Abstract: The present invention provides waterborne curable film-forming compositions comprising: a) an aqueous dispersion of polymeric acrylic particles, wherein the particles have a Z average particle size less than 80 nm and have reactive functional groups; wherein the particles are prepared from a monomer mixture comprising ethylenically unsaturated monomers that are polymerized in the presence of a branched polymer having an acid value of 40-200, wherein the branched polymer is prepared from ethylenically unsaturated monomers; b) a crosslinking agent having functional groups reactive with functional groups on the polymeric acrylic particles; and c) an aqueous dispersion of at least one additional polymer having hydroxyl and/or acid functional groups and having a Z average particle size greater than 100 nm. Further provided are multilayer coated substrates comprising the curable film-forming compositions and methods for forming a composite coating on a substrate using the curable film-forming compositions.

Abstract: A non-aqueous dispersion comprising a continuous phase and a dispersed phase, wherein the dispersed phase comprises the dispersion polymerization reaction product prepared from a reaction mixture comprising an ethylenically unsaturated monomer, an acrylic polymer stabilizer, and an aliphatic polyester stabilized seed polymer, is disclosed. Related coatings and coated substrates are also disclosed.

Abstract: A method for producing a bonded permanent magnet by additive manufacturing, the method comprising: (i) incorporating components of a reactive precursor material into an additive manufacturing device, the reactive precursor material comprising an amine component, an isocyanate component, and particles having a permanent magnetic composition; and (ii) mixing and extruding the crosslinkable reactive precursor material through a nozzle of the additive manufacturing device and depositing the extrudate onto a substrate under conditions where the extrudate is permitted to cure, to produce a bonded permanent magnet of desired shape. The resulting bonded permanent magnet and articles made thereof are also described.

Abstract: The present invention provides waterborne curable film-forming compositions comprising: a) an aqueous dispersion of polymeric acrylic particles, wherein the particles have a Z average particle size less than 80 nm and have reactive functional groups; wherein the particles are prepared from a monomer mixture comprising ethylenically unsaturated monomers that are polymerized in the presence of a branched polymer having an acid value of 40-200, wherein the branched polymer is prepared from ethylenically unsaturated monomers; b) a crosslinking agent having functional groups reactive with functional groups on the polymeric acrylic particles; and c) an aqueous dispersion of at least one additional polymer having hydroxyl and/or acid functional groups and having a Z average particle size greater than 100 nm. Further provided are multilayer coated substrates comprising the curable film-forming compositions and methods for forming a composite coating on a substrate using the curable film-forming compositions.

Abstract: Curable film-forming compositions are provided. The compositions comprise (a) a curing agent comprising reactive functional groups; (b) a film-forming compound comprising functional groups reactive with the reactive functional groups in (a); and (c) a catalyst component added to the curable film-forming composition as a dispersion of micelles in a continuous phase. The catalyst component (c) comprises a catalyst compound contained within or encapsulated by a carrier, and the catalyst compound and carrier together form the micelles in the continuous phase. The carrier comprises block copolymers that comprise at least one hydrophobic block derived from hydrophobic monomers and at least one hydrophilic block derived from (1) hydrophilic monomers and/or (2) monomers containing groups that may be rendered hydrophilic after polymerization.

Abstract: Curable film-forming compositions are provided. The compositions comprise (a) a curing agent comprising reactive functional groups; (b) a film-forming compound comprising functional groups reactive with the reactive functional groups in (a); and (c) a catalyst component added to the curable film-forming composition as a dispersion of micelles in a continuous phase. The catalyst component (c) comprises a catalyst compound contained within or encapsulated by a carrier, and the catalyst compound and carrier together form the micelles in the continuous phase. The carrier comprises block copolymers that comprise at least one hydrophobic block derived from hydrophobic monomers and at least one hydrophilic block derived from (1) hydrophilic monomers and/or (2) monomers containing groups that may be rendered hydrophilic after polymerization.

