Abstract: A method of desulfurizing sulfur-crosslinked rubber includes adding a radical precursor that generates a radical active species that acts on a sulfur bond in the sulfur-crosslinked rubber and cleaves the sulfur bond and a radical initiator for generating a radical for converting the radical precursor into the radical active species to the sulfur-crosslinked rubber and performing heating.

Abstract: A crosslinked rubber composition contains ethylene-propylene-diene copolymer rubber crosslinked with a rotaxane compound having a cyclic molecule and an axial molecule penetrating through the cyclic molecule. In the crosslinked rubber composition, the ethylene-propylene-diene copolymer rubber contains vinylnorbornene, dicyclopentadiene, or tetrahydroindene as a diene component, and the rotaxane compound has a nitrile oxide group on the cyclic molecule and one end of the axial molecule, and the cyclic molecule is crown ether.

Abstract: A crosslinked rubber composition contains ethylene-propylene-diene copolymer rubber crosslinked with a rotaxane compound having a cyclic molecule and an axial molecule penetrating through the cyclic molecule. In the crosslinked rubber composition, the ethylene-propylene-diene copolymer rubber contains vinylnorbornene, dicyclopentadiene, or tetrahydroindene as a diene component, and the rotaxane compound has a nitrile oxide group on the cyclic molecule and one end of the axial molecule, and the cyclic molecule is crown ether.

Abstract: A method of producing a sealing member for a fuel cell includes: setting a base material made of a modified polypropylene in a mold; bringing a hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer into contact with the base material and performing molding in the mold; and vulcanizing the hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer and at the same time, bonding the hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer and the base material by vulcanization, in the mold with a molding temperature set to a temperature that is higher than a vulcanization start temperature of the hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer and lower than a melting point of the modified polypropylene.

Abstract: A method of producing a sealing member for a fuel cell includes: setting a base material made of a modified polypropylene in a mold; bringing a hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer into contact with the base material and performing molding in the mold; and vulcanizing the hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer and at the same time, bonding the hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer and the base material by vulcanization, in the mold with a molding temperature set to a temperature that is higher than a vulcanization start temperature of the hydrosilicone crosslinked ethylene/?-olefin/non-conjugated diene copolymer and lower than a melting point of the modified polypropylene.

Abstract: An air hose for an automobile, which has a two-layered structure of an inner tube made of an NBR composition and an outer cover made of a CSM composition, wherein the NBR composition satisfies (A) and (B) below: (A) an unvulcanized NBR in which an amount of AN is 30 to 50 and a Mooney viscosity (ML (1+4) 100° C.) is 50 to 90, is vulcanized in the presence of 0.5 to 7.0 parts by mass of a thiuram compound serving as a vulcanization accelerator, 0 to 2.5 parts by mass of 4,4?-dithio dimorpholine, and 2.0 to 7.0 parts by mass of a thiazole compound to 100 parts by mass of the unvulcanized NBR; and (B) 5 to 50 parts by mass of a plasticizer having a molecular weight of 700 to 2,000 is blended to 100 parts by mass of the unvulcanized NBR.

Abstract: An air hose for an automobile, which has a two-layered structure of an inner tube made of an NBR composition and an outer cover made of a CSM composition, wherein the NBR composition satisfies (A) and (B) below: (A) an unvulcanized NBR in which an amount of AN is 30 to 50 and a Mooney viscosity (ML (1+4) 100° C.) is 50 to 90, is vulcanized in the presence of 0.5 to 7.0 parts by mass of a thiuram compound serving as a vulcanization accelerator, 0 to 2.5 parts by mass of 4,4?-dithio dimorpholine, and 2.0 to 7.0 parts by mass of a thiazole compound to 100 parts by mass of the unvulcanized NBR; and (B) 5 to 50 parts by mass of a plasticizer having a molecular weight of 700 to 2,000 is blended to 100 parts by mass of the unvulcanized NBR.

