Patent number: 8795902
Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zO?, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850?x/(x+y+z)?0.930, and 0.087?y/(y+z)?0.115; “a” is 0?a?1; “b” is 0?b?1; “?” is 0.8???1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.
Type:
Grant
Filed:
April 13, 2010
Date of Patent:
August 5, 2014
Assignee:
Toyota Jidosha Kabushiki Kaisha
Inventors:
Chihiro Yada, Hiroshi Suyama, Shoji Yokoishi, Brian Elliot Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee
Publication number: 20130022878
Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zO?, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850?x/(x+y+z)?0.930, and 0.087?y/(y+z)?0.115; “a” is 0?a?1; “b” is 0?b?1; “67 ” is 0.8???1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.
Type:
Application
Filed:
April 13, 2010
Publication date:
January 24, 2013
Applicant:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Chihiro Yada, Hiroshi Suyama, Shoji Yokoishi, Brian Elliot Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee
Publication number: 20120237835
Abstract: A main object of the present invention is to provide a Li-La-Ti-O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3?x)?aM1a) (Ti1?bM2b)O3, wherein “x” is 0<x<0.17; “a” is 0?a?0.5; “b” is 0?b?0.5; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga, and wherein the solid electrolyte material is a crystalline material, is in thin film form, and has a thickness of 250 nm to 850 nm.
Type:
Application
Filed:
April 13, 2010
Publication date:
September 20, 2012
Applicant:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Chihiro Yada, Shoji Yokoishi, Brian Elliot Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee