Patents by Inventor Bizhong Zhu
Bizhong Zhu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240066843Abstract: An article includes a laminate material with an aerogel layer and a polysiloxane layer distinct from the aerogel layer and in contact with the aerogel layer either directly or through an adhesive that is in direct contact with both the aerogel layer and the polysiloxane layer; where the polysiloxane layer comprises a polysiloxane and greater than 5 weight-percent and 95 weight-percent or less based on polysiloxane layer weight of fire retarding additives selected from a group consisting of metal hydroxides, mixed metal hydroxides, hydrated metal salts, and any combinations thereof dispersed throughout the polysiloxane layer.Type: ApplicationFiled: February 22, 2022Publication date: February 29, 2024Inventors: Bizhong Zhu, Chi-Hao Chang, Kaila Mattson, Craig Gross, Joseph Sootsman, Greg Becker
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Patent number: 11807775Abstract: A silicone-organic copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0<j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-organic copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-organic copolymer and a condensation-reaction catalyst.Type: GrantFiled: December 16, 2019Date of Patent: November 7, 2023Assignees: Dow Silicones Corporation, Dow Global Technologies LLCInventors: Emmanuel Duquesne, Michael S. Ferrito, Martin Grasmann, Brian Harkness, William Johnson, Bindu Krishnan, Elizabeth Santos, Justin Scherzer, Jeanette Young, Bizhong Zhu
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Patent number: 11760841Abstract: A silicone-polycarbonate copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polycarbonate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0?j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polycarbonate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polycarbonate copolymer and a condensation-reaction catalyst.Type: GrantFiled: November 16, 2019Date of Patent: September 19, 2023Assignees: DOW SILICONES CORPORATION, DOW GLOBAL TECHNOLOGIES LLCInventors: Emmanuel Duquesne, Martin Grasmann, Brian Harkness, William Johnson, Elizabeth Santos, Justin Scherzer, Jeanette Young, Bizhong Zhu
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Publication number: 20230271386Abstract: A method of forming a three-dimensional (3D) pattern or article comprises: (1) selecting a first composition to be printed with a nozzle of an apparatus; (II) identifying desired characteristics of a pattern or layer (“pattern/layer”) to be formed by printing the first composition; (Ill) determining dimensional differences between the desired characteristics of the pattern/layer and predicted characteristics of the pattern/layer based on computational simulation modeling, or determining dimensional differences between the desired characteristics of the pattern/layer and actual characteristics of a trial layer, based on a flow rate of the first composition, a speed of a substrate and/or the nozzle, and the desired characteristics of the pattern/layer; and (IV) printing the first composition with the nozzle on the substrate to form the pattern/layer. The method comprises, during (IV) printing, (V) implementing a correction signal to adjust a flow rate of the first composition.Type: ApplicationFiled: February 27, 2023Publication date: August 31, 2023Inventors: Bizhong ZHU, Stanley YEE, Kurt A. KOPPI, Jon V. DEGROOT, JR., Albert SHIH, Matthew HILDNER, William VAN DEN BOGERT, James LORENZ
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Patent number: 11732156Abstract: A primer is useful for adhering cured silicones to low energy plastic substrates. The primer is prepared from starting materials including a) an organoboron compound capable of forming a free radical generating species, and at least one of b) an organosilicon compound having, per molecule, at least one free radical reactive group and at least one other reactive group, and/or c) an organoborane liberating compound capable of reacting with starting material a) to liberate the free radical generating species. The method for forming the primer may further include use of d) an organic solvent, and e) a free radical polymerizable monomer, oligomer, macromonomer, or polymer.Type: GrantFiled: March 9, 2018Date of Patent: August 22, 2023Assignee: DOW SILICONES CORPORATIONInventor: Bizhong Zhu
