Abstract: The present invention relates to a copolymer comprising units of type A deriving from carboxylic acid monomers and units of type B deriving from sulfonic acid monomers, said units of type A and B representing more than 80 mol % of the total moles of units in the copolymer, characterized in that it comprises at least: one first block formed of at least 95 mol % of units of type A and having a degree of polymerization DP1 comprised between 5 and 150; and one second block formed of at least 95 mol % of units of type A and B with a molar ratio of units of type A to units of type B greater or equal to 1, wherein said units of type A and units of type B are statistically distributed, said second block having a degree of polymerization DP2 such that DP2/DP1?1. It also relates to new detergent compositions comprising such a copolymer, and to the use of this copolymer in a detergent composition, especially an ADW composition, to prevent, limit or eliminate the filming phenomena.

Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate in a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising at least three blocks, including: at least one first block which is adsorbed, preferably irreversibly, onto at least some of the particles (p); a second block (B) having a composition other than that of the first and a mean molecular weight of more than 10,000 g/mol, and which is soluble in the fluid (F); and at least one third block of type (A) or type (B).

Abstract: An aqueous formulation for enhanced oil recovery may include at least one surfactant and at least one associative polymer. The associative polymer may be obtained by micellar radical polymerization by bringing into contact, in an aqueous medium, hydrophilic monomer dissolved in the aqueous medium, hydrophobic monomers in the form of a micellar solution, at least one radical polymerization initiator, and preferably at least one radical polymerization control agent.

Abstract: The present invention relates to a process of a process for preparation of a polymer dispersion comprising a step (E) of free radical polymerization in an aqueous medium (M) in the presence of: at least a pre-polymer (pO) soluble in the medium (M), at least one free-radical polymerization initiator, and at least one ethylenically unsaturated hydrophobic monomer (m) which is chosen from an alkyl (meth)acrylate of at least C6, wherein the aqueous medium (M) includes water and at least one water miscible solvent.

Abstract: The present invention relates to a copolymer comprising units of type A deriving from carboxylic acid monomers and units of type B deriving from sulfonic acid monomers, said units of type A and B representing more than 80 mol % of the total moles of units in the copolymer, characterized in that it comprises at least: —one first block formed of at least 95 mol % of units of type A and having a degree of polymerization DP1 comprised between 5 and 150; and —one second block formed of at least 95 mol % of units of type A and B with a molar ratio of units of type A to units of type B greater or equal to 1, wherein said units of type A and units of type B are statistically distributed, said second block having a degree of polymerization DP2 such that DP2/DP1?1. It also relates to new detergent compositions comprising such a copolymer, and to the use of this copolymer in a detergent composition, especially an ADW composition, to prevent, limit or eliminate the filming phenomena.

Abstract: An aqueous formulation for enhanced oil recovery may include at least one surfactant and at least one associative polymer. The associative polymer may be obtained by micellar radical polymerization by bringing into contact, in an aqueous medium, hydrophilic monomer dissolved in the aqueous medium, hydrophobic monomers in the form of a micellar solution, at least one radical polymerization initiator, and preferably at least one radical polymerization control agent.

Abstract: Processes to prepare aqueous polymer dispersions are provided, as well as compositions thereof, which have high solids content (e.g., 50%) with low viscosity. The process uses a selective hydrophilic macro-RAFT agent of formula (I), and is substantially free of surfactants. This process can be used to make latex polymers with good stability, which can be used widely in coatings (e.g., architectural paints, stone paints, industrial coatings, wood coatings, etc.), adhesives, sealants and mastic compositions.

Abstract: This invention relates to the field of techniques for treating subterranean formations with gels during an oil or gas exploration or production operation, i.e., during drilling, completion, or hydraulic fracking processes. The invention relates in particular to a system making it possible to limit or even inhibit the phenomena known as loss of fluids (wager and/or gas) in an underground formation, particularly in a zone where the temperature is high. More particularly, the invention relates to a suspension (S) comprising: an aqueous phase containing salts; and within said aqueous phase, particles (p) based on associative polymers (P).

Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate and the rheology of a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising: a first block which is adsorbed onto at least some of the particles; and a second block having a composition other than that of the first block and a mean molecular weight of more than 10,000 g/mol, for example more than 100,000 g/mol, and which is soluble in the fluid.

