Abstract: The invention relates to a surface size composition for surface sizing of paper, board, or the like. The composition comprises at least an aluminium compound and an anionic lignin-carbohydrate complex.

Abstract: A method of producing a surface sizing composition, the method comprising: providing a metal salt having at least 3 valence electrons, wherein the metal salt is selected from the group of aluminium sulfate, aluminium chloride, aluminium nitrate, polyaluminium sulfate (PAS), polyaluminium chloride (PAC), and polyaluminium chloride sulfate (PACS), polyaluminium formiate, polyaluminium nitrate, and any combination thereof; providing an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) and an aqueous prepolymer composition (B), wherein the aqueous polymer dispersion (A) is obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend, and wherein the aqueous prepolymer composition (B) is obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend; and mixing the metal salt and the aqueous p

Abstract: The invention relates to the use of a surface size composition comprising at least one cellulose derivative selected from cellulose ethers, excluding carboxyalkyl celluloses, for providing compression strength for a fibrous web, such as paper, board or the like, preferably comprising recycled cellulosic fibres. The invention relates also to a method for surface sizing of paper, board or the like.

Abstract: The invention relates to an aqueous polymer dispersion and its preparation. The dispersion comprises a styrene acrylate polymer, which is obtainable by free-radical polymerisation of 1-90 weight-% of monomer (a), which comprises at least one optionally substituted styrene; 10-99 weight-% of monomer (b), which comprises at least one alkyl (meth)acrylate, and 0-9 weight-% of monomer (c), which comprises at least one ethylenically unsaturated monomer, which is different from monomer (b). The polymerisation is conducted in a polymerisation medium comprising a cationic prepolymer, which is obtainable by free radical polymerisation of at least 10-55 weight-% of a monomer (i), which comprises at least one ethylenically unsaturated quaternary and/or tertiary amine, 35-90 weight-% of a monomer (ii), which comprises at least one optionally substituted styrene, and 0-55 weight-% of a monomer (iii), which comprises at least one alkyl (meth)acrylate. The oligomer content in the polymer dispersion is ?1.

Abstract: A method of producing a surface sizing composition, the method comprising: providing a metal salt having at least 3 valence electrons, wherein the metal salt is selected from the group of aluminium sulfate, aluminium chloride, aluminium nitrate, polyaluminium sulfate (PAS), polyaluminium chloride (PAC), and polyaluminium chloride sulfate (PACS), polyaluminium formiate, polyaluminium nitrate, and any combination thereof; providing an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) and an aqueous prepolymer composition (B), wherein the aqueous polymer dispersion (A) is obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend, and wherein the aqueous prepolymer composition (B) is obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend; and mixing the metal salt and the aqueous p

Abstract: The present invention relates to a surface sizing composition comprising a metal salt, wherein the metal has at least 3 valence electrons, and an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (a) 0 to 75% by weight of at least one optionally substituted styrene, (b) 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, and (c) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (a)+(b)+(c) is 100%, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend comprising (i) 5 to 50%

Abstract: A coating structure for a sheet-like substrate, which includes lignocellulosic fibres is disclosed. The structure includes at least one pre-coat layer including at least 70 weight-% of a first styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser, having a glass transition temperature Tg ?20° C. preferably ?10° C., ?30 weight-% of inorganic platy mineral particles and 0.01-2 weight-% of at least one first thickener. The coating structure further includes a top coat layer including at least 50 weight-% of a second styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser having a glass transition temperature Tg ?20° C. preferably ?10° C., ?30 weight-% of inorganic mineral particles, 0.01-5 weight-% of at least one second thickener and 0.5-30 weight-% of an antiblocking agent. Further disclosed is a sheet-like product coated with the coating structure.

Abstract: The invention relates to a composition for modifying rheology of coating colour and its use. The composition comprises an aqueous polymer dispersion, comprising a copolymer of monomer (a), which is at least one optionally substituted styrene, and monomer (b), which is at least one C1-C4-alkyl (meth)acrylate. The copolymer has a particle size D50<100 nm. Composition comprises also degraded starch having an average molecular weight Mn<1000 g/mol.

Abstract: Provided herein is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend having 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, in the presence of a water-soluble redox system having a first free radical initiator for free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent having C1-6-carboxylic acid and C1-6-carboxylic acid anhydride a second ethylenically unsaturated monomer blend with 5 to 50% by weight of at least one ethylenically unsaturated quaternary amine, and 10 to 95% by weight of at least one optionally substituted styrene, in the presence of a second free radical initiator.

Abstract: The present invention relates to a surface sizing composition comprising a metal salt, wherein the metal has at least 3 valence electrons, and an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (a) 0 to 75% by weight of at least one optionally substituted styrene, (b) 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, and (c) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (a)+(b)+(c) is 100%, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend comprising (i) 5 to 50%

Abstract: The present invention relates to a sizing agent composition comprising starch, lignosulfonate and poly(alkyl acrylate), poly(alkyl (meth)acrylate), a mixture of poly(alkyl acrylate) and poly(alkyl methacrylate) or a copolymer of alkyl acrylate and alkyl (meth)acrylate. The present invention further relates to a method for preparing the sizing agent composition, and use of the sizing agent composition for sizing paper, paper products or board.