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Patent number: 11672768Abstract: A crosslinkable composition is useful for preparing a skin contact adhesive or a coating on a substrate. The crosslinkable composition includes (A) a polyurethane-polyorganosiloxane copolymer and (B) a curing catalyst. The skin contact adhesive prepared by crosslinking the crosslinkable composition is useful in applications such as adhesives for medical tapes, adhesives for wound dressings, adhesives for prosthetics, ostomy appliance adhesives, adhesives for medical monitoring appliances, adhesives for scar therapy treatments, adhesives for cosmetic patches, and transdermal drug delivery systems.Type: GrantFiled: August 18, 2017Date of Patent: June 13, 2023Assignee: DOW SILICONES CORPORATIONInventors: Bizhong Zhu, Martin Grasmann, Vinita Pandit, David Pierre, Bertrand Louis Julien Lenoble
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Publication number: 20220411587Abstract: A networked silicone is disclosed. The networked silicone comprises crosslinked strands of hindered organosilicon compounds. A composition for preparing the networked silicone is also disclosed, and comprises (A) a hindered organosilicon compound, (B) a crosslinking compound, and optionally (C) a catalyst. Additionally, a method of preparing the networked silicone is disclosed, and comprises reacting the hindered organosilicon compound (A) and the crosslinking compound (B), optionally in the presence of the catalyst (C), to give the networked silicone. A reaction product comprising the networked silicone is also disclosed. The reaction product is prepared from the composition and/or in accordance with the method, and may be a cured product. Additionally, a composite article and a method of forming the same are disclosed. The composite article is formed by disposing a networked silicone composition on the substrate and curing the networked silicone composition, thereby preparing the composite article.Type: ApplicationFiled: September 24, 2020Publication date: December 29, 2022Inventors: Bizhong ZHU, Kaila M. MATTSON
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Publication number: 20220410094Abstract: A static mixer is disclosed. The static mixer comprises a housing (22) defining an internal mixing cavity (36) that longitudinally extends along a central axis between an inlet (38) and an outlet (40) and is adapted for axial flow of a fluid therethrough. The static mixer also comprises a mixing element (42) disposed within the mixing cavity (36). The mixing element (42) is configured to be free from an impingement surface oriented substantially perpendicular to a main direction of fluid flow through the internal mixing cavity (36). The mixing element (42) comprises an elongated mixing blade that is oriented longitudinally within the mixing cavity (36) and comprises a nose axially oriented toward the inlet (38). The static mixer may comprise a heat-exchanging jacket integrally formed with the housing (22). An additive manufacturing system comprising the static mixer, and methods of making and using the same, are also disclosed.Type: ApplicationFiled: November 20, 2020Publication date: December 29, 2022Inventors: Bizhong ZHU, Stanley YEE, Matthew HILDNER, Jeffrey PLOTT, Albert SHIH
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Patent number: 11446859Abstract: A method of forming a porous three-dimensional (3D) silicone article is disclosed. The method comprises I) printing a first composition with a 3D printer to form a first layer from the first composition. The method further comprises II) printing a second composition on the first layer with the 3D printer to form a second layer from the second composition on the first layer. At least one of the first and second compositions comprises a silicone composition. In the method, step II) may optionally be repeated with independently selected composition(s) for any additional layer(s). At least one of the first and second layers does not consist of linear filaments. Finally, the method comprises III) exposing the layers to a solidification condition. The porous three-dimensional (3D) silicone article defines a plurality of voids.Type: GrantFiled: March 30, 2018Date of Patent: September 20, 2022Assignee: DOW SILICONES CORPORATIONInventors: Herschel Henry Reese, Bizhong Zhu
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Publication number: 20220267535Abstract: A silicone-polyether copolymer has the formula (X-D2)g-Y, where each X is an independently selected silicone moiety having a particular structure, D2 is a divalent hydrocarbon group, subscript g is greater than 1, and Y is a linear or branched polyether moiety. A method of preparing the silicone-polyether copolymer comprising reacting a polyether compound and an organosilicon compound in the presence of a hydrosilylation-reaction catalyst. A sealant is also disclosed, the sealant comprising the silicone-polyether copolymer and a condensation-reaction catalyst.Type: ApplicationFiled: May 12, 2022Publication date: August 25, 2022Inventors: Martin GRASMANN, David HAGAN, Brian HARKNESS, William H. HEATH, Stephen Michael HLINKA, II, Eric JOFFRE, William JOHNSON, Bindu KRISHNAN, Jeanette YOUNG, Bizhong ZHU
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Publication number: 20220251304Abstract: A networked silicone is disclosed. The networked silicone comprises crosslinked strands of looped organosilicon compounds. A composition for preparing the networked silicone is also disclosed, and comprises (A) a looped organosilicon compound, (B) a crosslinking organosilicon compound, and optionally (C) a catalyst. Additionally, a method of preparing the networked silicone is disclosed, and comprises reacting the looped organosilicon compound (A) and the crosslinking organosilicon compound (B), optionally in the presence of the catalyst (C), to give the networked silicone. A reaction product comprising the networked silicone is also disclosed. The reaction product is prepared from the composition and/or in accordance with the method, and may be a cured product. Additionally, a composite article and a method of forming the same are disclosed.Type: ApplicationFiled: July 22, 2020Publication date: August 11, 2022Inventors: Bizhong ZHU, Kaila MATTSON, Jeremiah A. JOHNSON, Deborah June Choi EHRLICH
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Patent number: 11390747Abstract: A composition for forming a silicone elastomer is disclosed. The composition comprises: A) a linear organopolysiloxane having at least two silicon-bonded ethylenically unsaturated groups per molecule; B) a linear organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule; C) at least one cross-linker; and D) a hydrosilylation catalyst. The cross-linker C) is selected from the group consisting of: C1) an organopolysiloxane having at least three silicon-bonded ethylenically unsaturated groups per molecule; and C2) an organopolysiloxane having at least three silicon-bonded hydrogen atoms per molecule. At least one of the silicon-bonded ethylenically unsaturated groups of component C1) has a lower reactivity relative to the silicon-bonded ethylenically unsaturated groups of component A). Moreover, at least one of the silicon-bonded hydrogen atoms of component C2) has a lower reactivity relative to the silicon-bonded hydrogen atoms of component B).Type: GrantFiled: August 28, 2019Date of Patent: July 19, 2022Assignee: Dow Silicones CorporationInventors: Jon V. Degroot, Jr., Eun Sil Jang, Eric Joffre, Bizhong Zhu
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Patent number: 11286389Abstract: A method of forming a three-dimensional (3D) article is disclosed. The method comprises I) printing a first thermoplastic silicone composition with a 3D printer to form an at least partially solidified layer. The method further comprises II) printing a second thermoplastic silicone composition on the at least partially solidified layer with the 3D printer to form a subsequent at least partially solidified layer. Optionally, step II) may be repeated with independently selected thermoplastic silicone composition(s) for any additional layer(s) to form the 3D article. The first and second thermoplastic silicone compositions are the same as or different from one another.Type: GrantFiled: September 9, 2016Date of Patent: March 29, 2022Assignee: DOW SILICONES CORPORATIONInventors: Zachary Milroy, Sara Schaubroeck, Bizhong Zhu
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Publication number: 20220081515Abstract: A silicone-polycarbonate copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polycarbonate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0?j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polycarbonate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polycarbonate copolymer and a condensation-reaction catalyst.Type: ApplicationFiled: December 16, 2019Publication date: March 17, 2022Inventors: Emmanuel DUQUESNE, Martin GRASMANN, Brian HARKNESS, William JOHNSON, Elizabeth SANTOS, Justin SCHERZER, Jeanette YOUNG, Bizhong ZHU
