Patents by Inventor Antony K. Van Dyk

Antony K. Van Dyk has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230159782
    Abstract: The present invention relates to a composition comprising an aqueous dispersion of cerium (III) carbonate particles having a z-average particle size in the range of from 5 nm to 500 nm, which composition further comprises a capping ligand. The composition is useful as an additive in formulations that contain polymer, pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
    Type: Application
    Filed: February 9, 2021
    Publication date: May 25, 2023
    Inventors: James C. Bohling, Juan F. Callejas, Alexander Katz, Manish K. Mishra, Antony K. Van Dyk
  • Publication number: 20230146467
    Abstract: The present invention relates to a composition comprising a polymer and cerium (III) carbonate. The composition is useful in coatings formulations that include pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
    Type: Application
    Filed: February 9, 2021
    Publication date: May 11, 2023
    Inventors: James C. Bohling, Juan F. Callejas, Alexander Katz, Manish K. Mishra, Antony K. Van Dyk
  • Publication number: 20230144769
    Abstract: The present invention relates to a method of preparing an aqueous dispersion of nanosized cerium (III) carbonate particles comprising the step of admixing in water a) a water-soluble ammonium cerium (III) salt, b) a water-soluble carbonate, and c) a capping ligand to form an aqueous dispersion of cerium (III) carbonate particles having a resultant z-average particle size is in the range of from 5 nm to 500 nm. The method is useful for the preparation of an additive that is useful in formulations that contain polymer, pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
    Type: Application
    Filed: February 9, 2021
    Publication date: May 11, 2023
    Inventors: James C. Bohling, Juan F. Callejas, Alexander Katz, Manish K. Mishra, Antony K. Van Dyk
  • Publication number: 20230033318
    Abstract: A reaction system for forming a viscoelastic polyurethane foam includes an isocyanate component and an isocyanate-reactive component that includes at least a polyol component, an additive component, and a preformed aqueous polymer dispersant. The mixture includes 50.0 wt % to 99.8 wt % of the polyol component, 0.1 wt % to 49.9 wt % of the additive component, and 0.1 wt % to 6.0 wt % of the preformed aqueous polymer dispersant. The aqueous polymer dispersant has a pH from 6.0 to 12.0 and includes from 5 wt % to 60 wt % of a polymeric component and from 40 wt % to 95 wt % of a fluid medium. The polymeric component includes at least one base polymer derived from 20 wt % to 100 wt % of at least one hydrophilic acid monomer having at least one carbonyl group, phosphate group, phosphonate group, or sulfonyl group, and optionally derived from at least one hydrophobic terminally unsaturated hydrocarbon monomer.
    Type: Application
    Filed: July 23, 2021
    Publication date: February 2, 2023
    Inventors: Kaoru Aou, Thomas H. Kalantar, Qinghao Meng, John Klier, Antony K. Van Dyk, Gary W. Dombrowski, Joseph Jacobs
  • Publication number: 20220363908
    Abstract: The present invention is a composition comprising an aqueous dispersion of metal oxide pigment particles coated with an organosilane polymer comprising structural units of an alkyltrihydroxysilane or a salt thereof, a dialkyldihydroxysilane or a salt thereof, and an ancillary alkylsilane triol. The composition of the present invention provides hydrophobicity to pigment particles, thereby imparting water resistance, and allows for high loadings of pigment in water without increased viscosity. The dispersion is further useful for providing stain and corrosion resistance in coatings arising from paints.
    Type: Application
    Filed: October 1, 2020
    Publication date: November 17, 2022
    Inventors: David G. Barton, James C. Bohling, Juan F. Callejas, Amrita Chakravarty, Alexander Katz, Manish K. Mishra, Clayton J. Radke, Antony K. Van Dyk
  • Patent number: 11492538
    Abstract: A method for inhibiting scale comprises adding to a fluid that causes scale formation a polycarboxylic acid or a salt thereof which has a star structure and at least 5 arms. A star polymer comprising a core based on 2,2?-[Oxybis(methylene)]bis[2-(hydroxymethyl)-1,3-propanediol] and 6 arms comprising linear polycarboxylic acids of degree of polymerization (DP) of the arm of at least 2 and in some embodiments up to 15 or more is useful in inhibiting scale formation.
    Type: Grant
    Filed: January 28, 2020
    Date of Patent: November 8, 2022
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY, THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Puspendu Deo, Antony K. Van Dyk, Paul Clark, David Lunn, Craig Hawker, Maria Simon, Sungbaek Seo, Alaina McGrath
  • Patent number: 11472921
    Abstract: The present invention relates to a compound comprising a hydrophobically modified poly(oxyalkylene-urethane) having a hydrophobic fragment represented by Structure I: where Ar1, Ar2; R1, m, and n are defined herein. The compound of the present invention provides viscosity stability upon tinting for paints containing a hydrophobically modified poly(oxyalkylene-urethane) rheology modifier, more particularly a HEUR rheology modifier.
