Abstract: A polyethylene composition having increased environmental stress crack resistance comprises a polymer blend of a multimodal high density polyethylene (HDPE) and an additive of at least one of a polycarbonate-siloxane copolymer, a polyethylene glycol (PEG) having an average molecular weight (Mw) of at least 2000, and a random block copolymer comprising two different saturated alkane blocks between two aromatic hydrocarbon blocks. The additive is present in the polymer blend in an amount of from 1 wt. % or less by weight of the polymer blend.

Abstract: A polyethylene composition having increased environmental stress crack resistance (ESCR) is comprised of a polymer blend of a high density polyethylene (HDPE) and polyethylene glycol (PEG). The PEG is present in the polymer blend in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The PEG may have an average molecular weight of from 2000 to 40,000. In a method of forming a polyethylene composition having increased ESCR, a HDPE is modified by combining the HDPE with PEG in a polymer blend, the PEG being present in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The polymer blend can be formed into an article of manufacture, such as a bottle cap.

Abstract: A multilayer film that includes at least a first polymeric layer comprising a polyolefin-based polymer and a second polymeric layer comprising a blend of a polar polymer and a silicon (Si) containing material comprising a silane having at least one alkyl group having at least 6 carbon atoms (C6) is disclosed. Methods of using and making the multilayer film is also disclosed.

Abstract: Oxygen scavenging polymeric compositions that possess an improved oxygen scavenging capability and can be formed into transparent/translucent thin films are disclosed. A composition can include iron powder, ferrous sulfate heptahydrate (FeSO4.7H2O) and glycerol dispersed in polyethylene. Such compositions are useful for creating packaging films with improved oxygen scavenging capability.

Abstract: Polymer blends, methods of making the polymer blends, and articles of manufacture that include the polymer blends are described. A polymer blend can include a high density polyethylene (HDPE) polymer and a random block copolymer. The random block copolymer can include two different saturated alkane blocks between aromatic blocks (e.g., two styrenic blocks).

Abstract: A dielectric polymeric composition comprising a polymeric matrix comprising structural units derived from a polymerizable vinyl monomer; an ionic liquid comprising an organic cation and a balancing anion, wherein the ionic liquid is miscible or partially miscible with the polymerizable vinyl monomer, and wherein the concentration of ionic liquid in dielectric polymeric composition ranges from 0.5 to 30 wt. %; and less than 10 ppm of unreacted polymerizable vinyl monomer, based on the total weight of the composition, wherein an amount of unreacted polymerizable vinyl monomer in the composition is measured via HPLC. The polymeric matrix further comprises structural units derived from a polymerizable co-monomer comprising a functional group that has the ability to form hydrogen bonds within the polymeric matrix.

Abstract: A polyethylene composition having increased environmental stress crack resistance (ESCR) is comprised of a polymer blend of a high density polyethylene (HDPE) and a polycarbonate-siloxane copolymer. The polycarbonate-siloxane copolymer is present in the polymer blend in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. In a method of forming a polyethylene composition having increased ESCR, a HDPE is modified by combining the HDPE with a polycarbonate-siloxane copolymer in a polymer blend, the polycarbonate-siloxane copolymer being present in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The polymer blend can be formed into an article of manufacture, such as a bottle cap.

Abstract: A polymer composite thin film exhibiting piezoelectric properties may include a polymer matrix with base material of Polyoxymethylene (POM) and a piezoelectric additive of greater than approximately five (5) percent by weight of the polymer composite thin film. The piezoelectric additives may include BaTiO3 and KNN. The polymer composite thin film exhibits piezoelectric characteristics and may be used in electronic devices in piezoelectric actuators and piezoelectric sensors.

Abstract: Oxygen scavenging polymeric compositions that possess an improved oxygen scavenging capability and can be formed into transparent/translucent thin films are disclosed. A composition can include iron powder, ferrous sulfate heptahydrate (FeSO4.7H2O) and glycerol dispersed in polyethylene. Such compositions are useful for creating packaging films with improved oxygen scavenging capability.

Abstract: A polyethylene composition having increased environmental stress crack resistance comprises a polymer blend of a multimodal high density polyethylene (HDPE) and an additive of at least one of a polycarbonate-siloxane copolymer, a polyethylene glycol (PEG) having an average molecular weight (Mw) of at least 2000, and a random block copolymer comprising two different saturated alkane blocks between two aromatic hydrocarbon blocks. The additive is present in the polymer blend in an amount of from 1 wt. % or less by weight of the polymer blend.

