Abstract: Process and apparatus for producing a low-nitrogen synthesis gas from a natural gas containing nitrogen and carbon dioxide, from which water and carbon dioxide are removed in a first temperature swing adsorption plant and subsequently nitrogen is removed in a cryogenic gas fractionator, to give a low-nitrogen, water-free and carbon dioxide-free natural gas, which is next supplied to a thermochemical conversion, so as to recover a crude syngas comprising hydrogen, carbon monoxide, water and carbon dioxide, from which the low-nitrogen synthesis gas is obtained at least by the removal of water and carbon dioxide in a second temperature swing adsorption plant. The characteristic feature here is that at least a part of the low-nitrogen, water-free and carbon dioxide-free natural gas prior to its thermochemical conversion is used as regenerating gas in the regeneration of the first and/or second temperature swing adsorption plant.

Abstract: The invention relates to a method for the synthesis of ammonia, in which a fresh gas consisting largely of hydrogen and nitrogen is compressed via a compressor and subsequently fed to an ammonia converter for conversion into a converter product containing ammonia and comprising hydrogen and nitrogen. Upstream of the compressor, ammonia is evaporated into the fresh gas in order to cool the fresh gas and to produce a cold substance mixture comprising ammonia and the fresh gas. The substance mixture is heated in a heat exchanger against at least one process stream to be cooled, and subsequently compressed via the compressor, to obtain a compressed substance mixture comprising ammonia and the fresh gas. Upstream of the circuit cooler, a gas mixture consisting largely of hydrogen and nitrogen is fed to a substance stream comprising the fresh gas. The constituents of the gas mixture are separated from the converter product and/or from the compressed substance mixture comprising ammonia and the fresh gas.

Abstract: A method and to a device for producing a synthesis gas, which contains carbon monoxide and hydrogen, wherein natural gas having a first carbon dioxide partial pressure (CO2 pressure) is provided and is processed inter alia by means of a pressure increase to form a natural gas input for a thermochemical conversion, in which a synthesis raw gas having a second CO2 pressure greater than the first CO2 pressure is produced, from which synthesis raw gas at least carbon dioxide is subsequently separated in order to obtain the synthesis gas and carbon dioxide, at least some of which is returned and is used in the thermochemical conversion of the natural gas input. To separate carbon dioxide, the synthesis raw gas is conducted across the one membrane on the retentate side, which membrane is permeable to carbon dioxide and is flushed on the permeate side by the provided natural gas.

Abstract: The invention relates to a method for the synthesis of ammonia, in which a fresh gas consisting largely of hydrogen and nitrogen is compressed via a compressor and subsequently fed to an ammonia converter for conversion into a converter product containing ammonia and comprising hydrogen and nitrogen. Upstream of the compressor, ammonia is evaporated into the fresh gas in order to cool the fresh gas and to produce a cold substance mixture comprising ammonia and the fresh gas. The substance mixture is heated in a heat exchanger against at least one process stream to be cooled, and subsequently compressed via the compressor, to obtain a compressed substance mixture comprising ammonia and the fresh gas. Upstream of the circuit cooler, a gas mixture consisting largely of hydrogen and nitrogen is fed to a substance stream comprising the fresh gas. The constituents of the gas mixture are separated from the converter product and/or from the compressed substance mixture comprising ammonia and the fresh gas.

Abstract: A process for producing hydrocarbons is disclosed in which a first feed substream and a second feed substream are obtained from a hydrocarbonaceous feed stream, of which the first feed substream is converted by means of partial oxidation or autothermal reforming to a first synthesis gas stream and the second feed substream is converted by means of steam reforming to a second synthesis gas stream and subsequently combined with the first synthesis gas stream to give a third synthesis gas stream, of which at least a first portion is converted by Fischer-Tropsch synthesis to a crude product stream comprising hydrocarbons of different chain lengths, from which light hydrocarbons are separated in a tail gas, in order to recycle them and use them in the partial oxidation or autothermal reforming. The characteristic feature here is that unsaturated hydrocarbons are separated from at least a portion of the tail gas.

Abstract: A process for producing hydrocarbons is disclosed in which a first feed substream and a second feed substream are obtained from a hydrocarbonaceous feed stream, of which the first feed substream is converted by means of partial oxidation or autothermal reforming to a first synthesis gas stream and the second feed substream is converted by means of steam reforming to a second synthesis gas stream and subsequently combined with the first synthesis gas stream to give a third synthesis gas stream, of which at least a first portion is converted by Fischer-Tropsch synthesis to a crude product stream comprising hydrocarbons of different chain lengths, from which light hydrocarbons are separated in a tail gas, in order to recycle them and use them in the partial oxidation or autothermal reforming. The characteristic feature here is that unsaturated hydrocarbons are separated from at least a portion of the tail gas.

Abstract: The invention relates to a method for purifying synthesis gas, in particular for ammonia synthesis, wherein a partial stream (26) of an H2-rich, CO-containing synthesis gas stream is burned, in particular to generate electrical energy, and wherein at least one component contained in the remaining H2-rich, CO-containing synthesis gas stream (26a), in particular in the form of carbon dioxide, methanol and/or water, is absorbed by an adsorber at low temperatures, after which said absorbed component is desorbed from the adsorber by flushing using nitrogen (33) at higher temperatures. According to the invention the H2-rich partial stream (26) is diluted using the nitrogen (35) used for the flushing before being burned. The invention further relates to a system (1) for purifying synthesis gas, in particular for ammonia synthesis.

Abstract: The invention relates to a method for purifying synthesis gas, in particular for ammonia synthesis, wherein a partial stream (26) of an H2-rich, CO-containing synthesis gas stream is burned, in particular to generate electrical energy, and wherein at least one component contained in the remaining H2-rich, CO-containing synthesis gas stream (26a), in particular in the form of carbon dioxide, methanol and/or water, is absorbed by an adsorber at low temperatures, after which said absorbed component is desorbed from the adsorber by flushing using nitrogen (33) at higher temperatures. According to the invention the H2-rich partial stream (26) is diluted using the nitrogen (35) used for the flushing before being burned. The invention further relates to a system (1) for purifying synthesis gas, in particular for ammonia synthesis.

Abstract: A method for producing nitrogen for injection into an enhanced oil recovery operation wherein the nitrogen is produced in an air separation device and the oxygen stream produced is not discarded but recovered and employed with or without an additional air gas stream for feeding to a partial oxidation unit/autothermal reformer and shift conversion to produce carbon dioxide and hydrogen. The carbon dioxide can additionally be used for injection into an enhanced oil recovery operation and the hydrogen can be used as a fuel for a gas turbine driven closed cycle power plant for providing energy to the air separation device.

Abstract: A method for producing carbon dioxide using the waste gas oxygen stream from an air separation unit producing nitrogen as the oxygen feed. The oxygen is fed to an autothermal reformation or partial oxidation unit to produce synthesis gas which is subjected to a shift reaction to produce hydrogen and carbon dioxide. The carbon dioxide is separated and recovered and can be employed in an enhanced oil recovery operation.