Abstract: The present invention relates to a method of inhibiting or control wax formation during stimulation treatment of a well. More specifically, the present invention proposes the use of aqueous polymer dispersions suitable as wax inhibitor compositions which are compatible with aqueous fracturing fluids.

Abstract: Modification of the rheology of a liquid medium, aqueous or nonaqueous, with polymers in the form of specific particles obtained by grinding (micronizing) a porous macrogel, itself prepared by a process comprising a radical polymerization step which comprises reacting in the presence of pore formers monomers containing monomers bearing at least two ethylenic unsaturations, typically in combination with monomers bearing a single ethylenic unsaturation; a polymerization initiator; and optionally a polymerization control agent. These polymer particles keep other particles in suspension within the liquid medium, and also the stabilized suspensions are obtained.

Abstract: The present invention relates to the use of amphiphilic sequenced copolymers as an agent for controlling the filtrate in a fluid (F) injected under pressure into an underground formation, comprising—at least one chain (C) soluble in the fluid (F); and—at least one block (B) that is insoluble in the fluid (F).

Abstract: The present invention relates to the use of a block polymer as fluid loss control agent in a fluid injected under pressure into an oil-bearing rock, where: the fluid comprises solid particles and/or is brought into contact with solid particles within the oil-bearing rock subsequent to its injection, the polymer comprises: a first block which is adsorbed on at least a portion of the particles; and a second block with a composition distinct from that of the first and with a weight-average molecular weight of greater than 10 000 g/mol, for example of greater than 100 000 g/mol, and which is soluble in the fluid.

Abstract: The present invention relates to a method for preparing an aqueous dispersion of water-soluble polymers, which comprises a step (E) of radical polymerization, wherein the following are brought into contact in an aqueous medium (M) in which the synthesised polymer is not soluble: at least one ethylenically unsaturated monomer which is soluble in the aqueous medium (M); at least one source of free radicals; and a reactive stabiliser which comprises: a polymer chain (CP) which is soluble in the medium (M), a group (G) providing the radical polymerization of step (E) with a living and controlled nature, such as, for example, a group carrying a thiocarbonylthio —S(C?S)— group.

Abstract: Disclosed is a polymer dispersion prepared by controlled radical polymerization and a use of the polymer dispersion as a friction reducer in oil field processes.

Abstract: The invention relates to aqueous formulations suitable as extraction fluid in enhanced oil recovery, which comprise: at least one surfactant; and at least one associative polymer, such as obtained by micellar radical polymerization by bringing into contact, in an aqueous medium: hydrophilic monomers, dissolved or dispersed in the aqueous medium; hydrophobic monomers in the form of a micellar solution; and at least one radical polymerization initiator; and preferably at least one radical polymerization control agent.

Abstract: The present invention relates to the field of oil extraction. More specifically, it relates to a particular polymerization process, which provides access to formulations of polymers that may be used in particular for modifying rheology and fluid loss control during extraction operations and that have a better heat stability.

Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate in a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising at least three blocks, including: at least one first block which is adsorbed, preferably irreversibly, onto at least some of the particles (p); a second block (B) having a composition other than that of the first and a mean molecular weight of more than 10,000 g/mol, and which is soluble in the fluid (F); and at least one third block of type (A) or type (B).

Abstract: The present invention relates to the preparation of polymers that are of use in particular as a rheology agent, and are suitable for use in very concentrated saline media, which comprises a step of micellar radical polymerization in which are brought into contact, in an aqueous medium: —hydrophilic monomers; —hydrophobic monomers in the form of a micellar solution, containing micelles comprising these hydrophobic monomers; —a radical polymerization initiator; and —preferably an agent for controlling radical polymerization, wherein said micelles comprise at least one surfactant of amphoteric nature. The polymers obtained according to the invention are in particular of use for enhanced oil recovery.

Abstract: Products and processes that are related to phosphonated polysaccharide compositions, including phosphonated polysaccharide gels, having a substituent degree of substitution with a lower limit of 0.02 and an upper limit of 3, and having a weight average molecular weight with an upper limit of 5,000,000 g/mole, as well as to oil field application or fracturing fluid compositions comprising such phosphonated polysaccharide compositions.