Abstract: A non-aqueous dispersion comprising the dispersion polymerization reaction product of an ethylenically unsaturated monomer and a nonlinear, random acrylic polymer stabilizer is disclosed. Related coatings, methods, and substrates are also disclosed.

Abstract: A catalyst composition is provided. The composition comprises at least 30 percent by weight of a catalyst compound based on the total weight of solids in the catalyst composition; and a polymer prepared from ethylenically unsaturated monomers. The polymer either (i) has a backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization, and a plurality of side chains along the backbone derived from substantially hydrophobic monomers, or (ii) has a backbone derived from substantially hydrophobic monomers and a plurality of side chains along the backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization. The catalyst compound is contained within or encapsulated by the polymer. Methods of preparing the catalyst composition and curable compositions containing the catalyst composition are also provided.

Abstract: A catalyst composition is provided. The composition comprises at least 30 percent by weight of a catalyst compound based on the total weight of solids in the catalyst composition; and a polymer prepared from ethylenically unsaturated monomers. The polymer either (i) has a backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization, and a plurality of side chains along the backbone derived from substantially hydrophobic monomers, or (ii) has a backbone derived from substantially hydrophobic monomers and a plurality of side chains along the backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization. The catalyst compound is contained within or encapsulated by the polymer. Methods of preparing the catalyst composition and curable compositions containing the catalyst composition are also provided.

Abstract: The present invention provides an aqueous polymer dispersion for vibration damping comprising a film-forming polymer in the form of dispersed particles comprising a polymer phase P1 and different polymer phases P2 and P3; the polymer dispersion obtained by free radical emulsion polymerization. Controlling the difference in glass transition temperatures of the polymers in the various polymer phases results in effective sound damping as determined by a Damping Loss Factor of at least 0.1 over a temperature range of at least 40° C. determined at a frequency of 200 Hz over a temperature range of ?10 to 65° C. Use of a chain transfer agent in the polymerization of the various monomer charges results in good appearance in the resultant vibration damping coating.

Abstract: A non-aqueous dispersion comprising a continuous phase and a dispersed phase, wherein the dispersed phase comprises the dispersion polymerization reaction product prepared from a reaction mixture comprising an ethylenically unsaturated monomer, an acrylic polymer stabilizer, and an aliphatic polyester stabilized seed polymer, is disclosed. Related coatings and coated substrates are also disclosed.

Abstract: Described are film-forming compositions comprising a polyepoxide and a curing agent comprising an acid functional acrylic polymer, as well as coating systems comprising a coating deposited from such compositions and related processes and coated substrates.

Abstract: Described are film-forming compositions comprising a polyepoxide and a curing agent comprising an acid functional acrylic polymer, as well as coating systems comprising a coating deposited from such compositions and related processes and coated substrates.

Abstract: A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

Abstract: A non-aqueous dispersion comprising the dispersion polymerization reaction product of an ethylenically unsaturated monomer and a nonlinear, random acrylic polymer stabilizer is disclosed. Related coatings, methods, and substrates are also disclosed.

Abstract: Cationic electrodepositable coatings comprising rosin, wherein the rosin forms part of the cationic resin backbone, are disclosed.

Abstract: Modified epoxy resins comprising the reaction product of rosin and a linking molecule, further reacted with an epoxy resin, are disclosed. Aqueous dispersions and coatings comprising these resins are also disclosed.

Abstract: A cationic electrodepositable coating composition is disclosed.

Abstract: Aqueous dispersions and coatings comprising modified epoxy resins comprising the reaction product of rosin and a dienophile, further reacted with an epoxy resin, are disclosed.

Abstract: Modified epoxy resins comprising the reaction product of a cycloaliphatic, polycyclic and/or aromatic biomass derived compound and an epoxy resin are disclosed. Aqueous dispersions and coatings comprising these reaction products are also disclosed.