Abstract: The invention relates to an aqueous polymer dispersion having a viscosity of ?150 m Pas at 40% solids content and comprising polymer particles having a particle size D50 less than 85 nm. The polymer dispersion is obtainable by free radical emulsion copolymerisation of at least monomer (a) and monomer (b), where monomer (a) is at least one optionally substituted styrene and monomer (b) is at least one C1-C4-alkyl (meth)acrylate, in a reaction mixture comprising degraded starch which has an average molecular weight Mn<1000 g/mol. The invention relates also to the use of the polymer dispersion and method for preparing it.

Abstract: The present invention provides a core/shell polymer particle for surface sizing of cellulosic products, wherein the core polymer and the shell polymer of the core/shell polymer particle are polymerized from monomers comprising at least 40%, by weight of monomers selected from branched C3-10-alkyl (meth)acrylate, styrene, linear C1-10-alkyl (meth)acrylate, and acrylonitrile, based on the total weight of the monomers of the core/shell polymer particle; provided that the polymer of the core/shell polymer particle comprises at least 40% by weight of branched C3-6-alkyl (meth)acrylate and at least 50% by combined weight of branched C3-10-alkyl (meth)acrylate and styrene, linear C1-10-alkyl (meth)acrylate, and/or acrylonitrile, based on the total weight of the monomers of the core/shell polymer particle.

Abstract: The invention relates to a water-soluble polymer product in particle form, comprising amphoteric polyacrylamide, which is obtained by gel polymerisation of acrylamide together with anionic and cationic monomers. The amphoteric polyacrylamide has a mass average molecular weight MW of 1 500 000-6 000 000 g/mol, and a total ionicity of 4-15 mol-%, whereby the polymer product has a polymer content of at least 60 weight-%. The invention relates also to uses of the polymer product in paper and board making.

Abstract: The invention relates to a composition for modifying rheology of coating colour and its use. The composition comprises an aqueous polymer dispersion, comprising a copolymer of monomer (a), which is at least one optionally substituted styrene, and monomer (b), which is at least one C1-C4-alkyl (meth)acrylate. The copolymer has a particle size D50<100 nm. Composition comprises also degraded starch having an average molecular weight Mn<1000 g/mol.

Abstract: The invention relates to an aqueous polymer dispersion having a viscosity of ?150 m Pas at 40% solids content and comprising polymer particles having a particle size D50 less than 85 nm. The polymer dispersion is obtainable by free radical emulsion copolymerisation of at least monomer (a) and monomer (b), where monomer (a) is at least one optionally substituted styrene and monomer (b) is at least one C1-C4-alkyl (meth)acrylate, in a reaction mixture comprising degraded starch which has an average molecular weight Mn<1000 g/mol. The invention relates also to the use of the polymer dispersion and method for preparing it.

Abstract: Provided herein is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend having 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, in the presence of a water-soluble redox system having a first free radical initiator for free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent having C1-6-carboxylic acid and C1-6-carboxylic acid anhydride a second ethylenically unsaturated monomer blend with 5 to 50% by weight of at least one ethylenically unsaturated quaternary amine, and 10 to 95% by weight of at least one optionally substituted styrene, in the presence of a second free radical initiator.

Abstract: The present invention relates to a sizing agent composition comprising starch, lignosulfonate and poly(alkyl acrylate), poly(alkyl (meth)acrylate), a mixture of poly(alkyl acrylate) and poly(alkyl methacrylate) or a copolymer of alkyl acrylate and alkyl (meth)acrylate. The present invention further relates to a method for preparing the sizing agent composition, and use of the sizing agent composition for sizing paper, paper products or board.

Abstract: The present invention provides a core/shell polymer particle for surface sizing of cellulosic products, wherein the core polymer and the shell polymer of the core/shell polymer particle are polymerized from monomers comprising at least 40%, by weight of monomers selected from branched C3-10-alkyl (meth)acrylate, styrene, linear C1-10-alkyl (meth)acrylate, and acrylonitrile, based on the total weight of the monomers of the core/shell polymer particle; provided that the polymer of the core/shell polymer particle comprises at least 40% by weight of branched C3-6-alkyl (meth)acrylate and at least 50% by combined weight of branched C3-10-alkyl (meth)acrylate and styrene, linear C1-10-alkyl (meth)acrylate, and/or acrylonitrile, based on the total weight of the monomers of the core/shell polymer particle.

Abstract: The invention relates to a water-soluble polymer product in particle form, comprising amphoteric polyacrylamide, which is obtained by gel polymerisation of acrylamide together with anionic and cationic monomers. The amphoteric polyacrylamide has a mass average molecular weight MW of 1500000-6000000 g/mol, and a total ionicity of 4-15 mol-%, whereby the polymer product has a polymer content of at least 60 weight-%. The invention relates also to uses of the polymer product in paper and board making.