Abstract: A thermoplastic composition featuring an improved resistance to hydrolysis is disclosed. The composition comprises (i) thermoplastic polycarbonate resin (ii) about 0.01 to 3 percent of a compound selected from the group consisting of phosphite and phosphonite and (iii) an additive amount of an oligomer or polymer the structure of which features at least one pendant cyclic iminoether group per molecular chain. The additive amount is that which is sufficient to improve the resistance of the polycarbonate resin to hydrolysis.
Type:
Grant
Filed:
October 8, 1998
Date of Patent:
August 22, 2000
Assignee:
Bayer Corporation
Inventors:
Sivaram Krishnan, James B. Johnson, Donald K. Booher
Abstract: This invention relates to a process for producing 2-substituted succinate esters of formula (I) by reacting (a) a dicarboxylic compound with a first alcohol R'O[CH'.CH.sub.2 O].sub.x H where x is 0 or an integer from 1-6 in the presence of a catalyst to form a hydrocarbyl ester or, when x=1-6, a hydrocarbyloxy alkylene ester of maleic and/or fumaric acid and (b) the ester from step (a) with an alkaline earth metal alkoxide in the presence of a second alcohol R.OH to form the 2-substituted succinate ester of formula (I). The esters and paint formulations based thereon are also claimed.
Type:
Grant
Filed:
February 5, 1998
Date of Patent:
August 15, 2000
Assignee:
BP Chemicals Limited
Inventors:
Benjamin Patrick Gracey, Christopher Hallett
Abstract: A description is given of powder coating compositions comprising a) an organic film-forming binder and b) as stabilizer at least one compound of formula I ##STR1## wherein the general symbols are as defined in claim 1. Using powder coating compositions stabilized in this manner reduces the discoloration of the coatings during heat-cures, in particular during gas furnace cures.
Abstract: Modifying agents for polyolefins improve the physical and/or optical properties of the polymers and have formula (I): ##STR1## and salts thereof, wherein X, Y, Z, R and R1 are as defined in the specification.
Type:
Grant
Filed:
April 3, 1998
Date of Patent:
August 1, 2000
Assignee:
3M Innovative Properties Company
Inventors:
Stephen E. Amos, George G. I. Moore, Kent E. Nielsen, Markus A. Wicki
Abstract: The invention relates to a moldable thermoplastic resin composition comprising:(a) 99.95-25% by weight of at least one polyamide-containing compound,(b) 0.05-5% by weight of at least one compound selected from the group consisting of magnesium-, zinc- and aluminium salts, and optionally(c) 0-70% by weight of at least one additive compound, which resin composition has an apparent melt viscosity according to ISO 11443 of less than 100 Pa.s, at a shear rate of 1000 s(-1) and at 0.1% by weight moisture content of the resin composition in the form of granules.This invention furthermore relates to molded articles comprising such a thermoplastic resin composition.
Type:
Grant
Filed:
November 12, 1996
Date of Patent:
July 11, 2000
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Philip Leslie Boydell, Trevor John Hutley
Abstract: Salts of 1-hydroxydihydrophosphole oxides and 1-hydroxyphospholane oxides and use thereof as flame retardants. The salts of 1-hydroxydihydrophosphole oxides and 1-hydroxyphospholane oxides are useful as flame retardants, especially for plastics such as polyester or polyamide. The aluminum salts are preferred.
Abstract: A pigment composition for liquid toner comprising a carbon black, a resin and non-aqueous solvent, the carbon black and the resin being dissolved and dispersed in the non-aqueous solvent, and any one of (1) carbon black having a grit content of not more than 10 ppm and an ash content of not more than 0.1% by weight, (2) such carbon black that a value obtained by dividing a total amount of oxygen calculated from a composition of volatile components in carbon black at 1,500.degree. C. by a specific surface area thereof, lies in the range of 0.20 to 0.40 mg/m.sup.2, and (3) such carbon black that when extracted with monochlorobenzene, the content of polynuclear aromatic hydrocarbons in the extract is not more than 30 ppm, being used as the carbon black. The composition is produced by kneading the pigment and the resin together, freeze-pulverizing the mixture and then dissolving and dispersing the resultant particles in the non-aqueous solvent.
Type:
Grant
Filed:
August 14, 1998
Date of Patent:
July 11, 2000
Assignees:
Mitsubishi Chemical Corporation, Mitsubishi Heavy Industries Ltd.
Abstract: CPVC adhesives for joining CPVC substrates, pipes and articles are provided which comprise (a) about 5 to about 25 wt. % CPVC resin, (b) about 20 to about 90 wt. % of a single pentanone or blends of pentanones, (c) 0 to about 20 wt. % total heterocyclic solvent, and (d) 0 to about 45 wt. % total of non-heterocyclic solvents other than component (b) (such as MEK, acetone, cyclohexanone, and so forth). The CPVC adhesive compositions of this invention permit a reduction in the content of heterocyclic solvents to be achieved while meeting performance standards applicable to CPVC pipe joining, such as hydrostatic burst strength and hydrostatic sustained pressure test.
Type:
Grant
Filed:
September 18, 1998
Date of Patent:
July 11, 2000
Assignee:
IPS Corporation
Inventors:
Naresh D. Patel, Edward D. Otremba, Rashid H. Siddiqi
Abstract: Barrier coating mixtures contain in a carrier liquid, (a) an elastomeric (preferably butyl-containing) polymer; (b) a dispersed exfoliated layered filler having an aspect ratio greater than 25; and (c) at least one surfactant, wherein the solids content of the mixture is less than 30% and the ratio of polymer (a) to filler (b) is between 20:1 and 1:1. Coated articles, which are rigid or flexible and elastomeric, and free-standing films and membranes, which are flexible and elastomeric, are produced using the barrier coating mixtures.
Type:
Grant
Filed:
June 8, 1998
Date of Patent:
July 11, 2000
Assignees:
InMat, LLC, Michelin Recherche et Technique S.A.
Inventors:
Carrie A. Feeney, Michele Farrell, Klaus Tannert, Harris A. Goldberg, Mengshi Lu, Michael D. Grah, William G. Steiner, Paul B. Winston
Abstract: The present invention relates to polyester-platelet particle composite compositions comprising about 0.01 to about 25 weight percent platelet particles dispersed in at least one polyester wherein said composition has an I.V. of greater than about 0.55 dl/g, low shear melt viscosity greater than about 30,000 poise and a gas permeability which is at least 10% lower than that of unmodified polyester and processes for producing same.
Type:
Grant
Filed:
December 22, 1997
Date of Patent:
July 4, 2000
Assignee:
Eastman Chemical Corporation
Inventors:
James Christopher Matayabas, Jr., Sam Richard Turner, Bobby Jones Sublett, Gary Wayne Connell, John Walker Gilmer, Robert Boyd Barbee
Abstract: The present invention is directed to an improvement in a wire or cable system comprising a wire or cable portion, an insulation composition surrounding the wire or cable portion, a filler material surrounding the insulation composition and a jacket composition surrounding the filler material wherein either the insulation composition, the jacket composition, or both comprise at least one antioxidant, wherein the improvement comprises the inclusion in the filler material of a stabilizing mixture comprising at least two antioxidants, selected from at least two members of the group consisting of:(a) metal dithiocarbamate salts,(b) amine antioxidants, and(c) sterically hindered phenolic antioxidants,wherein the stabilizing mixture is present in the filler material in an amount that is effective for the reduction of the oxidation of the cable filling material, thereby reducing deterioration of the jacket and/or insulation.
Type:
Grant
Filed:
March 25, 1998
Date of Patent:
June 27, 2000
Assignee:
Uniroyal Chemical Company, Inc.
Inventors:
Christopher John Fagouri, Robert Scott Archibald
Abstract: The present invention relates to a composition comprising platelet particles treated with at least one polyalkoxylated ammonium salt comprising at least one polyalkoxylated group consisting of greater than 5 repeating alkyl oxide groups. The treated particles of the present invention display particularly good dispersion when incorporated into various polyester compositions at concentrations up to about 25 weight %. Also disclosed is a process incorporating said treated platelet particles into a polyester and for forming said treated platelet particles.
Type:
Grant
Filed:
December 22, 1997
Date of Patent:
June 6, 2000
Assignee:
Eastman Chemical Company
Inventors:
Robert Boyd Barbee, James Christopher Matayabas, Jr., John Walker Gilmer
Abstract: A non-curing sealant composition includes a monoepoxy compound, a polysulfide, and a tertiary amine catalyst, and optionally a liquid polythioether polymer having a functionality between about 2 and about 3. The composition is substantially free of chromates.
Abstract: A non-toxic, antifouling coating composition is provided which comprises zinc oxide contacted with photosensitizer(s) which increase the capability of zinc oxide to absorb visible light.
Abstract: An electrically conductive or semi-conductive polymeric material including a metal salt dissolved in a polymer. The metal salt is completed with the polymer, which is what provides the material with its conductive properties. The materials have a resistivity of between 10.sup.5 and 10.sup.12 ohms-cm.
Type:
Grant
Filed:
July 24, 1997
Date of Patent:
May 16, 2000
Assignee:
Mearthane Products Corp.
Inventors:
Albert C. Chiang, John A. Roderick, George B. Martins, Marcelino A. Martins, Wen-Pin Chen
Abstract: A flame retardant salt of organic polyphosphorus compound and/or composition are produced by reacting an organic phosphorus compounds with an inorganic phosphorus compound to produce an organic polyphosphorus compound, which is then reacted with a salt forming compound, such as a nitrogen-containing compound, which is then incorporated in or on a more flammable organic material. The more flammable organic material such as thermoplastic resins are made less flammable by melt-kneading a more flammable resin with a salt of organic polyphosphorus compound, a carbonization compound, a metal-containing compound having a carbonization acceleration effect, a comb-like polymer consisting of a polyethylene main chain and a polyoxyalkylene side chain and a filler.
Abstract: Corrosion inhibiting thermoplastic alloys and methods of preparing same for use in fabricating molded articles with long-term corrosion protection. Masterbatches of an ABS resin together with selected corrosion inhibitor formulations are extruded for use in molding operations particularly adapted for preparing protective enclosures for delicate metals, such as are present in electronic media devices and apparatus. Molded articles are prepared from acrylonitrile butadiene styrene resin and a solid phase corrosion inhibitor blended in situ, and wherein the resin consists essentially of acrylonitrile butadiene styrene, and wherein the corrosion inhibitor contains a blend of dicyclohexylammonium nitrite, sodium nitrite, benzotriazole, sodium molybdate and sodium sebacate.
Type:
Grant
Filed:
January 12, 1999
Date of Patent:
April 25, 2000
Assignee:
Cortec Corporation
Inventors:
Thomas Nelson, Scott Bradley, Margarita Kharshan, Boris Miksic
Abstract: In a silicone rubber composition comprising an organopolysiloxane, reinforcing silica, and a curing agent, an ester wax, typically having a melting point of 40-150.degree. C., is blended as an abherent. When the composition is molded in a mold, the flow of the composition in the mold and the parting of the cured silicone rubber from the mold are significantly improved.
Abstract: A process for the preparation of a melamine condensation product comprising the step of heating a starting material comprising melamine or a melamine salt in the presence of: (i) at least one organic acid, (ii) at least one ammonia or melamine salt of the organic acid, or (iii) a mixture of (i) and (ii), under reaction conditions effective for the formation of the melamine condensation product. The melamine condensation product with a residual condensation agent content of less than 1 wt. % is useful in a moldable polymer composition possessing flame-retardant properties.
Type:
Grant
Filed:
March 4, 1998
Date of Patent:
April 18, 2000
Assignee:
DSM N.V.
Inventors:
Augustinus E.H. de Keijzer, Bernardus J.H. Dijkstra
Abstract: Polymer compositions which comprise (a) a major amount of a polymer of carbon monoxide and at least one olefin and (b) a minor amount of a pseudoboehmite are stabilised against degradation in melt processing. The polymer is suitably a polyketone.
Type:
Grant
Filed:
September 25, 1998
Date of Patent:
July 25, 2000
Assignee:
BP Chemicals Limited
Inventors:
Andrew Ross Barron, Neil Shearer Davidson, Brian Kneale