Abstract: A polymeric coating composition for use in overlaying at least a portion of a substrate element composed of a plural component polymeric system composed of a reactive blend of at least one first component and at least one second component, wherein the first component consists essentially of a polymer and/or blend of polymers present in an amount sufficient to impart a predetermined amount of tensile strength, hardness, flexibility and adhesive strength to the resulting polymeric coating, and the second component is an isocyanate or isocyanate quasi-prepolymer. The substrate element is a blast-resistant polymeric material having low surface energy and/or low reactivity at or near the surface of the substrate. Also disclosed is a blast and/or ballistic-resistant construction element composed of a structure having the aforementioned polymeric material thereover. The polymeric material has a substrate matrix containing at least one of ultrahigh molecular weight polyethylene, aramid materials, and the like.

Abstract: A polymeric coating composition for use in overlaying at least a portion of a substrate element composed of a plural component polymeric system composed of a reactive blend of at least one first component and at least one second component, wherein the first component essentially of a polymer and/or blend of polymers present in an amount sufficient to impart a predetermined amount of tensile strength, hardness, flexibility and adhesive strength to the resulting polymeric coating, and the second component is an isocyanate or isocyanate quasi-prepolymer. The substrate element is a blast-resistant polymeric material having low surface energy and/or low reactivity at or near the surface of the substrate. Also disclosed is a blast and/or ballistic-resistant construction element composed of a structure having the aforementioned polymeric material thereover. The polymeric material has a substrate matrix containing at least one of ultrahigh molecular weight polyethylene, aramid materials, and the like.

Abstract: A polymeric coating composition for use in overlaying at least a portion of a substrate element composed of a plural component polymeric system composed of a reactive blend of at least one first component and at least one second component, wherein the first component is consists essentially of a polymer and/or a blend of polymers present in an amount sufficient to impart a predetermined amount of tensile strength, hardness, flexibility and adhesive strength to the resulting polymeric coating and the second component is an isocyanate or isocyanate quasi-prepolymer. The substrate element is a blast-resistant polymeric material having low surface energy and/or low reactivity at or near the surface of the substrate. Also disclosed is a blast and/or ballistic-resistant construction element composed of a structure having the aforementioned polymeric material in overlying attached relationship thereto.

Abstract: This invention relates to the process of preparation and application of a plural component, fast cure phenolic/polyurea elastomer coating co-polymer system. The disclosed coating system is prepared from the reaction of an isocyanate component and an amine terminated resin blend component. Each of the two components may individually or both contain a phenolic resin based product as part of the active hydrogen donation for the reaction with the isocyanate. These phenolic/polyurea co-polymers are characterized as having significantly improved chemical resistance and lower moisture vapor transmission through the coating system over conventional polyurea elastomer coating systems, thus making the coatings suitable for highly corrosive environments.

Abstract: This invention concerns a method for the preparation of polyurea elastomers, comprising: (a) reacting an amine chain extender with dialkyl maleate to form an aspartic ester, wherein the chain extender has a molar amount of amine groups that is greater than the moles of dialkyl maleate; (b) blending the aspartic ester with one or more polyoxyalkyleneamines to prepare a resin blend; (c) contacting the resin blend with an isocyanate under conditions effective to form a polyurea elastomer. This invention concerns a method for the preparation of polyurethane elastomers, comprising: (a) reacting an diamine chain extender with dialkyl maleate or fumarate, wherein the mole ratio of primary amine functionality in the diamine chain extender to dialkyl maleate or fumarate is more than 1:1; (b) coating a substrate with effective film forming amounts of the product of step (a), an isocyanate, and a polyhydroxyl compound under conditions effective to form a the polyurethane elastomer.

Abstract: This invention concerns a method for the preparation of polyurea elastomers, comprising: (a) reacting an amine chain extender with dialkyl maleate to form an aspartic ester, wherein the chain extender has a molar amount of amine groups that is greater than the moles of dialkyl maleate; (b) blending the aspartic ester with one or more polyoxyalkyleneamines to prepare a resin blend; (c) contacting the resin blend with an isocyanate under conditions effective to form a polyurea elastomer. This invention concerns a method for the preparation of polyurethane elastomers, comprising: (a) reacting an diamine chain extender with dialkyl maleate or fumarate, wherein the mole ratio of primary amine functionality in the diamine chain extender to dialkyl maleate or fumarate is more than 1:1; (b) coating a substrate with effective film forming amounts of the product of step (a), an isocyanate, and a polyhydroxyl compound under conditions effective to form a the polyurethane elastomer.

Abstract: This invention concerns a method for the preparation of polyurea elastomers, comprising: (a) reacting an amine chain extender with dialkyl maleate to form an aspartic ester, wherein the chain extender has a molar amount of amine groups that is less than the moles of dialkyl maleate; (b) blending the aspartic ester with one or more polyoxyalkyleneamines to prepare a resin blend; (c) contacting the resin blend with an isocyanate under conditions effective to form a polyurea elastomer. This invention also concerns a a polyurea elastomer, comprising the reaction product of (a) a resin blend containing one or more polyoxyalkyleneamine and an aspartic ester and (b) an isocyanate, wherein the aspartic ester in the resin blend comprises a reaction product of an amine chain extender and a dialkyl maleate, wherein the mole ratio of amine functionality in the amine chain extender to dialkyl maleate or fumarate is greater than 1:1.

Abstract: Polyurea elastomer systems have improved adhesion to a substrate with the use of a primer that is applied first. The primer is composed of hydrophobic, primary hydroxyl-containing compound, for example, castor oil, and an isocyanate. It is not necessary to wait for the primer to cure prior to applying of the polyurea elastomer system. The primer system is particularly useful on wet substrates, where the primer penetrates the sub-strate prior to polyurea elastomer spraying. Regardless of whether the substrate is dry or wet, adhesion is improved.

