Abstract: Disclosed herein is an aqueous colloidal titanium dioxide dispersion preferably having a pH value in a range of 6.2 to 7.8 at 25° C. and including titanium dioxide particles, the titanium particles having a Z-average particle size in a range from 30 nm to 220 nm as determined by dynamic light scattering and a particle size distribution span [(D90-D10)/(D50)] in a range from 0.7 to 1.5; one or more dispersing agents comprising groups which bind to the titanium dioxide particles; one or more organic solvents; and if necessary, one or more pH value adjusting compounds. Further disclosed herein are a method of preparing such dispersions, a coating composition containing the components of such dispersions, coated substrates and methods of coating the substrates with such dispersions and a method of using of the dispersions in the manufacture of coating compositions.