Patents by Inventor Daniel Ray Fruge

Daniel Ray Fruge has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160083587
    Abstract: Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
    Type: Application
    Filed: December 3, 2015
    Publication date: March 24, 2016
    Applicant: W. R. Grace & Co-Conn.
    Inventors: Demetrius Michos, Daniel Ray Fruge
  • Patent number: 9234104
    Abstract: Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: January 12, 2016
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Demetrius Michos, Daniel Ray Fruge
  • Publication number: 20130189425
    Abstract: An inorganic oxide coating produced by preparing a coating composition comprising inorganic oxide particles and a polymer, applying the composition on a substrate to form a coating, and heating the substrate to remove the polymeric component, wherein the resulting coating is transparent.
    Type: Application
    Filed: July 20, 2012
    Publication date: July 25, 2013
    Inventors: Demetrius Michos, Daniel Ray Fruge, Qi Sun
  • Publication number: 20120285349
    Abstract: Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
    Type: Application
    Filed: December 13, 2010
    Publication date: November 15, 2012
    Inventors: Demetrius Michos, Daniel Ray Fruge
  • Publication number: 20120142845
    Abstract: A metal oxide particulate dispersion comprising, oil and metal oxide particles having an average particle size of 35 microns or less, wherein the dispersion includes less than 10% by weight water and water-miscible solvent, based on the total weight of the dispersion.
    Type: Application
    Filed: September 11, 2009
    Publication date: June 7, 2012
    Inventors: Kris P. De Winter, Nicolas H.M. Leliveld, Horst Herrig, Daniel Ray Fruge
  • Publication number: 20100314585
    Abstract: An anticorrosion material comprising colloidal particles and multivalent metal ions is disclosed. The particles are preferably silica. The metal ions may be Al, Ga, Ti, Zr, Hf, Zn, Mg, Ca, Nb, Ta, Fe, Cu, Sn, Co, W or Ce. The material can be added to a conversion coating liquid, mixed with a polymeric binder or used as such to form a coating.
    Type: Application
    Filed: November 24, 2008
    Publication date: December 16, 2010
    Inventors: Daniel Ray Fruge, Yoshitaka Sugimoto, Qi Sun
  • Publication number: 20100294168
    Abstract: An inorganic oxide coating produced by preparing a coating composition comprising inorganic oxide particles and a polymer, applying the composition on a substrate to form a coating, and heating the substrate to remove the polymeric component, wherein the resulting coating is transparent.
    Type: Application
    Filed: March 22, 2007
    Publication date: November 25, 2010
    Applicant: W. R. GRACE & CO.-CONN.
    Inventors: Qi Sun, Daniel Ray Fruge, Demetrius Michos
  • Patent number: 7622170
    Abstract: A coating composition comprising low sodium containing colloidal silicas and ink jet recording sheets prepared from such coatings are described. The coating comprises binder and colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: November 24, 2009
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6902780
    Abstract: A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: June 7, 2005
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6896942
    Abstract: A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: May 24, 2005
    Assignee: W. R. Grace & Co. -Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6893691
    Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: May 17, 2005
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030198759
    Abstract: A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.
    Type: Application
    Filed: March 18, 2003
    Publication date: October 23, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030180478
    Abstract: A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(−0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Application
    Filed: March 18, 2003
    Publication date: September 25, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030180480
    Abstract: A coating composition comprising low sodium containing colloidal silicas and ink jet recording sheets prepared from such coatings are described. The coating comprises binder and colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(−0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Application
    Filed: March 18, 2003
    Publication date: September 25, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030180483
    Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.
    Type: Application
    Filed: March 18, 2003
    Publication date: September 25, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos