Abstract: A process for fabrication of a battery that includes providing a colloidal suspension of particles conducting lithium ions and providing two conducting substrates as battery current collectors, at least one surface of the conducting substrates being at least partially coated with one of a cathode film and an anode film, and depositing an electrolyte film by electrophoresis, from a suspension of electrolyte material particles, on at least one of said anode film, said cathode film and said conducting substrates.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials, a film of solid electrolyte materials and a film of cathode materials, in which: each of these three films is deposited using an electrophoresis process, the anode film and the cathode film are each deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film, said conducting substrates or their conducting elements being useable as battery current collectors, the electrolyte film is deposited on the anode and/or cathode film, and in which said process also comprises at least one step in which said sheets or bands are stacked so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials (anode film), a film of solid electrolyte materials (electrolyte film) and a film of cathode materials (cathode film) in electrical contact with a cathode collector, characterized in that: a first electrode film (cathode or anode) is deposited by electrophoresis on a conducting substrate or a substrate with at least one conducting zone, said substrate or said at least one conducting zone possibly being used as a collector of said electrode current (anode or cathode current) of the micro-battery, the electrolyte film is deposited by electrophoresis on said first electrode film, a second electrode film (anode or cathode) is deposited on the electrolyte film either by electrophoresis or by a vacuum deposition process.

Abstract: Process for deposition of a dense thin film comprising at least one material Px on a substrate, in which: (a) a colloidal suspension is procured containing nanoparticles of at least one material Px, (b) said substrate is immersed in said colloidal suspension, jointly with a counter electrode, (c) an electrical voltage is applied between said substrate and said counter electrode so as to obtain the electrophoretic deposition of a compact film comprising nanoparticles of said at least one material Px on said substrate, (d) said compact film is dried, (e) said film is mechanically consolidated, (f) thermal consolidation is carried out at a temperature TR that does not exceed 0.7 times (and preferably does not exceed 0.5 times) the melting or decomposition temperature (expressed in ° C.) of the material Px that melts at the lowest temperature, preferably at a temperature of between 160° C. and 600° C., and even more preferably at a temperature of between 160° C. and 400° C.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials (anode film), a film of solid electrolyte materials (electrolyte film) and a film of cathode materials (cathode film) in electrical contact with a cathode collector, characterized in that: a first electrode film (cathode or anode) is deposited by electrophoresis on a conducting substrate or a substrate with at least one conducting zone, said substrate or said at least one conducting zone possibly being used as a collector of said electrode current (anode or cathode current) of the micro-battery, the electrolyte film is deposited by electrophoresis on said first electrode film, a second electrode film (anode or cathode) is deposited on the electrolyte film either by electrophoresis or by a vacuum deposition process.

Abstract: Process for the fabrication of a solid electrolyte thin film for an all-solid state Li-ion battery comprising steps to: a) Procure a possibly conducting substrate film, possibly coated with an anode or cathode film, b) Deposit an electrolyte thin film by electrophoresis, from a suspension of particles of electrolyte material, on said substrate and/or said previously formed anode or cathode film, c) Dry the film thus obtained, d) Consolidate the electrolyte thin film obtained in the previous step by mechanical compression and/or heat treatment.

Abstract: A process for fabrication of a battery that includes providing a colloidal suspension of particles conducting lithium ions and providing two conducting substrates as battery current collectors, at least one surface of the conducting substrates being at least partially coated with one of a cathode film and an anode film, and depositing an electrolyte film by electrophoresis, from a suspension of electrolyte material particles, on at least one of said anode film, said cathode film and said conducting substrates.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials, a film of solid electrolyte materials and a film of cathode materials, in which: each of these three films is deposited using an electrophoresis process, the anode film and the cathode film are each deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film, said conducting substrates or their conducting elements being useable as battery current collectors, the electrolyte film is deposited on the anode and/or cathode film, and in which said process also comprises at least one step in which said sheets or bands are stacked so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials, a film of solid electrolyte materials and a film of cathode materials, in which: each of these three films is deposited using an electrophoresis process, the anode film and the cathode film are each deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film, said conducting substrates or their conducting elements being useable as battery current collectors, the electrolyte film is deposited on the anode and/or cathode film, and in which said process also comprises at least one step in which said sheets or bands are stacked so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.

Abstract: A process for fabrication of all-solid-state thin film batteries, may include batteries including a film of anode materials, a film of solid electrolyte materials and a film of cathode materials. Each of these three films may be deposited using an electrophoresis process. The anode film and the cathode film may each be deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film. The conducting substrates or their conducting elements may be useable as battery current collectors, the electrolyte film may be deposited on the anode and/or cathode film. The process may also include stacking the sheets or bands so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.

Abstract: An electrode film of an all-solid-state battery, an all-solid-state battery, and an electrode of an all-solid-state battery, which are fabricated by a process that includes thermally consolidating an electrode film by sintering at a temperature that does not exceed a predetermined threshold of a lowest melting temperature between an anode material and an cathode material.

Abstract: The invention relates to a process for fabrication of an electrode film in an all-solid-state battery comprising successive steps to: a) Procure a substrate, preferably a conducting substrate, b) Deposit an electrode film on said substrate by electrophoresis, from a suspension containing particles of electrode materials, c) Dry the film obtained in the previous step, d) Thermal consolidation of the electrode film obtained in the previous step by sintering, sintering being done at a temperature TR that preferably does not exceed 0.7 times the melting temperature (expressed in ° C.), even more preferably does not exceed 0.5 times the melting temperature (expressed in ° C.), and much more preferably does not exceed 0.3 times the melting temperature (expressed in ° C.) of the electrode material that melts at the lowest temperature.

