Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor selected from the class of M2D2C2-2bBbA2N6:Ln??(I) with M=selected from the group consisting of divalent Ca, Sr, and Ba; D=selected from the group consisting of monovalent Li, divalent Mg, Mn, Zn, Cd, and trivalent Al and Ga; C=selected from the group consisting of monovalent Li and Cu; B=selected from the group consisting of divalent Mg, Zn, Mn and Cd; A=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; Ln=selected from the group consisting of ES and RE; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; and 0?b?1.

Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor selected from the class of M2D2C2-2bBbA2N6:Ln ??(I) with M=selected from the group consisting of divalent Ca, Sr, and Ba; D=selected from the group consisting of monovalent Li, divalent Mg, Mn, Zn, Cd, and trivalent Al and Ga; C=selected from the group consisting of monovalent Li and Cu; B=selected from the group consisting of divalent Mg, Zn, Mn and Cd; A=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; Ln=selected from the group consisting of ES and RE; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; and 0?b?1.

Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor having the formula M1?x?y?zZzAaBbCcDdEeN4?nOn:ESxREy (I), with M=selected from the group consisting of Ca, Sr, and Ba; Z=selected from the group consisting of monovalent Na, K, and Rb; A=selected from the group consisting of divalent Mg, Mn, Zn, and Cd; B=selected from the group consisting of trivalent B, Al and Ga; C=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; D=selected from the group consisting of monovalent Li, and Cu; E=selected for the group consisting of P, V, Nb, and Ta; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; 0?x?0.2; 0?y?0.2; 0<x+y?0.4; 0?z<1; 0?n?0.5; 0?a?4 (such as 2?a?3); 0?b?4; 0?c?4; 0?d?4; 0?e?4; a+b+c+d+e=4; and 2a+3b+4c+d+5e=10?y?n+z.

Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor having the formula M1?x?y?zZzAaBbCcDdEeN4?nOn:ESxREy (I), with M=selected from the group consisting of Ca, Sr, and Ba; Z=selected from the group consisting of monovalent Na, K, and Rb; A=selected from the group consisting of divalent Mg, Mn, Zn, and Cd; B=selected from the group consisting of trivalent B, Al and Ga; C=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; D=selected from the group consisting of monovalent Li, and Cu; E=selected for the group consisting of P, V, Nb, and Ta; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; 0?x?0.2; 0?y?0.2; 0<x+y?0.4; 0?z<1; 0?n?0.5; 0?a?4 (such as 2?a?3); 0?b?4; 0?c?4; 0?d?4; 0?e?4; a+b+c+d+e=4; and 2a+3b+4c+d+5e=10?y?n+z.

Abstract: The invention relates to an improved red light emitting material of the formula M1?yA1+xSi4?xN7?x?2yOx+2y:RE whereby M is selected out of the group comprising Ba, Sr, Ca, Mg or mixtures thereof, A is selected out of the group comprising Al, Ga, B or mixtures thereof, RE is selected out of the group comprising rare earth metals, Y, La, Sc or mixtures thereof and x is ?0 and ?1 and y is ?0 and ?0.2. This material is believed to crystallize in a novel structure type that comprises two individual lattice sites for rare earth metal incorporation, which leads to an improved lighting behaviour.

Abstract: The invention relates to an improved red light emitting material of the formula M1?yA1+xSi4?xN7?x?2yOx+2y:RE whereby M is selected out of the group comprising Ba, Sr, Ca, Mg or mixtures thereof, A is selected out of the group comprising Al, Ga, B or mixtures thereof, RE is selected out of the group comprising rare earth metals, Y, La, Sc or mixtures thereof and x is ?0 and ?1 and y is ?0 and ?0.2.

Abstract: The invention relates to an improved red light emitting material of the formula M1?yA1+xSi4?xN7?x?2yOx+2y:RE whereby M is selected out of the group comprising Ba, Sr, Ca, Mg or mixtures thereof, A is selected out of the group comprising Al, Ga, B or mixtures thereof, RE is selected out of the group comprising rare earth metals, Y, La, Sc or mixtures thereof and x is ?0 and ?1 and y is ?0 and ?0.2. This material is believed to crystallize in a novel structure type that comprises two individual lattice sites for rare 10 earth metal incorporation, which leads to an improved lighting behavior.

Abstract: The invention relates to an improved red light emitting material of the formula M1?yA1+xSi4?xN7?x?2yOx+2y: RE whereby M is selected out of the group comprising Ba, Sr, Ca, Mg or mixtures thereof, A is selected out of the group comprising Al, Ga, B or mixtures thereof, RE is selected out of the group comprising rare earth metals, Y, La, Sc or mixtures thereof and x is ?0 and ?1 and y is ?0 and ?0.2. This material is believed to crystallize in a novel structure type that comprises two individual lattice sites for rare 10 earth metal incorporation, which leads to an improved lighting behaviour.