Abstract: A multilayer film that includes at least a first polymeric layer comprising a polyolefin-based polymer and a second polymeric layer comprising a blend of a polar polymer and a silicon (Si) containing material comprising a silane having at least one alkyl group having at least 6 carbon atoms (C6) is disclosed. Methods of using and making the multilayer film is also disclosed.

Abstract: A polyethylene composition having increased environmental stress crack resistance (ESCR) is comprised of a polymer blend of a high density polyethylene (HDPE) and a polycarbonate-siloxane copolymer. The polycarbonate-siloxane copolymer is present in the polymer blend in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. In a method of forming a polyethylene composition having increased ESCR, a HDPE is modified by combining the HDPE with a polycarbonate-siloxane copolymer in a polymer blend, the polycarbonate-siloxane copolymer being present in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The polymer blend can be formed into an article of manufacture, such as a bottle cap.

Abstract: A polyethylene composition having increased environmental stress crack resistance (ESCR) is comprised of a polymer blend of a high density polyethylene (HDPE) and polyethylene glycol (PEG). The PEG is present in the polymer blend in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The PEG may have an average molecular weight of from 2000 to 40,000. In a method of forming a polyethylene composition having increased ESCR, a HDPE is modified by combining the HDPE with PEG in a polymer blend, the PEG being present in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The polymer blend can be formed into an article of manufacture, such as a bottle cap.

Abstract: Polymer blends, methods of making the polymer blends, and articles of manufacture that include the polymer blends are described. A polymer blend can include a high density polyethylene (HDPE) polymer and a random block copolymer. The random block copolymer can include two different saturated alkane blocks between aromatic blocks (e.g., two styrenic blocks).

Abstract: Disclosed is a composite comprising: a polymer matrix formed from one or more of a monomer or a precursor polymer; and an in-situ dispersion of a piezoelectric ceramic filler and an ionic additive within the polymer matrix, wherein the composite exhibits a d33 of at least 1 pC/N when measured using a piezoelectric meter. Disclosed also herein are methods of forming the composite.

Abstract: A polymer composite thin film exhibiting piezoelectric properties may include a polymer matrix with base material of Polyoxymethylene (POM) and a piezoelectric additive of greater than approximately five (5) percent by weight of the polymer composite thin film. The piezoelectric additives may include BaTiO3 and KNN. The polymer composite thin film exhibits piezoelectric characteristics and may be used in electronic devices in piezoelectric actuators and piezoelectric sensors.

Abstract: A dielectric polymeric composition comprising a polymeric matrix comprising structural units derived from a polymerizable vinyl monomer; an ionic liquid comprising an organic cation and a balancing anion, wherein the ionic liquid is miscible or partially miscible with the polymerizable vinyl monomer, and wherein the concentration of ionic liquid in dielectric polymeric composition ranges from 0.5 to 30 wt. %; and less than 10 ppm of unreacted polymerizable vinyl monomer, based on the total weight of the composition, wherein an amount of unreacted polymerizable vinyl monomer in the composition is measured via HPLC. The polymeric matrix further comprises structural units derived from a polymerizable co-monomer comprising a functional group that has the ability to form hydrogen bonds within the polymeric matrix.

Abstract: A curable composition comprising (a) an organopolysiloxane comprising a curable functional group; (b) a cross-linker comprising a silyl hydride group or a thiol group; (c) a reaction accelerator; (d) optionally an inhibitor; and (e) optionally other additives. The curable composition exhibits high refractive index and optical clarity. The curable composition can be used to prepare a cured material that exhibits high refractive index, optical clarity, crack resistance, and low moisture vapor permeability.

Abstract: A thermal energy storage system utilizes a phase change material with an encapsulating material surrounding the phase change material. The encapsulating material fully contains the phase change material to prevent passage of the phase change material out of the encapsulating material and/or prevent direct contact of the phase change material with external objects. The encapsulating material is a high density polyethylene (HDPE), which may be a non-crosslinked or crosslinked HDPE. In a method of forming a thermal energy storage system a phase change material is surrounded with the encapsulating material.

Abstract: The present invention provides curable compositions comprising non-tin metal accelerators that accelerate the condensation curing of moisture-curable silicones/non-silicones. In particular, the present invention provides an accelerator comprising metal-arene complexes that are suitable as replacements for organotin in sealant and RTV formulations.