    Type: Grant
    Filed: January 31, 2020
    Date of Patent: October 18, 2022
    Assignee: Rohm and Haas Company
    Inventors: John J. Rabasco, Daniel A. Saucy, Antony K. Van Dyk
  • Patent number: 11407917
    Abstract: A water-based coating composition containing two parts A and B: (A) a binder component containing a waterborne epoxy dispersion, dispersed inorganic particles, and a polymeric dispersant; and (B) a hardener component, and a ratio of the component (A) and the component (B) is 90:1 to 2:1. The polymeric dispersant contains anti-agglomerating functional groups that are unreactive with oxirane groups of the epoxy dispersion.
    Type: Grant
    Filed: November 2, 2016
    Date of Patent: August 9, 2022
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Rui Wang, Hu Li, Weijun Yang, Siyuan Jiang, Hui Chen, Antony K. Van Dyk, Lidaris San Miguel Rivera, Tao Wang, Tao Wang
  • Patent number: 11359132
    Abstract: Disclosed herein is a method for inhibiting scale comprising adding to a fluid that causes scale formation a polycarboxylic acid having a polymer backbone and a plurality of branches from the polymer backbone.
    Type: Grant
    Filed: January 28, 2020
    Date of Patent: June 14, 2022
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY, THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Puspendu Deo, Antony K. Van Dyk, Paul Clark, David Lunn, Craig Hawker, Maria Simon, Sungbaek Seo, Alaina McGrath
  • Publication number: 20220162495
    Abstract: Disclosed is a method for inhibiting scale comprising adding to a fluid that causes scale formation a polycarboxylic acid or a salt thereof which has a star structure and at least 5 arms. Also, disclosed is a specific star polymer useful in scale inhibition which comprises a core based on 2,2?-[Oxybis(methylene)]bis[2-(hydroxymethyl)-1,3-propanediol] and 6 arms comprising linear polycarboxylic acids of degree of polymerization (DP) of the arm of at least 2 and in some embodiments up to 15 or more.
    Type: Application
    Filed: January 28, 2020
    Publication date: May 26, 2022
    Inventors: Puspendu DEO, Antony K. VAN DYK, Paul CLARK, David LUNN, Craig HAWKER, Maria SIMON, Sungbaek SEO, Alaina MCGRATH
  • Publication number: 20220041918
    Abstract: Disclosed herein is a method for inhibiting scale comprising adding to a fluid that causes scale formation a polycarboxylic acid having a polymer backbone and a plurality of branches from the polymer backbone.
    Type: Application
    Filed: January 28, 2020
    Publication date: February 10, 2022
    Inventors: Puspendu DEO, Antony K. VAN DYK, Paul CLARK, David LUNN, Craig HAWKER, Maria SIMON, Sungbaek SEO, Alaina MCGRATH
  • Patent number: 11198791
    Abstract: A hydrophilic polyurethane comprising polymerized units of: (a) a water-soluble polyol having hydroxyl functionality from two to four and a weight-average molecular weight from 800 to 16,000; and (b) an aliphatic polyisocyanate having isocyanate functionality from two to six; wherein polymerized ethylene oxide units comprise at least 85 wt % of said hydrophilic polyurethane; and wherein a product of weight fraction of polymerized ethylene oxide units and polyethylene oxide mean molecular weight is from 4,200 to 16,000.
    Type: Grant
    Filed: December 19, 2016
    Date of Patent: December 14, 2021
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Kimy Yeung, Antony K. Van Dyk, Jonathan DeRocher, Steven Arturo, John J. Rabasco
  • Patent number: 11186743
    Abstract: A stable two-component waterborne coating composition comprising an epoxy component A comprising a waterborne epoxy resin, a polymeric dispersant, and pigments and/or extenders; and a component B comprising a curing agent; providing coatings made therefrom with improved anti-corrosion properties; and a method of preparing the coating composition.
    Type: Grant
    Filed: June 2, 2017
    Date of Patent: November 30, 2021
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Weijun Yang, Hu Li, Longlan Cui, Siyuan Jiang, Tao Wang, Yu Cai, Jia Tang, Antony K. Van Dyk
  • Patent number: 11155722
    Abstract: The present invention relates to a process for preparing a coatings composition with an open time additive comprising the steps of a) contacting an aqueous dispersion of alkali swellable polymer particles with a rheology modifier and a binder to form a coatings composition with a VOC of less than 50 g/L; and b) neutralizing the alkali swellable particles with a non-volatile base after or upon contact with the rheology modifier and the binder to form swelled multi-staged polymer particles; wherein the alkali swellable polymer particles comprise a shell having a Tg of not greater than 25° C. and an acid functionalized core; and wherein the core-to-shell ratio is in the range of from 1:3.2 to 1:10. The composition arising from the process of the present invention is useful for improving open time, especially for low VOC coatings applications.