Abstract: To provide a polymer alloy formed of a non-polar rubber and a polar rubber, and a rubber product, which are improved in ozone resistance (weather resistance) while having oil resistance and can achieve high mechanical strength (in particular, tensile strength), and a production method thereof. A rubber product in which an organic peroxide or other cross-linking agent is used to cross-link a polymer alloy comprising: a modified rubber in which EPDM, NR, or another non-polar rubber having a non-conjugated double bond is modified with 2-methoxy-1-naphthonitrile oxide, 2,6-dimethoxybenzonitrile oxide, or another nitrile oxide of an aromatic nitrile oxide derivative; and nitrile rubber, acrylic rubber, or another polar rubber.

Abstract: To provide a polymer alloy formed of a non-polar rubber and a polar rubber, and a rubber product, which are improved in ozone resistance (weather resistance) while having oil resistance and can achieve high mechanical strength (in particular, tensile strength), and a production method thereof. A rubber product in which an organic peroxide or other cross-linking agent is used to cross-link a polymer alloy comprising: a modified rubber in which EPDM, NR, or another non-polar rubber having a non-conjugated double bond is modified with 2-methoxy-1-naphthonitrile oxide, 2,6-dimethoxybenzonitrile oxide, or another nitrile oxide of an aromatic nitrile oxide derivative; and nitrile rubber, acrylic rubber, or another polar rubber.

Abstract: The present invention provides a crosslinker used for crosslinking a polymer material having, in the molecule thereof, a multiple bond reactable with a nitrile oxide, the crosslinker including a bifunctional nitrile oxide having an aromatic nitrile oxide derivative structure in which one hydrogen atom of an aromatic ring is substituted with a nitrile oxide group and all hydrogen atoms at an ortho-position of the nitrile oxide group are substituted with a substituent other than a nitrile oxide group, wherein two such aromatic nitrile oxide derivative structures are bonded to either two oxy groups of a di-oxy structure having the two oxy groups or two carbonyl groups of a di-carbonyl structure having the two carbonyl groups.

Abstract: The present invention provides a production method of a modified polymer material produced by modifying a polymer material having in a molecule thereof a multiple bond that reacts with a nitrile oxide, includes reacting the polymer material with an aromatic nitrile oxide derivative having a substituent at an ortho-position of a nitrile oxide group of an aromatic nitrile oxide in which the nitrile oxide group is bonded to an aromatic ring.

Abstract: The present invention provides a production method of a crosslinkable polymer material which includes adding 2 -(glycidyloxy)-1-naphthonitrile oxide or 2-[5 -(ethoxycarbonyl)pentyloxy]-1-naphthonitrile oxide by an addition reaction to a polymer material having a multiple bond to which a nitrile oxide is added by an addition reaction so as to introduce a glycidyl group or an ethoxycarbonyl group into the polymer material.

Abstract: The present invention provides a production method of a crosslinkable polymer material which includes adding 2-(glycidyloxy)-1-naphthonitrile oxide or 2-[5-(ethoxycarbonyl)pentyloxy]-1-naphthonitrile oxide by an addition reaction to a polymer material having a multiple bond to which a nitrile oxide is added by an addition reaction so as to introduce a glycidyl group or an ethoxycarbonyl group into the polymer material.

Abstract: The present invention provides a crosslinker used for crosslinking a polymer material having, in the molecule thereof, a multiple bond reactable with a nitrile oxide, the crosslinker including a bifunctional nitrile oxide having an aromatic nitrile oxide derivative structure in which one hydrogen atom of an aromatic ring is substituted with a nitrile oxide group and all hydrogen atoms at an ortho-position of the nitrile oxide group are substituted with a substituent other than a nitrile oxide group, wherein two such aromatic nitrile oxide derivative structures are bonded to either two oxy groups of a di-oxy structure having the two oxy groups or two carbonyl groups of a di-carbonyl structure having the two carbonyl groups.

Abstract: The present invention provides a production method of a modified polymer material produced by modifying a polymer material having in a molecule thereof a multiple bond that reacts with a nitrile oxide, includes reacting the polymer material with an aromatic nitrile oxide derivative having a substituent at an ortho-position of a nitrile oxide group of an aromatic nitrile oxide in which the nitrile oxide group is bonded to an aromatic ring.