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Patent number: 11267193Abstract: A method of forming a porous three-dimensional (3D) is disclosed. The method comprises (I) printing a first composition on a substrate (16) with the nozzle (12) of the apparatus (10) to form at least one first filament (14) comprising the first composition, (II) selectively controlling the distance and/or the speed such that the at least one first filament coils on the substrate to give a first layer on the substrate, the first layer comprising a coiled filament, optionally repeating steps I) and II) with independently selected composition(s) for any additional layer(s), and (III) exposing the layer(s) to a solidification condition. A porous three-dimensional (3D) article formed in accordance with the method is also disclosed.Type: GrantFiled: March 30, 2018Date of Patent: March 8, 2022Assignees: Dow Silicones Corporation, The Regents of the University of MichiganInventors: Jeffrey Plott, Herschel Henry Reese, Albert J. Shih, Xiaoqing Tian, Hongjun Wang, Bizhong Zhu
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Publication number: 20220064482Abstract: A silicone-organic copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0<j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-organic copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-organic copolymer and a condensation-reaction catalyst.Type: ApplicationFiled: December 16, 2019Publication date: March 3, 2022Inventors: Emmanuel DUQUESNE, Michael S. FERRITO, Martin GRASMANN, Brian HARKNESS, William JOHNSON, Bindu KRISHNAN, Elizabeth SANTOS, Justin SCHERZER, Jeanette YOUNG, Bizhong ZHU
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Publication number: 20220064383Abstract: A silicone-polyacrylate copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0?j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyacrylate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyacrylate copolymer and a condensation-reaction catalyst.Type: ApplicationFiled: December 16, 2019Publication date: March 3, 2022Inventors: Emmanuel DUQUESNE, Michael S. FERRITO, Martin GRASMANN, Brian HARKNESS, William JOHNSON, Bindu KRISHNAN, Elizabeth SANTOS, Justin SCHERZER, Jeanette YOUNG, Bizhong ZHU
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Publication number: 20220041813Abstract: A silicone-polyester copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyester moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0?j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyester copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyester copolymer and a condensation-reaction catalyst.Type: ApplicationFiled: December 16, 2019Publication date: February 10, 2022Inventors: Emmanuel DUQUESNE, Martin GRASMANN, Brian HARKNESS, William JOHNSON, Bindu KRISHNAN, Elizabeth SANTOS, Justin SCHERZER, Jeanette YOUNG, Bizhong ZHU
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Patent number: 11192354Abstract: A method of forming a three-dimensional (3D) article comprises the steps of I) printing a first heat-curable silicone composition with a 3D printer to form a layer, II) heating the layer to form an at least partially cured layer, III) printing a second heat-curable silicone composition on the at least partially cured layer with the 3D printer to form a subsequent layer, and IV) heating the subsequent layer to form an at least partially cured subsequent layer. Optionally, steps III) and IV) can be repeated with independently selected heat-curable silicone composition(s) for any additional layer(s) to form the 3D article. The first and second heat-curable silicone compositions may be the same as or different from one another.Type: GrantFiled: September 2, 2016Date of Patent: December 7, 2021Assignee: Dow Silicones CorporationInventors: Michael W. Backer, Zachary Milroy, Sara Schaubroeck, Hans Peter Wolf, Bizhong Zhu
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Publication number: 20210317311Abstract: A composition for forming a silicone elastomer is disclosed. The composition comprises: A) a linear organopolysiloxane having at least two silicon-bonded ethylenically unsaturated groups per molecule; B) a linear organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule; C) at least one cross-linker; and D) a hydrosilylation catalyst. The cross-linker C) is selected from the group consisting of: C1) an organopolysiloxane having at least three silicon-bonded ethylenically unsaturated groups per molecule; and C2) an organopolysiloxane having at least three silicon-bonded hydrogen atoms per molecule. At least one of the silicon-bonded ethylenically unsaturated groups of component C1) has a lower reactivity relative to the silicon-bonded ethylenically unsaturated groups of component A). Moreover, at least one of the silicon-bonded hydrogen atoms of component C2) has a lower reactivity relative to the silicon-bonded hydrogen atoms of component B).Type: ApplicationFiled: August 28, 2019Publication date: October 14, 2021Inventors: Jon V. DEGROOT, JR., Eun Sil JANG, Eric JOFFRE, Bizhong ZHU