Abstract: Monomodal copolymers of ethylene and molding compositions comprising such copolymers, wherein the copolymers have a density determined according to DIN EN ISO 1183-1, variant A in the range from 0.938 to 0.944 g/cm3, a melt index MFR21 determined according to ISO 1133 at 190° C. under a load of 21.6 kg in the range from 12 to 17 g/10 min, a weight average molar mass Mw in the range from 140 000 g/mol to 330 000 g/mol, a polydispersity Mw/Mn in the range from 9 to 17, and a content of comonomer side chains per 1000 carbon atoms Cx equal to or above a value defined via equation (I) Cx=128.7?134.62×d?, wherein d? is the numerical value of the density of the copolymer in g/cm3, the use of the copolymers for producing injection-molded articles, as well as injection-molded articles comprising the copolymers, and process for the preparation of such monomodal copolymers.

Abstract: The present disclosure provides a low density polyethylene (LDPE) having (A) a density from 0.910 to 0.924 g/cm3, determined according to ISO 1183 at 23° C.; (B) an elongational hardening of at least 4.2, at 150° C. at an elongational rate of 1 s?1; (C) a ratio Mw/Mn of at least 18, where (i) Mw is the weight average molar mass, measured by a MALLS detector coupled to a GPC, and (ii) Mn is the number average molar mass, measured by GPC (Gel Permeation Chromatography); and (D) a Mw of at least 230,000 g/mol. The present disclosure also provides an article of manufacture made from or containing (A) a substrate and (B) a coating layer made from or containing the disclosed LDPE. The present disclosure further provides a polymerization process occurring (A) in the presence of oxygen as the only radical initiating agent and (B) in the absence of solvents.

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties for use in preparing blow-molded articles and having the following features: 1) a density from 0.945 to less than 0.952 g/cm3; 2) an MIF/MIP ratio from 15 to 30; 3) a Shear-Induced Crystallization Index (SIC) from 2.5 to 5.5.

Abstract: The present disclosure provides a low density polyethylene (LDPE) having (A) a density from 0.910 to 0.924 g/cm3, determined according to ISO 1183 at 23° C.; (B) an elongational hardening of at least 4.2, at 150° C. at an elongational rate of 1 s?1; (C) a ratio Mw/Mn of at least 18, where (i) Mw is the weight average molar mass, measured by a MALLS detector coupled to a GPC, and (ii) Mn is the number average molar mass, measured by GPC (Gel Permeation Chromatography); and (D) a Mw of at least 230,000 g/mol. The present disclosure also provides an article of manufacture made from or containing (A) a substrate and (B) a coating layer made from or containing the disclosed LDPE. The present disclosure further provides a polymerization process occurring (A) in the presence of oxygen as the only radical initiating agent and (B) in the absence of solvents.

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties for use in preparing blow-moulded articles and having the following features: 1) a density from 0.945 to less than 0.952 g/cm3; 2) an MIF/MIP ratio from 15 to 30; 3) a Shear-Induced Crystallization Index (SIC) from 2.5 to 5.5.

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties for use in preparing blow-moulded articles and having the following features: 1) a density from 0.945 to less than 0.952 g/cm3; 2) an MIF/MIP ratio from 15 to 30; 3) a Shear-Induced Crystallization Index (SIC) from 2.5 to 5.5.

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) a density from 0.952 to 0.960 g/cm3; 2) an MIF/MIP ratio from 17 to 30; and 3) a Shear-Induced Crystallization Index SIC from 2.5 to 5.0.

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties for use in preparing blow-moulded articles and having the following features: 1) a density from 0.945 to less than 0.952 g/cm3; 2) an MIF/MIP ratio from 15 to 30; 3) a Shear-Induced Crystallization Index (SIC) from 2.5 to 5.5.

Abstract: Polyethylene composition with improved balance of environmental stress cracking resistance (FNCT) and impact resistance (Charpy), particularly suited for preparing pipes, said composition having the following features: 1) density from 0.945 to 0.955 g/cm3; 2) ratio MIF/MIP from more than 30 to 45; 3) Shear-Induced Crystallization Index SIC from 1.0 to 2.5; 4) Long Chain Branching index equal to or greater than 0.85.

Abstract: Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-molded articles, said composition having the following features: 1) density from 0.945 to less than 0.952 g/cm3; 2) ratio MIF/MIP from 15 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.5.

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) a density from 0.952 to 0.960 g/cm3; 2) an MIF/MIP ratio from 17 to 30; and 3) a Shear-Induced Crystallization Index SIC from 2.5 to 5.0.

Abstract: Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) density from 0.952 to 0.960 g/cm3; 2) ratio MIF/MIP from 17 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.0.

Abstract: Process for preparing ethylene copolymers in the presence of free-radical polymerization initiator at pressures in the range of from 160 MPa to 350 MPa and temperatures in the range of from 100° C. to 350° C. in a tubular reactor by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers, wherein the bi- or multifunctional comonomer bears at least two different functional groups, of which at least one is a unsaturated group, which can be incorporated into the growing polymer chain, and at least another functional group can act as chain transfer agent in radical ethylene polymerization, ethylene copolymers obtainable by such a process, the use of the ethylene copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene copolymers.

Abstract: Polyethylene composition with improved balance of environmental stress cracking resistance (FNCT) and impact resistance (Charpy), particularly suited for preparing pipes, said composition having the following features: 1) density from 0.945 to 0.955 g/cm3; 2) ratio MIF/MIP from more than 30 to 45; 3) Shear-Induced Crystallization Index SIC from 1.0 to 2.5; 4) Long Chain Branching index equal to or greater than 0.85.

Abstract: Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) density from 0.952 to 0.960 g/cm3; 2) ratio MIF/MIP from 17 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.0.

Abstract: Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) density from 0.945 to less than 0.952 g/cm3; 2) ratio MIF/MIP from 15 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.5.

Abstract: Novel polyethylenes having defined molecular weight distribution and LCB structure are devised, for films or moldings.

Abstract: New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5 s?1, at 150° C.), branching index g? equal or lower than 0.9 (at Mw of 2·106 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100° C., for a time of at least 10 minutes.

Abstract: Catalysts suitable for preparation of a polyethylene which comprises ethylene homopolymers and/or copolymers of ethylene with 1-alkenes and has a molar mass distribution width Mw/Mn of from 5 to 30, a density of from 0.92 to 0.955 g/cm3, a weight average molar mass Mw of from 50000 g/mol to 500 000 g/mol and has from 0.01 to 20 branches/1000 carbon atoms and a z-average molar mass Mz of less than 1 million g/mol.

Abstract: Process for preparing ethylene copolymers in the presence of free-radical polymerization initiator at pressures in the range of from 160 MPa to 350 MPa and temperatures in the range of from 100° C. to 350° C. in a tubular reactor by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers, wherein the bi- or multifunctional comonomer bears at least two different functional groups, of which at least one is a unsaturated group, which can be incorporated into the growing polymer chain, and at least another functional group can act as chain transfer agent in radical ethylene polymerization, ethylene copolymers obtainable by such a process, the use of the ethylene copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene copolymers.