monomers in the amphoteric polymer.
Abstract: Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.
Type:
Grant
Filed:
December 11, 2009
Date of Patent:
December 6, 2011
Assignee:
Albemarle Corporation
Inventors:
Charles H. Kolich, John F. Balhoff, Martin B. Berdon, Ronny W. Lin
Abstract: A fuel cell comprising a proton transporting membrane is provided. The proton transporting membrane comprises a polyelectrolyte film comprising a multilayer comprising an interpenetrating network of a net positively charged polyelectrolyte polymer comprising repeat units with at least two fluorine atoms and a net negatively charged polyelectrolyte polymer comprising repeat units with at least two fluorine atoms, and further comprising a fluorinated counterion within the multilayer.
Type:
Grant
Filed:
March 19, 2010
Date of Patent:
December 6, 2011
Assignee:
Florida State University Research Foundation
Abstract: Ethylene alpha-olefin copolymers formed by contacting at least one supported metallocene catalyst, ethylene, and an alpha-olefin in a gas phase reactor are disclosed. In some embodiments, the polymer may have: a density of between 0.890 and 0.970 g/cc; a melt index of between 0.7 and 200 dg/min; a melt index ratio of less than 30; an ESCR value of greater than 1000 hours; and a 1% secant modulus of greater than 75,000 psi. In other embodiments, the polymer may have: a density of between 0.930 g/cc and 0.970 g/cc; a melt index of between 10 dg/min and 200 dg/min; a melt index ratio of between 10 and 25; a part weight of greater than 3 g and a part length of greater than 38 cm in a spiral flow test, and; a zero shear viscosity of less than 150 Pa·s. Processes to produce these polymers are also disclosed.
Type:
Grant
Filed:
June 7, 2007
Date of Patent:
November 29, 2011
Assignee:
Univation Technologies, LLC
Inventors:
Christopher R. Davey, James M. Farley, Rainer Kolb, Mark P. Ossowski