Abstract: Spray polyurea elastomer systems have improved adhesion to a substrate with the incorporation of a functional alkoxy silane and water. Such systems typically also include a quasi-prepolymer of an isocyanate and an active hydrogen-containing material, and at least one amine resin, and preferably an amine-terminated chain extender. The system may also benefit from the incorporation of a higher than usual proportion of 2,4'-isomer methylene diisocyanate (MDI). The viscosity of the various components, as well as various processing characteristics, may be improved by the addition of an alkylene carbonate. The spray polyurea elastomer systems of this invention also have improved abrasion and impact resistance.

Abstract: Polyurea elastomer systems have improved adhesion to a substrate with the use of a primer that is applied first. The primer is composed of hydrophobic, primary hydroxyl-containing compound, for example, castor oil, and an isocyanate. It is not necessary to wait for the primer to cure prior to applying of the polyurea elastomer system. The primer system is particularly useful on wet substrates, where the primer penetrates the substrate prior to polyurea elastomer spraying. Regardless of whether the substrate is dry or wet, adhesion is improved.

Abstract: Spray polyurea elastomer systems have improved adhesion to a substrate with the incorporation of a functional alkoxy silane and water. Such systems typically also include a quasi-prepolymer of an isocyanate and an active hydrogen-containing material, and at least one amine resin, and preferably an amine-terminated chain extender. The system may also benefit from the incorporation of a higher than usual proportion of 2,4'-isomer methylene diisocyanate (MDI). The viscosity of the various components, as well as various processing characteristics, may be improved by the addition of an alkylene carbonate. The spray polyurea elastomer systems of this invention also have improved abrasion and impact resistance.

Abstract: This invention discloses an aliphatic spray polyurea elastomer comprising an (A) component that includes an aliphatic isocyanate and a (B) component that includes (1) an amine-terminated polyoxyalkylene polyol and (2) a cycloaliphatic diamine chain extender, wherein between about 20% to about 80% of the primary amines have been converted into secondary amines.

Abstract: An aliphatic spray polyurea elastomer is disclosed. The elastomer comprises an (A) and (B) component. The (A) component includes an aliphatic isocyanate. The (B) component includes an amine terminated polyoxyalkylene polyol and an amine terminated aliphatic chain extender.

Abstract: An aliphatic spray polyurea elastomer is disclosed. The elastomer comprises an (A) and (B) component. The (A) component includes an aliphatic isocyanate. The (B) component includes an amine terminated polyoxyalkylene polyol and an amine terminated aliphatic chain extender.

Abstract: Spray polyurea elastomers are disclosed made from an (A) component and a (B) component, where the (A) component has a quasi-prepolymer made from an isocyanate and an active hydrogen-containing material, such as a polyoxyalkylenepolyamine. The (B) component includes an amine resin, such as an amine-terminated polyoxyalkylene polyol which may be the same or different from the polyoxyalkylene polyamine of the quasi-prepolymer. The viscosity of the (A) component is reduced by the inclusion of an organic, alkylene carbonate, such as ethylene carbonate, propylene carbonate, butylene carbonate, dimethyl carbonate, and the like. The alkylene carbonate also serves as a compatibilizer between between the two components, thus giving an improved mix of the system.

Abstract: A polyurea elastomer which exhibits a reduced moisture transfer rate is disclosed. The elastomer includes an isocyanate, an amine terminated 1,2-polyoxybutylene diol and a chain extender. The isocyanate is preferably a quasiprepolymer of an isocyanate and a material selected from at least one polyol, a high molecular weight polyoxyalkyleneamine or a combination thereof.

Abstract: A spray polyurea elastomer which exhibits improved resistance to abrasion is disclosed. The elastomer includes an isocyanate, an amine terminated polyoxyalkylene polyol, a chain extender and a chemically sized filler material. The isocyanate is preferably a quasi-prepolymer of an isoyanate and a material selected from at least one polyol, a high molecular weight polyoxyalkyleneamine or a combination thereof. A method for making a spray polyurea elastomer which is substantially resistant to abrasion is also disclosed.

Abstract: A process for the production of expanded polyurea elastomers which comprises reacting:a) an aliphatic polyetheramine having primary amino functions and essentially no free hydroxyl groups;b) carbon dioxide in the form of carbamate, obtained by reacting carbon dioxide with a portion of the aliphatic polyetheramines;c) a polyisocyanate;d) water; ande) a catalyst having a tertiary amino group;in the presence off) an inert, halogen-free blowing agent.

Abstract: A polyurea elastomer is disclosed. The elastomer includes an isocyanate, an amine terminated polyoxyalkylene polyol, and a chain extender. The isocyanate is preferably a quasi-prepolymer of an isocyanate and a material selected from at least one polyol, a high molecular weight polyoxyalkyleneamine or a combination thereof. The chain extender includes at least an alkyl substituted piperazine.

Abstract: An aliphatic polyurea elastomer is disclosed. The elastomer comprises an (A) and a (B) component. The (A) component includes an aliphatic isocyanate. The (B) component includes an amine terminated polyoxyalkylene polyol and a chain extender including an aliphatic spray polyurea elastomer comprising an (a) component which includes an aliphatic isocyanate and a (b) component which includes (1) an amine terminated polyoxyalkylene polyol and (2) a chain extender including cis-1,4-diaminocyclohexane, isophoronediamine, m-xylenediamine, 4,4'-methylenedicyclohexylamine, methanediamine, 1,4-diaminoethylcyclohexane and substituted derivatives thereof. Preferably, the chain extender includes cis-1,4-diaminocyclohexane, isophoronediamine or mixtures thereof.