    Type: Grant
    Filed: May 2, 2018
    Date of Patent: October 26, 2021
    Assignees: Rohm and Haas Company, Dow Global Technologies, LLC.
    Inventors: James K. Bardman, Jonathan DeRocher, Andrew Hejl, Antony K. Van Dyk, Lin Wang, Kimy Yeung
  • Patent number: 11124656
    Abstract: The present invention relates to a composition comprising an aqueous dispersion of multistage polymer particles with a first phase comprising structural units of a carboxylic acid monomer and a nonionic ethylenically unsaturated monomer; and a second phase with a calculated Tg of less than 50° C. and comprising a mixture of polymers which together comprise structural units of styrene or methyl methacrylate or both; structural units of one or of n-butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, or n-butyl methacrylate; and structural units of a carboxylic acid monomer. The composition is useful as an open time additive in coatings formulations.
    Type: Grant
    Filed: July 15, 2019
    Date of Patent: September 21, 2021
    Assignee: Rohm and Haas Company
    Inventors: Jonathan DeRocher, Andrew Hejl, Jessica Levin, John J. Rabasco, Antony K. Van Dyk, Kimy Yeung
  • Publication number: 20210284863
    Abstract: A stable two-component waterborne coating composition comprising an epoxy component A comprising a waterborne epoxy resin, a polymeric dispersant, and pigments and/or extenders; and a component B comprising a curing agent; providing coatings made therefrom with improved anti-corrosion properties; and a method of preparing the coating composition.
    Type: Application
    Filed: June 2, 2017
    Publication date: September 16, 2021
    Inventors: Weijun Yang, Hu Li, Longlan Cui, Siyuan Jiang, Tao Wang, Yu Cai, Jia Tang, Antony K. Van Dyk
  • Patent number: 10968342
    Abstract: The present invention relates to a process for preparing an aqueous dispersion of neutralized multistage polymer particles comprising the steps of contacting under emulsion polymerization conditions a) an aqueous dispersion of first polymer particles with b) first monomers to form an aqueous dispersion of 2-stage polymer particles; then contacting under emulsion polymerization conditions the aqueous dispersion of 2-stage polymer particles with second monomers comprising to form an unneutralized aqueous dispersion of 3-stage polymer particles; then neutralizing the unneutralized aqueous dispersion of 3-stage polymer particles with a base to form an aqueous dispersion of neutralized 3-stage polymer particles, wherein the first and second monomers form a shell having a calculated Tg of less than 50° C. The process of the present invention is useful in preparing a composition that is useful as an open time additive in coatings formulations.
    Type: Grant
    Filed: July 15, 2019
    Date of Patent: April 6, 2021
    Assignee: Rohm and Haas Company
    Inventors: Jonathan DeRocher, Andrew Hejl, Jessica Levin, John J. Rabasco, Antony K. Van Dyk, Kimy Yeung
  • Patent number: 10947392
    Abstract: The present invention is a composition comprising an aqueous dispersion of metal oxide pigment particles coated with a polymer comprising structural units of an alkyltrihydroxysilane or a salt thereof and a dialkyldihydroxysilane or a salt thereof. The composition of the present invention provides hydrophobicity to pigment particles, thereby imparting water resistance, and allows for high loadings of pigment in water without increased viscosity.
    Type: Grant
    Filed: April 3, 2019
    Date of Patent: March 16, 2021
    Assignees: Rohm and Haas Company, The Regents of the University of California
    Inventors: James C. Bohling, Alexander Katz, Manish Mishra, Clayton J. Radke, Antony K. Van Dyk
  • Patent number: 10808074
    Abstract: The present invention relates to a compound having the following structure I: where Ar1, Ar2; R1, m, and n are defined herein. The compound of the present invention is useful as an open time additive in waterborne coatings compositions, particularly waterborne paint compositions.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: October 20, 2020
    Assignees: Rohm and Haas Company, Dow Global Technologies LLC
    Inventors: Edward D. Daugs, John J. Rabasco, Antony K. Van Dyk, Tianlan Zhang
  • Patent number: 10800888
    Abstract: The present invention relates to a compound having the following structure I: where Ar1, R, R1, E, m, n, x, y, p, and s are defined herein. The compound of the present invention is useful as an open time additive in waterborne coatings compositions, particularly waterborne paint compositions.
    Type: Grant
    Filed: June 25, 2018
    Date of Patent: October 13, 2020
    Assignees: Rohm and Haas Company, Dow Global Technologies, LLC
    Inventors: Edward D. Daugs, John J. Rabasco, Antony K. Van Dyk, Tianlan Zhang