Abstract: The invention relates to a process for fabrication of an electrode film in an all-solid-state battery comprising successive steps to: a) Procure a substrate, preferably a conducting substrate, b) Deposit an electrode film on said substrate by electrophoresis, from a suspension containing particles of electrode materials, c) Dry the film obtained in the previous step, d) Thermal consolidation of the electrode film obtained in the previous step by sintering, sintering being done at a temperature TR that preferably does not exceed 0.7 times the melting temperature (expressed in ° C.), even more preferably does not exceed 0.5 times the melting temperature (expressed in ° C.), and much more preferably does not exceed 0.3 times the melting temperature (expressed in ° C.) of the electrode material that melts at the lowest temperature.

Abstract: Process for deposition of a dense thin film comprising at least one material Px on a substrate, in which: (a) a colloidal suspension is procured containing nanoparticles of at least one material Px, (b) said substrate is immersed in said colloidal suspension, jointly with a counter electrode, (c) an electrical voltage is applied between said substrate and said counter electrode so as to obtain the electrophoretic deposition of a compact film comprising nanoparticles of said at least one material Px on said substrate, (d) said compact film is dried, (e) said film is mechanically consolidated, (f) thermal consolidation is carried out at a temperature TR that does not exceed 0.7 times (and preferably does not exceed 0.5 times) the melting or decomposition temperature (expressed in ° C.) of the material Px that melts at the lowest temperature, preferably at a temperature of between 160° C. and 600° C., and even more preferably at a temperature of between 160° C. and 400° C.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials (anode film), a film of solid electrolyte materials (electrolyte film) and a film of cathode materials (cathode film) in electrical contact with a cathode collector, characterized in that: a first electrode film (cathode or anode) is deposited by electrophoresis on a conducting substrate or a substrate with at least one conducting zone, said substrate or said at least one conducting zone possibly being used as a collector of said electrode current (anode or cathode current) of the micro-battery, the electrolyte film is deposited by electrophoresis on said first electrode film, a second electrode film (anode or cathode) is deposited on the electrolyte film either by electrophoresis or by a vacuum deposition process.

Abstract: Process for fabrication of all-solid-state thin film batteries, said batteries comprising a film of anode materials, a film of solid electrolyte materials and a film of cathode materials, in which: each of these three films is deposited using an electrophoresis process, the anode film and the cathode film are each deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film, said conducting substrates or their conducting elements being useable as battery current collectors, the electrolyte film is deposited on the anode and/or cathode film, and in which said process also comprises at least one step in which said sheets or bands are stacked so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.

Abstract: Process for the fabrication of a solid electrolyte thin film for an all-solid state Li-ion battery comprising steps to: a) Procure a possibly conducting substrate film, possibly coated with an anode or cathode film, b) Deposit an electrolyte thin film by electrophoresis, from a suspension of particles of electrolyte material, on said substrate and/or said previously formed anode or cathode film, c) Dry the film thus obtained, d) Consolidate the electrolyte thin film obtained in the previous step by mechanical compression and/or heat treatment.

Abstract: The present invention relates to a process for reducing residuals content in a vinyl aromatic polymer, said residuals comprising essentially unpolymerized vinyl aromatic monomer, wherein the vinyl aromatic polymer in the molten state is brought in contact with a solid in powder capable to catalyze the alkylation of said residual vinyl aromatic monomer on the vinyl aromatic polymer. Advantage of the present invention is a sharp reduction of the unpolymerized vinyl aromatic monomer in the vinyl aromatic polymer without generating a new residual and without inducing a colored vinyl aromatic polymer. The present invention also relates to said vinyl aromatic polymer having a low residuals content.

Abstract: The present invention relates to a process for preparing a high impact monovinylaromatic polymer comprising admixing a rubber, at least one monovinylaromatic monomer and optionally one or more comonomer in the presence of at least a borane complex of the L-BH3 type wherein L is a Lewis base and polymerizing the monovinylaromatic monomer. The borane complex initiator, L may be an ether (e.g THF, tetrahydrofurane), a thioether (e.g dimethylthioether) or an amine. A preferred complex is an amine borane such as by way of example triethylamine borane. The present invention also relates to a high impact monovinylaromatic polymer having a weight ratio of grafted monovinylaromatic monomer and optional comonomer to the initial monovinylaromatic monomer and optional comonomer above 0.1%, advantageously above 2% and preferably in the range 2 to 4%. The invention is of particular interest to make high impact polystyrene.

Abstract: The invention relates to the production and use of block copolymers which are obtained by means of controlled radical polymerization in the presence of nitroxides for the purpose of reinforcing fragile polymer matrices. The invention offers advantages such as (i) simplicity of copolymer synthesis and use and (ii) fine dispersion of the copolymer molecules in the fragile matrix, which ensures both the transparency of the material and high reinforcement against impact. More specifically, the invention relates to the radical synthesis of block copolymers comprising at least three blocks, which include one block having a glass transition temperature of less than 0° C. and a thermoplastic end block having a glass transition temperature of more than 0° C., thereby guaranteeing compatibility with the fragile matrix to be reinforced against impact.